Kenoargentotetrahedrite-(Fe)
A valid IMA mineral species
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About Kenoargentotetrahedrite-(Fe)
Formula:
[Ag6]4+(Cu4Fe2+2)Sb4S12◻
Ag in the M2 site consists of a [Ag6]4+ cluster that presumably exhibits metal-metal bonding; the "missing" M2 charge is compensated by a vacancy in the S2 site; thus, there are only 12 S atoms per formula unit, not 13.
Lustre:
Metallic
Crystal System:
Isometric
Member of:
Name:
The name kenoargentotetrahedrite-(Fe) partially supplants the former name freibergite for Fe>Zn members. The new name follows the revised nomenclature for the tetrahedrite group (Biagioni et al 2020).
Sb analogue of Kenoargentotennantite-(Fe).
The name kenoargentotetrahedrite-(Fe) partially supplants the former name freibergite for Fe>Zn members.
The name kenoargentotetrahedrite-(Fe) partially supplants the former name freibergite for Fe>Zn members.
Unique Identifiers
Mindat ID:
53610
Long-form identifier:
mindat:1:1:53610:3
GUID
(UUID V4):
(UUID V4):
059e7a93-3800-47c3-a810-024a2a3024d7
IMA Classification of Kenoargentotetrahedrite-(Fe)
Approved
IMA status notes:
Redefined by the IMA, Renamed by the IMA
IMA Formula:
Ag6(Cu4Fe2)Sb4S12◻
Type description reference:
Classification of Kenoargentotetrahedrite-(Fe)
2.GB.05
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Kattr-Fe | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kenoargentotetrahedrite-(Fe)
Metallic
Transparency:
Opaque
Chemistry of Kenoargentotetrahedrite-(Fe)
Mindat Formula:
[Ag6]4+(Cu4Fe2+2)Sb4S12◻
Ag in the M2 site consists of a [Ag6]4+ cluster that presumably exhibits metal-metal bonding; the "missing" M2 charge is compensated by a vacancy in the S2 site; thus, there are only 12 S atoms per formula unit, not 13.
Ag in the M2 site consists of a [Ag6]4+ cluster that presumably exhibits metal-metal bonding; the "missing" M2 charge is compensated by a vacancy in the S2 site; thus, there are only 12 S atoms per formula unit, not 13.
Crystallography of Kenoargentotetrahedrite-(Fe)
Crystal System:
Isometric
Class (H-M):
4 3m - Hextetrahedral
Space Group:
I4 3m
Cell Parameters:
a = 10.4930(4) Å
Unit Cell V:
1155.31 ų
Comment:
Space group by analogy with other members of Tetrahedrite group. Cell parameters from 'freibergite' of Welch et al 2018.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Kenoargentotetrahedrite-(Fe)
Co-Type Localities:
Place of Conservation of Type Material:
Senchenberg Museum collection, Frankfurt, Germany, 2289sa.
British Museum Natural History, London, UK, BM88668.
British Museum Natural History, London, UK, BM88668.
Reference:
Biagioni, C., George, L. L., Cook, N. J., Makovicky, E., Moëlo, Y., Pasero, M., ... & Bosi, F. (2020). The tetrahedrite group: Nomenclature and classification. American Mineralogist, 105(1), 109-122.
Other Language Names for Kenoargentotetrahedrite-(Fe)
German:Kenoargentotetrahedrit-(Fe)
Relationship of Kenoargentotetrahedrite-(Fe) to other Species
Member of:
Other Members of this group:
Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S | Iso. 4 3m : I4 3m |
Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S | Iso. 4 3m : I4 3m |
Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S | Iso. 4 3m : I4 3m |
Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S | Iso. 4 3m : I4 3m |
Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ | Iso. 4 3m : I4 3m |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
2.GB. | Polybasite-Tac | |
2.GB. | Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S |
2.GB. | Hakite-(Zn) | Cu6(Cu4Zn2)Sb4Se12Se |
2.GB. | Hakite-(Cd) | Cu6(Cu4Cd2)Sb4Se12Se |
2.GB. | Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S |
2.GB. | Pošepnýite | (Cu+3◻3)(Hg2+4Cu+2)Sb4Se12(Se0.5◻0.5) |
2.GB. | Argentopearceite | Ag16As2S11 |
2.GB. | Zvěstovite-(Zn) | Ag6(Ag4Zn2)As4S12S |
2.GB. | Kenoargentotennantite-(Fe) | [Ag6]4+(Cu4Fe2)As4S12◻ |
2.GB. | Tennantite-(Hg) | Cu6(Cu4Hg2)As4S12S |
2.GB. | Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ |
2.GB. | Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S |
2.GB. | Stibiogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S |
2.GB. | Tennantite-(Ni) | Cu6(Cu4Ni2)As4S12S |
2.GB. | Tetrahedrite-(Ni) | Cu6(Cu4Ni2)Sb4S12S |
2.GB. | Stibioústalečite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)Se12Se |
2.GB. | Arsenogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)S12S |
2.GB. | Tennantite-(In) | Cu6(Cu4(In3+Cu+))As4S12S |
2.GB. | Tennantite-(Cd) | Cu6(Cu4Cd2)As4S12S |
2.GB. | Tetrahedrite-(Mn) | Cu6(Cu4Mn2)Sb4S12S |
2.GB. | Argentopolybasite | [Ag6Sb2S7][Ag9AgS4] |
2.GB.X | Kenorozhdestvenskayaite-(Fe) | [Ag6]4+(Ag4Fe2+2)Sb4S12◻ |
2.GB. | Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S |
2.GB. | Tennantite-(Mn) | Cu6(Cu4Mn2)As4S12S |
2.GB. | Zvěstovite-(Fe) | Ag6(Ag4Fe2+2)As4S12S |
2.GB. | Hakite-(Fe) | Cu6(Cu4Fe2+2)Sb4Se12Se |
2.GB. | Tetrahedrite-(Cu) | Cu6(Cu4Cu2+2)Sb4S12S |
2.GB. | Arsenoústalečite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)Se12Se |
2.GB. | Tetrahedrite-(Cd) | Cu6(Cu4Cd2)Sb4S12S |
2.GB.05 | Argentotennantite-(Zn) | Ag6(Cu4Zn2)As4S12S |
2.GB.05 | Freibergite Subgroup | (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1 |
2.GB.05 | Giraudite-(Zn) | Cu6(Cu4Zn2)As4Se12Se |
2.GB.05 | Goldfieldite | (Cu4◻2)(Cu4Cu+2)Te4S12S |
2.GB.05 | Hakite-(Hg) | Cu6(Cu4Hg2)Sb4Se12Se |
2.GB.05 | Tennantite Subgroup | Cu6(Cu4C2+2)As4S12S |
2.GB.05 | Tetrahedrite Subgroup | Cu6(Cu4C2+2)Sb4S12S |
2.GB.05 | Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S |
2.GB.05 | Rozhdestvenskayaite-(Zn) | Ag6(Ag4Zn2)Sb4S12S |
2.GB.05 | UM1992-21-S:AgFeSb | Ag6(Ag4Fe2+2)Sb4S12S |
2.GB.05 | Tennantite-(Zn) | Cu6(Cu4Zn2)As4S12S |
2.GB.05 | Tetrahedrite-(Zn) | Cu6(Cu4Zn2)Sb4S12S |
2.GB.05 | Tennantite-(Fe) | Cu6(Cu4Fe2+2)As4S12S |
2.GB.05 | Tetrahedrite-(Fe) | Cu6(Cu4Fe2+2)Sb4S12S |
2.GB.05 | Tetrahedrite-(Hg) | Cu6(Cu4Hg2)Sb4S12S |
2.GB.10 | Selenostephanite | Ag5SbSe4 |
2.GB.10 | Stephanite | Ag5SbS4 |
2.GB.15 | Pearceite | [Ag6As2S7][Ag9CuS4] |
2.GB.15 | Polybasite | [Ag6Sb2S7][Ag9CuS4] |
2.GB.15 | UM2003-14-S:AgBiFeTe | Ag16FeBiTe3S8 |
2.GB.15 | Selenopolybasite | [(Ag,Cu)6(Sb,As)2(S,Se)7][Ag9Cu(S,Se)2Se2] |
2.GB.15 | Cupropearceite | [Cu6As2S7][Ag9CuS4] |
2.GB.15 | Cupropolybasite | [Cu6Sb2S7][Ag9CuS4] |
2.GB.15 | UM1979-17-S:BiCuFe | ~Cu18Fe4BiS16 |
2.GB.20 | Galkhaite | (Hg5Cu)CsAs4S12 |
2.GB.20 | Vorontsovite | (Hg5Cu)Σ6TlAs4S12 |
2.GB.20 | Ferrovorontsovite | (Fe5Cu)Σ6TlAs4S12 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kenoargentotetrahedrite-(Fe)
mindat.org URL:
https://www.mindat.org/min-53610.html
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References for Kenoargentotetrahedrite-(Fe)
Reference List:
Localities for Kenoargentotetrahedrite-(Fe)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Austria | |
| Auer et al. (2022) |
Bolivia | |
| Velebil et al. (2023) |
| Velebil et al. (2023) |
Canada | |
| rruff.info (n.d.) |
China | |
| Shu et al. (2022) |
Czech Republic | |
| Sejkora et al. (2022) |
Germany (TL) | |
| Biagioni et al. (2020) |
| Biagioni et al. (2020) |
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Barbara adit, Meiselding, Mölbling, Sankt Veit an der Glan District, Carinthia, Austria