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Akdalaite

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About AkdalaiteHide

Formula:
5Al2O3 · H2O
Colour:
White, pale greenish yellow in thin section
Lustre:
Vitreous
Hardness:
7 - 7½
Specific Gravity:
3.68
Crystal System:
Hexagonal
Name:
For the Kazakh name, Akdala, for the type locality.
In the structure there are oxygen planes with ABACA sequence (Yamaguchi et al., 1964). In the ab initio model proposed by Demichelis et al. (2008) there are 8 Al atoms located in the octahedral cavities and 2 Al atoms in the tetrahedral ones; two types of irregular AlO6 edge-sharing octahedra; AlO4 vertices-sharing tetrahedra. There are 2 sheets of first-type (a) octahedra, and two sheets with second-type (b) octahedra and tetrahedra (c).


Classification of AkdalaiteHide

Approved
Approval Year:
1969
4.FL.70

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
L : Hydroxides with H2O +- (OH); sheets of edge-sharing octahedra
4.3.2.1

4 : SIMPLE OXIDES
3 : A2X3
7.6.8

7 : Oxides and Hydroxides
6 : Oxides of Al

Physical Properties of AkdalaiteHide

Vitreous
Transparency:
Translucent
Comment:
vitreous to porcelaneous
Colour:
White, pale greenish yellow in thin section
Streak:
White
Hardness:
7 - 7½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
3.68 g/cm3 (Measured)    3.673 g/cm3 (Calculated)

Optical Data of AkdalaiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.747 nε = 1.741
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High

Chemical Properties of AkdalaiteHide

Formula:
5Al2O3 · H2O
IMA Formula:
(Al2O3)5 · H2O

Crystallography of AkdalaiteHide

Crystal System:
Hexagonal
Cell Parameters:
a = 12.87 Å, c = 14.97 Å
Ratio:
a:c = 1 : 1.163
Unit Cell V:
2,147.38 ų (Calculated from Unit Cell)
Z:
18
Morphology:
As hexagonal crystals, to 0.8 mm, tabular to equant; in lenslike aggregates.
Comment:
Possible space groups: P6122, P61

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
0.9931 (9)
1.393 (10)
1.418 (10)
2.11 (10)
2.32 (8)
2.35 (9)
2.494 (9)
Comments:
Material from type locality

Type Occurrence of AkdalaiteHide

General Appearance of Type Material:
lenslike aggregates and tabular to equant hexagonal crystals to 0.1 mm
Place of Conservation of Type Material:
A. E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia
Geological Setting of Type Material:
veinlets cutting amesite-fluorite-muscovite rock and fluorite-magnetite-diopside-vesuvianite skarn
Associated Minerals at Type Locality:

Synonyms of AkdalaiteHide

Other Language Names for AkdalaiteHide

German:Akdalait
Spanish:Akdalaita

Common AssociatesHide

Associated Minerals Based on Photo Data:
Aluminium1 photo of Akdalaite associated with Aluminium on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

4.FL.TrébeurdeniteFe2+2Fe3+4O2(OH)10CO3·3H2OTrig. 3m (3 2/m) : R3m
4.FL.05WoodalliteMg6Cr2(OH)16Cl2 · 4H2OTrig.
4.FL.05IowaiteMg6Fe3+2(OH)16Cl2 · 4H2OTrig. 3m (3 2/m) : R3m
4.FL.05JamboriteNi2+1-xCo3+x(OH)2-x(SO4)x · nH2OTrig. 3m (3 2/m) : R3m
4.FL.05MeixneriteMg6Al2(OH)16(OH)2 · 4H2OTrig. 3m (3 2/m) : R3m
4.FL.05MuskoxiteMg7Fe4O13 · 10H2OTrig. 3m (3 2/m)
4.FL.05FougèriteFe2+4Fe3+2(OH)12[CO3]·3H2OTrig. 3m (3 2/m) : R3m
4.FL.10HydrocalumiteCa4Al2(OH)12(Cl,CO3,OH)2 · 4H2OMon. 2 : P21
4.FL.15KuzeliteCa4Al2(OH)12[SO4] · 6H2OTrig.
4.FL.20Aurorite(Mn2+,Ag,Ca)Mn4+3O7 · 3H2OTrig. 3 : R3
4.FL.20Chalcophanite(Zn,Fe,Mn)Mn3O7 · 3H2OTrig. 3 : R3
4.FL.20ErnienickeliteNiMn3O7 · 3H2OTrig. 3 : R3
4.FL.20Jianshuiite(Mg,Mn,Ca)Mn3O7 · 3H2OTrig. 3 : R3
4.FL.25WoodruffiteZn2+x/2(Mn4+1-xMn3+x)O2·yH2OMon. 2/m : B2/m
4.FL.30Asbolane(Ni,Co)2-xMn4+(O,OH)4 · nH2OHex.
4.FL.35BuseriteNa4Mn14O27 · 21H2O
4.FL.40Ranciéite(Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2OTrig. 3 : P3
4.FL.40Takanelite(Mn,Ca)Mn4O9 · H2OHex.
4.FL.45Birnessite(Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2OMon. 2/m : B2/m
4.FL.55CianciulliiteMn(Mg,Mn)2Zn2(OH)10 · 2-4H2OMon. 2/m : B2/m
4.FL.60JenseniteCu3[TeO6] · 2H2OMon. 2/m : P21/m
4.FL.65LeisingiteCuMg2Te6+O6 · 6H2OTrig. 3 : P3
4.FL.75CafetiteCaTi2O5 · H2OMon. 2/m : P21/b
4.FL.80MouriteUMo5O12(OH)10Mon.
4.FL.85DeloryiteCu4(UO2)(MoO4)2(OH)6Mon.

Related Minerals - Dana Grouping (8th Ed.)Hide

4.3.2.2FerrihydriteFe3+10O14(OH)2Trig.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

7.6.1CorundumAl2O3Trig. 3m (3 2/m) : R3c
7.6.2BöhmiteAlO(OH)Orth. mmm (2/m 2/m 2/m)
7.6.2DiasporeAlO(OH)Orth. mmm (2/m 2/m 2/m)
7.6.4GibbsiteAl(OH)3Mon. 2/m
7.6.5BayeriteAl(OH)3Mon. 2/m : P21/m
7.6.6NordstranditeAl(OH)3Tric. 1 : P1
7.6.7DoyleiteAl(OH)3Tric.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for AkdalaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Yamaguchi, G., Yanagida, H., Shuitiro, O. (1964) New alumina hydrate, "tohdite" (5Al2O3·H2O). Bulletin of the Chemical Society of Japan: 37: 752-754.
Shpanov, E.P., Sidorenko, G.A., Stolyarova, T.I. (1970) Akdalaite, a new hydrous modification of alumina. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 99: 333-339. [in Russian]
Fleischer, M. (1971) American Mineralogist: 56: 635. [abstract]
Anthony, J.W., Bideaux, R.A., Bladh, K.W., Nichols, M.C. (1997) Handbook of Mineralogy, Vol. 3: Halides, Hydroxides, Oxides. Mineral Data Publishing (Tucson, AZ), 8.
Demichelis, R., Noel, Y., Zicovich-Wilson, C.M., Roetti, C., Valenzano, L., Dovesi, R. (2008) Ab-initio quantum mechanical study of akdalaite (5Al2O3·H2O): Structure and vibrational spectrum. Journal of Physics: Conference Series: 117: 012013.

Internet Links for AkdalaiteHide

Localities for AkdalaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Queensland
    • Cook Shire
      • Cape York Peninsula
Tilley, D. B., & Eggleton, R. A. (1996). The natural occurrence of eta-alumina (η-Al2O3) in bauxite. Clays and clay minerals, 44(5), 658-664.
Azerbaijan
 
  • Qobustan District (Gobustan; Kobustan)
    • Caspian Sea
Novgorodova M.I., MamedovYu.G. Lithology and Mineral Resources, 1996,N4, p.339-349
Kazakhstan
 
  • Akmola
Hwang, S. L., Shen, P., Chu, H. T., & Yui, T. F. (2006). A new occurrence and new data on akdalaite, a retrograde mineral from UHP Whiteschist, Kokchetav Massif, Northern Kazakhstan. International Geology Review, 48(8), 754-764.
  • Karaganda
    • Karazhal
      • Betpakdala Desert (Bet-Pak-Dal Desert)
        • Kara-Oba W deposit
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow; Fleischer M (1971) New mineral names. American Mineralogist 56, 631-640
South Africa
 
  • Northern Cape Province
Zhou, B., Sherriff, B. L., Taulelle, F., & Wu, G. (2003). Nuclear magnetic resonance study of Al: Si and F: OH order in zunyite. The Canadian Mineralogist, 41(4), 891-903.
USA
 
  • Idaho
    • Latah Co.
Hwang, S. L., Shen, P., Chu, H. T., Yui, T. F., & Iizuka, Y. (2015). Origin of rutile needles in star garnet and implications for interpretation of inclusion textures in ultrahigh‐pressure metamorphic rocks. Journal of Metamorphic Geology, 33(3), 249-272.
Mineral and/or Locality  
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