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Bicchulite

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Formula:
Ca2(Al2SiO6)(OH)2
Colour:
Translucent Colourless to white
Lustre:
Earthy
Specific Gravity:
2.75
Crystal System:
Isometric
Name:
Named in 1973 by Chiyoko Henmi, Isao Kusachi, Kitinosuke Henmi, Peter Aubrey Sabine, and Bian Raymond Young for Bicchu (also given as Bitchu, Bitcho-Cho, and Bicchu-Cho), Okayama Prefecture, Chugoku Region, Honshu Island, Japan the town wherein the Japanese type locality is situated, although Bicchu was subsequently encompassed by an expanded Takahashi City.
Dimorph of:
White to gray-white powder. Chemically very similar to gehlenite.


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Classification of BicchuliteHide

Approved
9.FB.10

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.3.5

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
16.9.12

16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca

Physical Properties of BicchuliteHide

Earthy
Transparency:
Translucent
Comment:
Fine-grained mineral
Colour:
Translucent Colourless to white
Streak:
White
Tenacity:
Brittle
Density:
2.75 g/cm3 (Measured)    2.813 g/cm3 (Calculated)
Comment:
Measured on synthetic material. May calculate to 2.792 using Gladstone-Dale relationship.

Optical Data of BicchuliteHide

Type:
Isotropic
Pleochroism:
Non-pleochroic

Chemical Properties of BicchuliteHide

Formula:
Ca2(Al2SiO6)(OH)2
IMA Formula:
Ca2Al2SiO6(OH)2
Common Impurities:
Ti,Fe,Mn,Mg,Na,K,P

Crystallography of BicchuliteHide

Crystal System:
Isometric
Class (H-M):
4 3m - Hextetrahedral
Space Group:
I4 3m
Setting:
I4 3m
Cell Parameters:
a = 8.83 Å
Unit Cell V:
688.47 ų (Calculated from Unit Cell)
Z:
4

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.60 (90)
3.49 (10)
3.12 (10)
3.04 (40)
2.96 (40)
2.786 (100)
2.753 (95)
2.597 (50)
2.460 (40)
2.354 (45)
2.205 (20)
2.135 (10)
2.079 (40)
1.984 (10)
1.890 (10)
1.801 (15)
1.763 (15)
1.732 (10)
1.665 (15)
1.625 (30)
1.559 (50)
1.514 (25)
Comments:
Henmi, et al. (1973). Also ICDD 27-66; formerly also ICDD 16-388

Occurrences of BicchuliteHide

Paragenetic Mode(s):

Type Occurrence of BicchuliteHide

Place of Conservation of Type Material:
Department of Earth Sciences, Faculty of Science, Okayama University, Okayama, Japan

Synonyms of BicchuliteHide

Other Language Names for BicchuliteHide

German:Bicchulith
Japanese:備中石
Spanish:Bicchulita

Common AssociatesHide

Associated Minerals Based on Photo Data:
Gehlenite2 photos of Bicchulite associated with Gehlenite on mindat.org.
Grossular-Hibschite Series1 photo of Bicchulite associated with Grossular-Hibschite Series on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClHex.
9.FB.05Cancrinite(Na,Ca,☐)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex.
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Hex.
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex.
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex.
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex.
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex.
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex.
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex.
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5)Hex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa6Ca2(Al6Si6O24)(SO4,S,S2, S3,Cl,OH)2Iso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa8(Al6Si6O24)Cl2Iso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth.
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Related Minerals - Dana Grouping (8th Ed.)Hide

76.2.3.1SodaliteNa8(Al6Si6O24)Cl2Iso. 4 3m : P4 3n
76.2.3.2NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
76.2.3.3Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
76.2.3.4LazuriteNa6Ca2(Al6Si6O24)(SO4,S,S2, S3,Cl,OH)2Iso. 4 3m : P4 3n
76.2.3.6KamaishiliteCa2(Al2SiO6)(OH)2Tet.
76.2.3.7TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
76.2.3.8Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

16.9.1GehleniteCa2Al(AlSiO7)Tet. 4 2m : P4 21m
16.9.2AnorthiteCa(Al2Si2O8)Tric. 1 : P1
16.9.3Yoshiokaite(Ca,Na)[Al(Al,Si)O4]Trig. 3 : P3
16.9.4SvyatoslaviteCa(Al2Si2O8)Orth.
16.9.5DmisteinbergiteCa(Al2Si2O8)Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
16.9.6GrossularCa3Al2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
16.9.7VuagnatiteCaAl(SiO4)(OH)Orth.
16.9.8Zoisite{Ca2}{Al3}(Si2O7)(SiO4)O(OH)Orth. mmm (2/m 2/m 2/m) : Pnma
16.9.9Clinozoisite{Ca2}{Al3}(Si2O7)(SiO4)O(OH)Mon. 2/m : P21/m
16.9.10PrehniteCa2Al2Si3O10(OH)2Orth. mm2
16.9.11KamaishiliteCa2(Al2SiO6)(OH)2Tet.
16.9.13MargariteCaAl2(Al2Si2O10)(OH)2Mon.
16.9.14ChantaliteCaAl2(SiO4)(OH)4Tet. 4/m : I41/a
16.9.15CebolliteCa5Al2(SiO4)3(OH)4Orth.
16.9.17KatoiteCa3Al2(SiO4)3-x(OH)4xIso.
16.9.18LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
16.9.19ParthéiteCa2(Si4Al4) O15 (OH)2•4H2OMon. 2/m : B2/b
16.9.20WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m
16.9.21VertumniteCa4Al4Si4O6(OH)24 · 3H2OMon. 2/m : P21/m
16.9.22ScoleciteCaAl2Si3O10 · 3H2OMon. m : Bb
16.9.23LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
16.9.24YugawaraliteCaAl2Si6O16 · 4H2OMon.
16.9.25Gismondine-CaCaAl2Si2O8 · 4H2O
16.9.26EpistilbiteCaAl2Si6O16 · 5H2OMon.
16.9.27GoosecreekiteCa[Al2Si6O16] · 5H2OMon.
16.9.28CowlesiteCaAl2Si3O10 · 6H2OOrth.
16.9.30StelleriteCa4(Si28Al8)O72 · 28H2OOrth. mmm (2/m 2/m 2/m) : Fmmm
16.9.31SträtlingiteCa2Al2SiO7 · 8H2OTrig.
16.9.32AmstalliteCaAl(Si,Al)4O8(OH)4 · (H2O,Cl)Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for BicchuliteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Henmi, C., Kusachi, I., Henmi, K., Sabine, P.A., Young, B.R. (1973) A new mineral bicchulite, the natural analogue of gehlenite hydrate, from Fuka, Okayama Prefecture, Japan and Carneal, County Antrim, Northern Ireland. Mineralogical Journal, 7: 243-251.
Gupta, Alok K. and Chatterjee, Niranjan D. (1968)Synthesis, composition, thermal stability, and thermodynamic properties of Bicchulite, Ca2[Al2SiO6](OH)2, American Mineralogist, 63: 58-65.
Zeitschrift für Kristallographie, 146: 35-41.
Zeitschrift für Kristallographie, 152: 13-21.

Internet Links for BicchuliteHide

Localities for BicchuliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Japan (TL)
 
  • Honshu Island
    • Chugoku Region
      • Okayama Prefecture
        • Takahashi City
          • Bicchu-cho (Bitchu-cho)
            • Fuka
Henmi, C., Kusachi, I., Henmi, K., Sabine, P.A., Young, B.R. (1973) A new mineral bicchulite, the natural analogue of gehlenite hydrate, from Fuka, Okayama Prefecture, Japan and Carneal, County Antrim, Northern Ireland. Mineralogical Journal: 7: 243-251.; I. Kusachi, Y. Takechi, C. Henmi and S. Kobayashi (1998) Parasibirskite, a New Mineral from Fuka, Okayama Prefecture, Japan. Mineralogical Magazine 62:521-525.; Mineralogical Record: 27: 304.;
    • Tohoku Region
      • Iwate Prefecture
        • Kamaishi City
Dr. Matsuo Nambu collection (curated by the Geological Survey of Japan)
        • Ohshuu City
          • Esashi ward
Bunno, M., Shimazaki, H., & Sato, K. (1982). Occurrence and genesis of bicchulite and tilleyite skarns at the Sakae adit, the Akagane mine, Iwate Prefecture. Mining Geology, 32, 141-150.; Shimazaki, H., Miyawaki, R., Yokoyama, K., Matsubara, S., & Bunno, M. (2008). Occurrence and new data of dellaite from the Akagane mine, Japan. Journal of mineralogical and petrological sciences, 103(6), 385-389.
UK
 
  • Northern Ireland
    • Co. Antrim
      • Glenoe
Henmi, C., Kusachi, I., Henmi, K., Sabine, P.A., and Young, B.R. (1973) A new mineral bicchulite, the natural analogue of gehlenite hydrate, from Fuka, Okayama Prefecture, Japan and Carneal, County Antrim, Northern Ireland. Mineralogical Journal, vol. 7, n° 3, 243-251.; Embrey, P.G. (1978) Fourth supplementary list of British minerals. Mineralogical Magazine, vol. 42, n° 322, 169-177.;
USA
 
  • Texas
    • Uvalde Co.
Mineral and/or Locality  
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