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Mutinaite

A valid IMA mineral species
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Formula:
Na3Ca4Si85Al11O192 · 60H2O
Colour:
Colorless to milky white
Lustre:
Vitreous, Silky
Specific Gravity:
2.13
Crystal System:
Orthorhombic
Member of:
Name:
Named after Mutina, the ancient Latin name of Modena, Italy, a center of zeolite research.
The natural counterpart of zeolite ZSM-5 (ZSM-5 - Zeolite Socony Mobil–5).

The ZSM-5 molecular sieve boasts unique and exceptional properties, which are widely employed in important processes and applications across a broad range of industries. Commonly used in converting methanol to gasoline and diesel as well as oil refining, ZSM-5 has proved superior to amorphous solid acid catalysts in reactions such as xylene isomerization, toluene disproportionation and toluene alkylation etc. Upon ion exchange or modification, H-ZSM-5 zeolites can be derived to also possess enhanced para-selectivity. All in all, the high versatility of this zeolite makes it a truly indispensable material across many industries.


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Unique IdentifiersHide

Mindat ID:
7184
Long-form identifier:
mindat:1:1:7184:6
GUID
(UUID V4):
27530265-9749-4c91-9a29-37a3115d007e

IMA Classification of MutinaiteHide

Classification of MutinaiteHide

9.GF.35

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
F : Other Rare Zeolites

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
MutIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MutinaiteHide

Vitreous, Silky
Transparency:
Transparent
Colour:
Colorless to milky white
Streak:
white
Tenacity:
Brittle
Cleavage:
Distinct/Good
good {100}
Fracture:
Irregular/Uneven
Density:
2.13(3) g/cm3 (Measured)    2.17 g/cm3 (Calculated)

Optical Data of MutinaiteHide

Type:
Biaxial (-)
RI values:
nα = 1.485(2) nβ = 1.487(2) nγ = 1.488(2)
2V:
Measured: 70° , Calculated: 70°
Max Birefringence:
δ = 0.003
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
none
Comments:
2V could not be measured

Chemistry of MutinaiteHide

Mindat Formula:
Na3Ca4Si85Al11O192 · 60H2O

Crystallography of MutinaiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 20.223(7) Å, b = 20.052(8) Å, c = 13.491(5) Å
Ratio:
a:b:c = 1.009 : 1 : 0.673
Unit Cell V:
5,470.76 ų (Calculated from Unit Cell)
Twinning:
none

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009842Mutinaitevan Koningsveld H (1990) High-temperature (350 K) orthorhombic framework structure of zeolite H-ZSM-5 Acta Crystallographica B46 731-7351990synthetic0293
0010960MutinaiteTaylor J C, Miller S A, Bibby D M (1986) A study of decomposition methods for refinement of H+-ZSM5 zeolite with powder diffraction data Zeitschrift fur Kristallographie 176 183-1921986synthetic0293
0015873MutinaiteVezzalini G, Quartieri S, Galli E, Alberti A, Cruciani G, Kvick A (1997) Crystal structure of the zeolite mutinaite, the natural analog of ZSM-5 Zeolites 19 323-3251997Mt. Adamson, Northern Victoria Land, Antarctica0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
11.20 Å(84)
9.98 Å(35)
3.85 Å(100)
3.75 Å(98)
3.67 Å(27)
3.00 Å(32)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
10 : Basalt-hosted zeolite minerals

Type Occurrence of MutinaiteHide

General Appearance of Type Material:
subspherical aggregates (up to 1.8 mm in diameter)
Place of Conservation of Type Material:
holotype material has been deposited at the Museo di Storia Naturale e de1 Territorio, University of Pisa, Italy, with accession number 15520.
Geological Setting of Type Material:
Dolerite above sedimentary rock
Associated Minerals at Type Locality:
Reference:
Galli, E., Vezzalini, G., Quartieri, S., Alberti, A., & Franzini, M. (1997). Mutinaite, a new zeolite from Antarctica: The natural counterpart of ZSM-5. Zeolites, 19(5-6), 318-322.

Synonyms of MutinaiteHide

Other Language Names for MutinaiteHide

German:Mutinait
Spanish:Mutinaita

Relationship of Mutinaite to other SpeciesHide

Member of:
Other Members of this group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet. 4/m : I41/a
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
Brewsterite SubgroupZeolite Group.
Chabazite-Levyne SubgroupM[Al2Si4O12] · 6H2O
ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
Clinoptilolite SubgroupM3-6(Si30Al6)O72 · 20H2O
CowlesiteCaAl2Si3O10 · 6H2OOrth. mmm (2/m 2/m 2/m)
Dachiardite SubgroupZeolite Group.
DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 2 2 2 : P21 21 21
EpistilbiteCaAl2Si6O16 · 5H2OMon.
Erionite SubgroupM2[Al4Si14O36] · 15H2O
Faujasite SubgroupM3.5[Al7Si17O48] · 32H2O
Ferrierite SubgroupZeolite Group.
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite Subgroup
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine SubgroupZeolite Group.
Gmelinite SubgroupIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm (2/m 2/m 2/m) : Pnma
GoosecreekiteCa[Al2Si6O16] · 5H2OMon. 2 : P21
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm (2/m 2/m 2/m) : Cmca
Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 4 3 2 : I41 3 2
KirchhoffiteCs(BSi2O6)Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
Loomisite Ba[Be2P2O8] · H2OMon. m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
Mazzite SubgroupZeolite Group.
Merlinoite(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2OOrth. mmm (2/m 2/m 2/m) : Immm
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth. mm2 : Fdd2
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
NabesiteNa2BeSi4O10 · 4H2OOrth. 2 2 2 : P21 21 21
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6 m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 2 3 : I2 3
ParthéiteCa2(Si4Al4) O15 (OH)2 · 4H2OMon. 2/m : B2/b
Paulingite SubgroupPaulingite was originally described in 1960.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
Phillipsite SubgroupZeolite Group.
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m (4/m 3 2/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mcm
Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite SubgroupThe large majority of "thomsonite" is thomsonite-Ca.
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m (4/m 3 2/m) : Fm3m
UM1996-38-SiO:AlCaHNaNa-Ca-Al-Si-O-H
UM1999-33-SiO:AlHKNaK7Na5Al12Si20O64 · 24H2O
UM2002-40-SiO:AlCaHKMgNa(Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2OTet. 4 2 2 : P41 2 2
Unnamed (Ca analogue of Merlinoite)(Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m : B2/m
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6 m2 : P62m
WillhendersoniteKCa[Al3Si3O12] · 5H2OTric. 1 : P1
YugawaraliteCaAl2Si6O16 · 4H2OMon. m : Pb

Related Minerals - Strunz-mindat GroupingHide

9.GF.05Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
9.GF.10GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm (2/m 2/m 2/m) : Cmca
9.GF.15LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
9.GF.20GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
9.GF.25ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
9.GF.25FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
9.GF.30Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
9.GF.40TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m (4/m 3 2/m) : Fm3m
9.GF.50Thornasite(Na,K)12Th3[Si8O19]4 · 18H2OTrig. 3m : R3m
9.GF.55DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
9.GF.60MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m (4/m 3 2/m) : Im3m
9.GF.65RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m

Fluorescence of MutinaiteHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MutinaiteHide

References for MutinaiteHide

Localities for MutinaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Antarctica (TL)
 
  • Eastern Antarctica
    • Victoria Land
American Mineralogist +1 other reference
 
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