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Crocobelonite

A valid IMA mineral species
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About CrocobeloniteHide

Formula:
CaFe3+2O(PO4)2
Colour:
saffron red to pinkish red
Lustre:
Vitreous, Greasy
Hardness:
4
Specific Gravity:
3.555 (Calculated)
Crystal System:
Orthorhombic
Name:
From Greek κρόκος (saffron) and βελόνα 81 (needle), for the orange-red colour and prismatic to acicular habit of its crystals.
New structure type. Chemically similar to beershevaite, with further relation to yakubovichite and graftonite-(Ca). Another natural anhydrous Ca-Fe phosphate (but a pyrophosphate) is anastasenkoite.


Unique IdentifiersHide

Mindat ID:
54653
Long-form identifier:
mindat:1:1:54653:5
GUID
(UUID V4):
e307084a-acbf-4cf7-9542-03dca837d65c

IMA Classification of CrocobeloniteHide

Approved
Approval year:
2020

Classification of CrocobeloniteHide

8.AC.

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CcbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CrocobeloniteHide

Vitreous, Greasy
Colour:
saffron red to pinkish red
Comment:
single crystals exhibit distinct dichroism from pink-red to deep-red
Streak:
orange
Hardness:
Tenacity:
Brittle
Cleavage:
Perfect
In two directions for Crocobelonite-2O and one direction for Crocobelonite-1M
Density:
3.555 g/cm3 (Calculated)
Comment:
for Crocobelonite-2O

Optical Data of CrocobeloniteHide

Type:
Biaxial (+)
RI values:
nα = 1.885(5) nβ = 1.885(5) nγ = 1.950
2V:
Measured: 10°
Max Birefringence:
δ = 0.065
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Pleochroism:
Strong
Comments:
Y – pale-yellow, Z – deep brownish-orange
Comments:
From Crocobelonite-2O

Chemistry of CrocobeloniteHide

Mindat Formula:
CaFe3+2O(PO4)2

Crystallography of CrocobeloniteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Crocobelonite-1MCrocobelonite-2O
CaFe3+2O(PO4)2CaFe3+2O(PO4)2
Monoclinic Orthorhombic 
2/m - Prismaticmmm (2/m 2/m 2/m) - Dipyramidal
P21/m Pnma
P21/m Pnma
a = 7.2447(2) Å, b = 6.3832(1) Å, c = 7.3993(2) Å
β = 106.401(2)°
a = 14.2757(1) Å, b = 6.3832(1) Å, c = 7.3169(1) Å
a:b:c = 1.135 : 1 : 1.159a:b:c = 2.236 : 1 : 1.146
V 328.25 ų
(Calculated from Unit Cell)
V 666.75 ų
(Calculated from Unit Cell)
24

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.54 Å(16)
5.12 Å(26)
3.549 Å(100)
3.200 Å(50)
2.912 Å(19)
2.869 Å(40)
2.662 Å(21)
2.264 Å(20)
Comments:
From Type Description of Crocobelonite-2O.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
21 : Chemically precipitated carbonate, phosphate, iron formations

Type Occurrence of CrocobeloniteHide

General Appearance of Type Material:
irregular dense segregations up to 0.5 mm
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5559/1 crocobelonite-2O
Geological Setting of Type Material:
Diopside paralava and appear as nests and schlieren up to 30 cm in size situated in brown to red-colored hornfels.
Associated Minerals at Type Locality:

Synonyms of CrocobeloniteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Crocobelonite associated with MagnetiteFe2+Fe3+2O4

Related Minerals - Strunz-mindat GroupingHide

8.AC.AngarfiteNaFe3+5(PO4)4(OH)4 · 4H2O Orth. 2 2 2 : C2 2 21
8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3m : R3c
8.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric. 1 : P1
8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 : P1
8.AC.ManganobadaloviteNaNaMn(MgFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.BeershevaiteCaFe3+3(PO4)3OMon. 2/m : P21/m
8.AC.CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.KabaloviteFe2+3Fe3+4(PO4)6Tric. 1 : P1
8.AC.Nazarchukite Ca2NiFe3+2(PO4)4Orth. mmm (2/m 2/m 2/m) : Pbca
8.AC.Changesite–(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m : R3c
8.AC.Crocobelonite-1MCaFe3+2O(PO4)2Mon. 2/m : P21/m
8.AC.Ebnerite(NH4)Zn(PO4)Hex. 6 : P63
8.AC.MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m
8.AC.Epiebnerite(NH4)Zn(PO4)Mon. 2 : P21
8.AC.02GrigorieviteCu3Fe3+2Al2(VO4)6Tric. 1 : P1
8.AC.02KoksharoviteCaMg2Fe3+4(VO4)6Tric. 1 : P1
8.AC.02ZiminaiteFe3+ 6 (VO4)6Tric. 1 : P1
8.AC.05CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m : B2/b
8.AC.05HowardevansiteNaCuFe2(VO4)3Tric. 1 : P1
8.AC.05O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Na□4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Ca□4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaFerroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
8.AC.05Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m : B2/b
8.AC.05ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : B2/m
8.AC.05HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Zn-H Arsenate Hydrxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m : B2/b
8.AC.05BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m : B2/b
8.AC.05MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
8.AC.05Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
8.AC.05KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m : B2/b
8.AC.05ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m : B2/b
8.AC.05CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
8.AC.05ManganohatertiteNaNaCa(MnFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.07ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m
8.AC.07FerrobobfergusoniteNa2Fe2+5Fe3+Al(PO4)6Mon.
8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m : B2/b
8.AC.10ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m
8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
8.AC.10Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m
8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m : P21/b
8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
8.AC.15FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m : P21/m
8.AC.17CzochralskiiteNa4Ca3Mg(PO4)4Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.18ManitobaiteNa16Mn2+ 25Al8(PO4)30Mon. m : Pb
8.AC.20MarićiteNaFe2+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Palenzonaite(NaCa2)Mn2+2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Hedegaardite(Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.25MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m : R3c
8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m : P21/b
8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth. mm2 : Pca21
8.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig. 3m (3 2/m) : P3m1
8.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : P3
8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m
8.AC.45TuiteCa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
8.AC.47IwateiteNa2BaMn(PO4)2Trig. 3 : P3
8.AC.47YurmariniteNa7(Fe3+,Mg,Cu)4(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47OzerovaiteNa2KAl3(AsO4)4Orth. mmm (2/m 2/m 2/m) : Cmca
8.AC.47AnatolyiteNa6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47PansneriteK3Na3(Fe3+,Al)6(AsO4)8Orth. mmm (2/m 2/m 2/m)
8.AC.50ChladniiteNa3CaMg11(PO4)9Trig. 3 : R3
8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig. 3 : R3
8.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig. 3 : R3
8.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig. 3 : R3
8.AC.50XenophylliteNa4Fe2+7(PO4)6Tric. 1 : P1
8.AC.50UdinaiteNaMg4(VO4)3Tet. 4 2m : I4 2d
8.AC.50ArsenudinaiteNaMg4(AsO4)3Tet. 4 2m : I4 2d
8.AC.52Lasnierite(Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3Orth. mmm (2/m 2/m 2/m) : Pbcn
8.AC.55PharmazinciteKZnAsO4Hex. 6 : P63
8.AC.57ZubkovaiteCa3Cu3(AsO4)4Mon. 2 : B2
8.AC.60KosnariteKZr2(PO4)3Trig. 3m (3 2/m) : R3c
8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m : P21/b
8.AC.70StanfielditeCa4Mg5(PO4)6Mon.
8.AC.75RonneburgiteK2MnV4O12Mon. 2/m
8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 : I4
8.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CrocobeloniteHide

References for CrocobeloniteHide

Localities for CrocobeloniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Israel
 
  • Southern District (HaDarom District)
    • Tamar Regional Council
      • Hatrurim Basin
[Crocobelonite-1M] Britvin et al. (2023)
Jordan
 
  • Amman Governorate
    • Transjordan Plateau
      • Daba-Siwaqa complex
Galuskin et al. (2023)
Miyawaki et al. (2020) +1 other reference
 
Mineral and/or Locality  
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