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Fluoro-cannilloite

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Formula:
CaCa2(Mg4Al)(Si5Al3)O22F2
System:
Monoclinic
Colour:
grey-green
Lustre:
Vitreous
Hardness:
6
Name:
In allusion to its composition, with FLUORine dominant over hydroxyl and its relationship to Cannilloite.
Originally, the mineral was named "cannilloite," but the type material was found to be fluorine-dominant (F>OH) and it was renamed as stated.

Note that the "fluoro-cannilloites" from Luc Yen, Vietnam, are pargasite (see http://www.mindat.org/mesg-7-198029.html).




Classification of Fluoro-cannilloite

Approved
Approval Year:
1996
8/F.10-105
9.DE.10

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles

Physical Properties of Fluoro-cannilloite

Vitreous
Colour:
grey-green
Streak:
grey-white
Hardness (Mohs):
6
Cleavage:
Perfect
on {110}

Optical Data of Fluoro-cannilloite

Type:
Biaxial (+)
RI values:
nα = 1.611 nβ = 1.616 nγ = 1.633
Max Birefringence:
δ = 0.022
Image shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
relatively strong

Chemical Properties of Fluoro-cannilloite

IMA Formula:
CaCa2(Mg4Al)(Si5Al3)O22F2
Mindat.org Formula:
{Ca}{Ca2}{Mg4Al}(Al3Si5O22)(F,OH)2

Defined as a an amphibole in the cannilloite group of the Calcium subgroup with Mg>Fe2+ and Al>Fe3+ in the C position and with F as the dominant anion in the W position
Elements listed in formula:

Crystallography of Fluoro-cannilloite

Crystal System:
Monoclinic

Type Occurrence of Fluoro-cannilloite

General Appearance of Type Material:
Fluor-cannilloite is gray-green and semitranslucent with a vitreous luster; it has a grayish white streak and shows
no fluorescence under long-wave or short-wave ultraviolet light. It occurs as isolated anhedral grains and small granular aggregates up to

Relationship of Fluoro-cannilloite to other Species

Other Members of Group:
CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2
Ferri-cannilloiteCa(Ca2)(Mg4Fe3+)(Al3Si5O22)(OH)2
Ferri-fluoro-cannilloite(Ca)(Ca2){Mg4Fe3+}(Al3Si5O22)F2
Ferro-cannilloiteCa(Ca2)(Fe42+Al)(Al3Si5O22)(OH)2
Ferro-ferri-cannilloiteCa(Ca2)(Fe42+Fe3+)(Al3Si5O22)(OH)2
Ferro-ferri-fluoro-cannilloite{Ca}{Ca2}{Fe42+Fe3+}(Al3Si5O22)F2
Ferro-fluoro-cannilloite{Ca}{Ca2}{Fe42+Al}(Al3Si5O22)F2
9.DE.05Anthophyllite◻Mg2Mg5Si8O22(OH)2
9.DE.05Cummingtonite◻Mg2Mg5Si8O22(OH)2
9.DE.05Clino-holmquistite Root Name☐{Li2}{Z32+Z23+}(Si8O22)(OH,F,Cl)2
9.DE.05Grunerite◻Fe22+Fe52+Si8O22(OH)2
9.DE.05Manganocummingtonite◻Mn2Mg5Si8O22(OH)2
9.DE.05Manganogrunerite◻Mn2Fe52+Si8O22(OH)2
9.DE.05Permanganogrunerite☐{Mn22+}{Mn52+}(Si8O22)(OH)2
9.DE.05Ferro-fluoro-pedrizite{Na}{Li2}{Fe2Al2Li}(Al2Si6O22)F2
9.DE.05Ferri-fluoro-leakeiteNaNa2(Mg2Fe23+Li)Si8O22F2
9.DE.10ActinoliteCa2(Mg4.5-2.5Fe2+0.5-2.5)Σ=5Si8O22(OH)2
9.DE.10Ferri-tschermakite☐{Ca2}{Mg3Fe23+}(Al2Si6O22)(OH)2
9.DE.10Ferro-actinolite◻Ca2Mg2.5-0Fe2+2.5-5Si8O22(OH)2
9.DE.10Ferro-hornblende◻Ca2(Fe42+Al)(Si7Al)O22(OH)2
9.DE.10Ferro-tschermakite☐{Ca2}{Fe32+Al2}(Al2Si6O22)(OH)2
9.DE.10JoesmithitePbCa2Mg3Fe23+(Si6Be2)O22(OH)2
9.DE.10Magnesio-hornblende◻Ca2(Mg4Al)(Si7Al)O22(OH)2
9.DE.10Tremolite◻Ca2Mg5Si8O22(OH)2
9.DE.10Tschermakite◻Ca2(Mg3Al2)Si6Al2O22(OH)2
9.DE.10CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2
9.DE.10Parvo-manganotremolite☐{CaMn2+}{Mg5}(Si8O22)(OH)2
9.DE.10Fluoro-tremolite◻Ca2Mg5Si8O22F2
9.DE.10Potassic-fluoro-pargasiteKCa2(Mg4Al)Si6Al2O22F2
9.DE.15EdeniteNaCa2Mg5(Si7Al)O22(OH)2
9.DE.15Ferro-edeniteNaCa2Fe52+(Si7Al)O22(OH)2
9.DE.15Ferro-kaersutite{Na}{Ca2}{Fe32+AlTi}(Al2Si6O22)O2
9.DE.15Ferro-pargasiteNaCa2(Fe42+Al)(Si6Al2)O22(OH)2
9.DE.15HastingsiteNaCa2(Fe42+Fe3+)(Si6Al2)O22(OH)2
9.DE.15KaersutiteNaCa2(Mg3Ti4+Al)(Si6Al2)O22O2
9.DE.15Magnesio-hastingsiteNaCa2(Mg4Fe3+)Si6Al2O22(OH)2
9.DE.15PargasiteNaCa2(Mg4Al)(Si6Al2)O22(OH)2
9.DE.15SadanagaiteNaCa2(Mg3Al2)(Si5Al3)O22(OH)2
9.DE.15Fluoro-edeniteNaCa2Mg5(Si7Al)O22F2
9.DE.15Potassic-ferro-ferri-sadanagaiteKCa2(Fe32+Fe23+)(Si5Al3)O22(OH)2
9.DE.15Potassic-sadanagaiteKCa2Mg3Al2(Si5Al3)O22(OH)2
9.DE.15Potassic-pargasiteKCa2(Mg4Al)(Si6Al2)O22(OH)2
9.DE.15Potassic-ferro-sadanagaiteKCa2(Fe32+Al2)(Si5Al3)O22(OH)2
9.DE.15Magnesio-fluoro-hastingsiteNaCa2(Mg4Fe3+)(Si6Al2)O22F2
9.DE.15Potassic-fluoro-hastingsiteKCa2(Fe42+Fe3+)(Si6Al2)O22F2
9.DE.15Potassic-chloro-hastingsiteKCa2[Fe42+Fe3+](Si6Al2)O22Cl2
9.DE.15Fluoro-pargasiteNaCa2(Mg4Al)(Si6Al2)O22F2
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2
9.DE.15Potassic-chloro-pargasiteKCa2(Mg4Al)(Si6Al2)O22Cl2
9.DE.15Potassic-ferro-chloro-edenite{K}{Ca2}{Fe52+}(AlSi7O22)(Cl,OH)2
9.DE.15Potassic-magnesio-hastingsiteKCa2(Mg4Fe3+)(Si6Al2)O22(OH)2
9.DE.15Potassic-ferro-pargasiteKCa2(Fe42+Al)Si6Al2O22(OH)2
9.DE.15Chromio-pargasiteNaCa2(Mg4Cr)(Si6Al2)O22(OH)2
9.DE.20Ferro-taramiteNa(NaCa)Fe32+Al2(Si6Al2)O22(OH)2
9.DE.20Barroisite◻NaCa[Mg3Al2](Si7Al)O22(OH)2
9.DE.20Ferro-ferri-barroisite☐(CaNa)(Fe32+Fe23+)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-winchite☐[CaNa][Fe42+(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite☐(CaNa)(Mg3Fe23+)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe32+Fe23+)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNa(NaCa)(Fe42+Fe3+)(Si7Al)O22(OH)2
9.DE.20Ferro-barroisite☐{CaNa}{Fe32+Al2}(AlSi7O22)(OH)2
9.DE.20Ferro-richteriteNa2CaFe52+Si8O22(OH)2
9.DE.20Ferro-winchite ☐{CaNa}{Fe42+Al}(Si8O22)(OH)2
9.DE.20Ferro-katophoriteNaNaCa[Fe42+Al](Si7Al)O22(OH)2
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe23+)(Al2Si6O22)(OH)2
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2
9.DE.20RichteriteNa2CaMg5Si8O22(OH)2
9.DE.20Winchite◻NaCa(Mg4Al)Si8O22(OH)2
9.DE.20TaramiteNa(NaCa)(Mg3Al2)(Si6Al2)O22(OH)2
9.DE.20Fluoro-richteriteNa(NaCa)Mg5Si8O22F2
9.DE.20KatophoriteNaNaCa(Mg4Al)(Si7Al)O22(OH)2
9.DE.20Potassic-fluoro-richteriteK(NaCa)Mg5Si8O22F2
9.DE.20Potassic-richteriteK[CaNa][Mg5]Si8O22(OH)2
9.DE.20Ferri-ghoseite◻(NaMn2+)(Mg4Fe3+)Si8O22(OH)2
9.DE.20Ferri-winchite◻NaCa(Mg4Fe3+)Si8O22(OH)2
9.DE.20Fluoro-taramiteNa(NaCa)(Mg3Al2)(Si6Al2)O22F2
9.DE.25ArfvedsoniteNaNa2(Fe42+Fe3+)Si8O22(OH)2
9.DE.25EckermanniteNaNa2(Mg4Al)Si8O22(OH)2
9.DE.25Ferro-eckermanniteNaNa2(Fe42+Al)Si8O22(OH)2
9.DE.25Ferro-glaucophane◻Na2(Fe32+Al2)Si8O22(OH)2
9.DE.25Glaucophane◻Na2(Mg3Al2)Si8O22(OH)2
9.DE.25Potassic-mangani-leakeiteKNa2(Mg2Mn23+Li)Si8O22(OH)2
9.DE.25Mangano-ferri-eckermanniteNaNa2(Mn42+Fe3+)Si8O22(OH)2
9.DE.25Ferri-leakeiteNa(NaLi)(Mg2Fe23+Li)Si8O22(OH)2
9.DE.25Magnesio-riebeckite◻Na2(Mg3Fe23+)Si8O22(OH)2
9.DE.25Magnesio-arfvedsoniteNaNa2(Mg4Fe3+)Si8O22(OH)2
9.DE.25NybøiteNaNa2(Mg3Al2)(Si7Al)O22(OH)2
9.DE.25Riebeckite◻Na2(Fe32+Fe23+)Si8O22(OH)2
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn22+Mn33+)Si8O22O2
9.DE.25Ferro-ferri-nybøiteNaNa2(Fe32+Fe23+)(Si7Al)O22(OH)2
9.DE.25Clino-ferro-ferri-holmquistite◻Li2(Fe32+Fe23+)Si8O22(OH)2
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe23+](AlSi7O22)(OH)2
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe22+Fe23+Li]Si8O22(OH)2
9.DE.25Ferro-ferri-fluoro-leakeiteNaNa2(Fe22+Fe23+Li)Si8O22F2
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe32+Fe23+}(Si8O22)(OH)2
9.DE.25Magnesio-fluoro-arfvedsoniteNaNa2(Mg4Fe3+)Si8O22F2
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe23+Li]Si8O22(OH)2
9.DE.25Potassic-ferri-leakeiteKNa2Mg2Fe23+LiSi8O22(OH)2
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(Si7Al)O22F2
9.DE.25Mangani-dellaventuraiteNaNa2(MgMn23+LiTi4+)Si8O22O2
9.DE.25Fluoro-pedriziteNaLi2(Mg2Al2Li)(Si8O22)F2
9.DE.25Potassic-arfvedsoniteKNa2Fe42+Fe3+Si8O22(OH)2
9.DE.25Mangani-obertiiteNaNa2(Mg3Mn3+Ti4+)Si8O22O2
9.DE.25Potassic-magnesio-fluoro-arfvedsoniteKNa2(Mg4Fe3+)Si8O22F2
9.DE.25Ferro-ferri-pedriziteNaLi2(LiFe22+Fe23+)Si8O22(OH)2
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2
9.DE.25Ferro-pedriziteNaLi2(Fe22+Al2Li)Si8O22(OH)2
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)Si8O22F2
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe32+Fe3+Ti)Si8O22O2

Other Names for Fluoro-cannilloite

Name in Other Languages:

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fluoro-cannilloite

Reference List:
Hawthorne F.C., Oberti R., Ungaretti L., Grice J.D. (1996) A new hyper-calcic amphibole with Ca at the A site: Fluor-cannilloite from Pargas, Finland. American Mineralogist: 81: 995-1002.

Mandarino, J.A. (1997) Abstracts of new mineral descriptions (department). Mineralogical Record: 28: 142.

Mandarino, J.A. (1998) The Second List of Additions and Corrections to the Glossary of Mineral Species (1995). The Amphibole Group. Mineralogical Record: 29: 169-174.

Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist: 97: 2031-2048.

Internet Links for Fluoro-cannilloite

mindat.org URL:
http://www.mindat.org/min-6949.html
Please feel free to link to this page.

Localities for Fluoro-cannilloite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
China
 
  • Yunnan Province
    • Wenshan Autonomous Prefecture
      • Wenshan Co.
Kristalldruse shop, Munich, Bavaria, Germany
Finland (TL)
 
  • Southwestern Finland Region
Hawthorne, F. C., Oberti, R., Ungaretti, L., Grice, J. D. (1996): A new hyper-calcic amphibole with Ca at the A site: Fluor-cannilloite from Pargas, Finland. American Mineralogist. 81, 995-1002
Hietala, Satu 2012. Paraisten kalkkilouhoksen mineraaleista. Kivi 1/2012 12-18.
Madagascar
 
  • Tuléar Province (Toliara)
    • Anosy Region (Fort Dauphin Region)
      • Amboasary District
Lapis 21 (11): p 45. (abstract)
Vietnam
 
  • Yenbai Province (Yen Bai Province)
http://www.thearkenstone.com/tuc-china2.html; Eugeni Bareche (2007) An Phu, Luc Yen, Vietnam. Revista de Minerales (Barcelona), 2007/2, 26-29.
      • An Phu (Anfu)
Eugeni Bareche (2007) An Phu, Luc Yen, Vietnam. Revista de Minerales (Barcelona), 2007/2, 26-29
Mineral and/or Locality  
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