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Khomyakovite

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About KhomyakoviteHide

Alexander Petrovich Khomyakov
Formula:
Na12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2
Colour:
Orange to orange-red.
Lustre:
Vitreous
Hardness:
5 - 6
Specific Gravity:
3.14 (Calculated)
Crystal System:
Trigonal
Member of:
Name:
Named in 1999 by O. Johnsen, Robert A. Gault, Joel D. Grice, and T.Scott Ercit in honor of Alexander Petrovich Khomyakov [April 2, 1933 Moscow, Russia - October 12, 2012 Russia], of the Institute of Mineralogy, Geochemistry and Crystal Chemistry of Rare Elements, Moscow, Russia, for his extensive contributions to the mineralogy and geochemistry of alkaline rocks. He described 101 mineral species and was senior author for 80 of those descriptions.
Eudialyte Group

Unique combination of elements.

One of four tungsten-bearing silicates, by johnsenite-(Ce), manganokhomyakovite, and welinite.


Classification of KhomyakoviteHide

Approved
9.CO.10

9 : SILICATES (Germanates)
C : Cyclosilicates
O : [Si9O27]18- 9-membered rings
Dana 7th ed.:
64.1.1.4
64.1.2.5

64 : CYCLOSILICATES Rings with Other Anions and Insular Silicate Groups
1 : Rings with Other Anions and Insular Silicate Groups with mixed ring types

Physical Properties of KhomyakoviteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Orange to orange-red.
Streak:
White.
Hardness:
5 - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
None(?)
Fracture:
Irregular/Uneven
Density:
3.14 g/cm3 (Calculated)

Optical Data of KhomyakoviteHide

Type:
Uniaxial (-)
RI values:
nω = 1.628 nε = 1.625
Max Birefringence:
δ = 0.002
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate

Chemical Properties of KhomyakoviteHide

Formula:
Na12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2
IMA Formula:
Na12Sr3Ca6Fe3Zr3W(Si25O73)(O,OH,H2O)3(Cl,OH)2
Common Impurities:
K,Sr,Mn,Nb,(REE,Mg,Ti,Hf,Al)

Crystallography of KhomyakoviteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 14.259 Å, b = 30.084 Å
Unit Cell V:
5324.6 ų

Type Occurrence of KhomyakoviteHide

Synonyms of KhomyakoviteHide

Other Language Names for KhomyakoviteHide

Relationship of Khomyakovite to other SpeciesHide

Member of:
Other Members of this group:
AlluaiviteNa19(Ca,Mn)6(Ti,Nb)3Si26O74Cl · 2H2OTrig. 3m (3 2/m) : R3m
AndrianoviteNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5Trig. 3m : R3m
Aqualite(H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9ClTrig. 3 : R3
CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
DavinciiteNa12K3Ca6Fe2+3Zr3(Si26O73OH)Cl2 Trig. 3m : R3m
DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m
EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
FeklicheviteNa11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5Trig. 3m : R3m
FengchengiteNa123(Ca,Sr)6Fe3+3 Zr3Si(Si25O73)(H2O,OH)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m
GolysheviteNa10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3 · H2OTrig. 3m : R3m
Hydrorastsvetaevite(Na11(H3O)11K6(H2O)1.5Sr)Ca12Fe3Na2MnZr6Si52O144(OH)4.5Cl3.5Trig. 3m : R3m
Ikranite(Na,H3O)15(Ca,Mn2+)6Fe3+2Zr3-4[Cl|(H0-3Si3O9)2|{(Si9O27)2,(Si9O27)2SiO}] · 2-3H2OTrig. 3m : R3m
Ilyukhinite(H3O,Na)14Ca6Mn2Zr3Si26O72(OH)2·3H2OTrig. 3m : R3m
Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
ManganoeudialyteNa14Ca6Mn3Zr3[Si26O72(OH)2](H2O,Cl,O,OH)6Trig. 3m : R3m
ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
MogoviditeNa9(Ca,Na)12Fe2Zr3Si25O72(CO3) (OH)4Trig. 3m : R3m
OneilliteNa15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2Trig. 3 : R3
RaslakiteNa15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5[(Cl,OH)|(Si3O9)2|(Si9O27)2SiO] · 3(OH,H2O)Trig. 3
RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
SiudaiteNa8(Mn2+2Na)Ca6(Fe3+,Mn2+)3Zr3NbSi24(Si,◻,Ti)O74(OH)2Cl·5H2OTrig. 3m : R3m
TaseqiteNa12Sr3Ca6Fe3Zr3Nb[Cl2|(Si3O9)2|(Si9O27)2SiO] · 3(O,OH,H2O)Trig. 3m : R3m
UM1971-22-SiO:CaClFeHMgMnNaNbZrNa12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2[Si3O9]2ClTrig. 3m : R3m
UM1990-79-SiO:CaClFeHMnNaNbREEZrNa14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl)
UM1990-80-SiO:CaFeHMnNaNbREEZrNa14Ca4(Mn,Ca)2Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Mn,Al,Ti)3(Na,Ce,La,Y,Mn)(Na,H2O,K,Sr)(OH)7-8
UM1998-21-SiO:CaCeClHMnNaZrNa16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4Trig. 3m : R3m
UM1999-36-SiO:CaCeHMnNaNbSrZrNa17(Ca,Ce,Sr)2Mn3(Zr,Nb)4Si25O73(O,OH,F,Cl)5Trig. 3 : R3
UM2000-66-SiO:CaClFeHMnNaNbSrZrNa12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11Trig. 3m : R3m
UM2003-39-SiO:CaClFeHHfNaNbSrTaTiZrNa12(Na,K,Mn,Sr)2Ca5(Ca,Mn)(Zr,Hf)3(Fe,◻,Ta)3(Si,Nb,W)(Si,Al,Ti)Si24O72(OH,O)3.5Cl•1.2H2O
UM2004-51-SiO:CaClFFeHNaNbTiNa16Ca6(Fe,Mn)3Zr3(Ti,Nb)Si26O72FCl0.5•nH2OTrig. 3m : R3m
UM2006-17-SiO:CaClFFeHMnNaZrNa15(Ca3Mn3)Zr3(Fe,Zr)3SiSi(Si3O9)2(Si9O27)2O2(OH,F,Cl)3•2H2O
UM2006-18-SiO:CaClFFeHMnNaZrNa15Ca3(Mn,Fe)3Zr3(Zr,Na)3(Si,Nb)(S,Ti,Si)(Si3O9)2(Si9O27)2(O,OH)5(Cl,F,H2O)
UM2006-28-SiO:CaHMnNaZrNa33Ca12Zr6Mn3(Mn,Nb,Ti)2Si50O132(O,OH)12(OH,H2O,Cl)10
UM2010-06-SiO:CaFeHMnNaNbREETiZr[Na,(H3O)]15(Ca3Mn3)Na3Zr3(Si,Ti)[Si25O72OH](OH)2·2H2O
Unnamed (Eudialyte 3248)Na29Ca12Zr6[Si48O132(O,OH)12]{[Na]4[Si]2}{[Mn]3[Mn,Nb,Ti]2}(OH,H2O,Cl)10Trig. 3m (3 2/m) : R3m
Unnamed (Hydrated Hydrous Na-Ca-Mn-Fe-Zr-Ti Silicate Chloride)Na37Ca10Mn2FeZr6Si50(Ti,Nb)2O144(OH)5Cl3·H2OTrig. 3m : R3m
VoronkoviteNa15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2OTrig. 3 : R3
Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2OTrig. 3m : R3m

Related Minerals - Nickel-Strunz GroupingHide

9.CO.10AlluaiviteNa19(Ca,Mn)6(Ti,Nb)3Si26O74Cl · 2H2OTrig. 3m (3 2/m) : R3m
9.CO.10EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
9.CO.10FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
9.CO.10Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
9.CO.10ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
9.CO.10OneilliteNa15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2Trig. 3 : R3
9.CO.10RaslakiteNa15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5[(Cl,OH)|(Si3O9)2|(Si9O27)2SiO] · 3(OH,H2O)Trig. 3
9.CO.10FeklicheviteNa11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5Trig. 3m : R3m
9.CO.10CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
9.CO.10Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2OTrig. 3m : R3m
9.CO.10Ikranite(Na,H3O)15(Ca,Mn2+)6Fe3+2Zr3-4[Cl|(H0-3Si3O9)2|{(Si9O27)2,(Si9O27)2SiO}] · 2-3H2OTrig. 3m : R3m
9.CO.10TaseqiteNa12Sr3Ca6Fe3Zr3Nb[Cl2|(Si3O9)2|(Si9O27)2SiO] · 3(O,OH,H2O)Trig. 3m : R3m
9.CO.10RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
9.CO.10GolysheviteNa10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3 · H2OTrig. 3m : R3m
9.CO.10Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
9.CO.10Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
9.CO.10MogoviditeNa9(Ca,Na)12Fe2Zr3Si25O72(CO3) (OH)4Trig. 3m : R3m
9.CO.10GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m
9.CO.10Aqualite(H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9ClTrig. 3 : R3
9.CO.10DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m
9.CO.10AndrianoviteNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5Trig. 3m : R3m
9.CO.10VoronkoviteNa15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2OTrig. 3 : R3
9.CO.10UM1999-36-SiO:CaCeHMnNaNbSrZrNa17(Ca,Ce,Sr)2Mn3(Zr,Nb)4Si25O73(O,OH,F,Cl)5Trig. 3 : R3
9.CO.10UM2000-66-SiO:CaClFeHMnNaNbSrZrNa12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11Trig. 3m : R3m
9.CO.10ManganoeudialyteNa14Ca6Mn3Zr3[Si26O72(OH)2](H2O,Cl,O,OH)6Trig. 3m : R3m
9.CO.10UM1990-78-SiO:CaClFeHKNaZr(H3O)7(Na,K)5(Ca,Sr,Mn)6Zr3[Si3O7(O,OH)2]2[Si9O23(O,OH)4]2[SiNaFe(Zr,Ti,Al,Nb)□]Cl1.5(O,OH)Trig. 3m : R3m
9.CO.10UM1990-79-SiO:CaClFeHMnNaNbREEZrNa14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl)
9.CO.10UM1971-22-SiO:CaClFeHMgMnNaNbZrNa12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2[Si3O9]2ClTrig. 3m : R3m
9.CO.10UM1998-21-SiO:CaCeClHMnNaZrNa16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4Trig. 3m : R3m

Related Minerals - Dana Grouping (8th Ed.)Hide

64.1.2.1Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
64.1.2.2FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
64.1.2.3CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
64.1.2.4AndrianoviteNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5Trig. 3m : R3m
64.1.2.6ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
64.1.2.7Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
64.1.2.8GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for KhomyakoviteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Johnsen, O., Gault, R.A., Grice, J.D., Ercit, T.S. (1999) Khomyakovite and manganokhomyakovite, two new members of the eudialyte group, from Mont Saint-Hilaire, Quebec. The Canadian Mineralogist: 37: 893-899.
Khomyakov, A.P., Nechelyustov, G.N., Rastsvetaeva, R.K. (2007) Aqualite, (H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9Cl, a new eudialyte-group mineral from Inagli alkaline massif (Sakha-Yakutia,Russia),and the problem of oxonium in hydrated eudialytes. Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva (Proceedings of the Russian Mineralogical Society): 136(2): 39-55.

Internet Links for KhomyakoviteHide

Localities for KhomyakoviteHide

ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Johnsen, O., Gault, R.A., Grice, J.D. & Ercit, T.S. (1999), Khomyakovite and manganokhomyakovite, two new members of the eudialyte group from Mont St.-Hilaire, Quebec, Canada, Canadian Mineralogist: 37: 893-899.
Mineral and/or Locality  
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