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Phillipsite-K

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William Phillips
Formula:
(K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O
Colour:
White
Lustre:
Vitreous
Hardness:
4 - 5
Crystal System:
Monoclinic
Name:
Named after William Phillips (1775-1828), English mineralogist and founder of the Geologial Society of London. The K-dominant member of the phillipsite series.
Hide all sections | Show all sections

Classification of Phillipsite-KHide

Approved
9.GC.10

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
C : Chains of doubly-connected 4-membered rings

Physical Properties of Phillipsite-KHide

Vitreous
Colour:
White
Streak:
White
Hardness:
4 - 5 on Mohs scale

Optical Data of Phillipsite-KHide

Type:
Biaxial (+/-)
RI values:
nα = 1.483 - 1.505 nβ = 1.484 - 1.511 nγ = 1.486 - 1.514
2V:
Measured: 60° to 90°, Calculated: 70° to 72°
Max Birefringence:
δ = 0.003 - 0.009
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v or r < v

Chemical Properties of Phillipsite-KHide

Formula:
(K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O
IMA Formula:
K6(Si10Al6)O32 · 12H2O

Crystallography of Phillipsite-KHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Cell Parameters:
a = 9.8881 Å, b = 14.4040 Å, c = 8.6848 Å
β = 124.2711°
Ratio:
a:b:c = 0.686 : 1 : 0.603
Unit Cell V:
1,022.20 ų (Calculated from Unit Cell)
Comment:
Data from Gualtieri (2000).

X-Ray Powder DiffractionHide

Image Loading

Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Type Occurrence of Phillipsite-KHide

Other Language Names for Phillipsite-KHide

Relationship of Phillipsite-K to other SpeciesHide

Other Members of this group:
Phillipsite-Ca(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32 . 12H2OMon. 2/m : P21/m
Phillipsite-Na(Na,K,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] · 12H2OMon.
Forms a series with:

Common AssociatesHide

Associated Minerals Based on Photo Data:
Calcite12 photos of Phillipsite-K associated with Calcite on mindat.org.
Nordstrandite11 photos of Phillipsite-K associated with Nordstrandite on mindat.org.
Baryte8 photos of Phillipsite-K associated with Baryte on mindat.org.
Chabazite-K8 photos of Phillipsite-K associated with Chabazite-K on mindat.org.
Thomsonite-Ca7 photos of Phillipsite-K associated with Thomsonite-Ca on mindat.org.
Phillipsite-Ca6 photos of Phillipsite-K associated with Phillipsite-Ca on mindat.org.
Hydrotalcite6 photos of Phillipsite-K associated with Hydrotalcite on mindat.org.
Motukoreaite5 photos of Phillipsite-K associated with Motukoreaite on mindat.org.
Faujasite Subgroup5 photos of Phillipsite-K associated with Faujasite Subgroup on mindat.org.
Magnesio-hornblende5 photos of Phillipsite-K associated with Magnesio-hornblende on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

9.GC.05AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
9.GC.05Garronite-CaNa2Ca5Al12Si20O64 · 27H2OTet. 4 2m : I4m2
9.GC.05Gismondine-CaCaAl2Si2O8 · 4H2O
9.GC.05GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth.
9.GC.10Harmotome(Ba0.5,Ca0.5,K,Na)5[Al5Si11O32] · 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-Ca(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32 . 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-Na(Na,K,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] · 12H2OMon.
9.GC.10Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
9.GC.15Merlinoite(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2OOrth.
9.GC.20Mazzite-Mg(Mg,K,Ca)5(Si26Al10)O72 · 28H2OHex.
9.GC.20Mazzite-NaNa8[Al4Si14O36]2 · 30H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GC.25PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex.
9.GC.30BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
9.GC.35Paulingite-Ca(Ca,K,Na,Ba,◻)10 (Si, Al)42O84•34H2OIso.
9.GC.35Paulingite-K(K2,Ca,Na2,Ba)5[Al10Si35O90] · 45H2OIso.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Phillipsite-KHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Steinfink, H. (1962): The crystal structure of the zeolite, phillipsite. Acta Crystallogr., 15, 644-652.
American Mineralogist (1972): 57: 1125-1145.
Rinaldi, R., Pluth, J. J. and Smith, J. V. (1974): Zeolites of the phillipsite family. Refinement of the crystal structures of phillipsite and harmotome. Acta Crystallogr., B30, 2426-2433.
Mineralogical Magazine (1998): 62: 553-554.
Gualtieri, A.F. (2000): Accuracy of XRPD QPA using the combined Rietveld-RIR method. Journal of Applied Crystallography 33, 267-278.
Gatta, G. D., Cappelletti, P. & Langella, A. (2010): Crystal-chemistry of phillipsites from the Neapolitan Yellow Tuff. European Journal of Mineralogy 22, 779-786.

Internet Links for Phillipsite-KHide

Localities for Phillipsite-KHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Gloucester Co.
      • Barrington Tops
        • Barrington
Graham, I. T., Pogson, R. E. and Colchester, D. (2002): Cowlesite and associated minerals from the Barrington Tops area, New South Wales. Australian J. Mineral. 8, 3-8.
    • Westmoreland Co.
      • Oberon
Graham, I. T., Colchester, D. and Pogson, R. E. (2002): Phillipsite and associated minerals from Hargraves quarry, Oberon, New South Wales. Australian Journal of Mineralogy 8, 29-32.
  • South Australia
    • Eyre Peninsula
      • Middleback Range
        • Iron Knob
Francis, G. A. (2010): Minerals of Iron Monarch.
  • Victoria
    • Hepburn Shire
      • Trentham
W.D.Birch 1989. Zeolites of Victoria, The Mineralogical Association Of Victoria No. 2 pp. 75-84,100; J.D.Hollis. 1979. Some little known zeolite localities in central Victoria. The Australian Mineralogist No.21 April 1979, pp. 101-102
Austria
 
  • Burgenland
    • Oberpullendorf
      • Kobersdorf
        • Pauliberg
U. Kolitsch, W. Postl, H.-P. Bojar and W. Trattner (2009): Die Mineralvorkommen im Basalt des Pauliberges. In: Autorenkollektiv (Red. M. A. Götzinger und P. Huber) (2009): Die Mineralien des Burgenlandes - Geologie, Mineralogie und mineralische Rohstoffe. – Wissenschaftliche Arbeiten aus dem Burgenland, Band 126, Amt der Burgenländischen Landesregierung, Abteilung 7 - Landesmuseum, Eisenstadt, 83-99.
  • Styria
    • Bad Gleichenberg
      • Wilhelmsdorf
Postl, W. et al. (2008)
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Tschernich, R. (1992): Zeolites of the World, p.414., Horváth, L and Gault, R.A. (1990), The mineralogy of Mont Saint-Hilaire Quebec. Mineralogical Record: 21: 284-359.
      • Lajemmerais RCM
        • Varennes & St-Amable
          • Saint-Amable sill
HORVÁTH, L. (2010) The minerals of the Saint-Amable sill: an update. MICRONEWS 44(4), 23-28.
Cyprus
 
  • Larnaca District (Larnaka District; İskele District)
Prüfer, P. (2011): Mineralien der Insel Zypern (2). Der Aufschluss 62, 175-186 (in German).
Czech Republic
 
  • Bohemia (Böhmen; Boehmen)
    • Karlovy Vary Region
      • Krušné Hory Mts (Erzgebirge)
        • Ostrov
Pauliš P., Dvořák Z., Svejkovský J., Malíková R., Pour O., Soumar J. (2015) Böhmit z klasického naleziště zeolitů Horní Hrad v Krušných horách (Česká republika). Bull. mineral.-petrolog. Odd. Nár. Muz. (Praha) 23, 1, 60-62. ISSN 1211- 0329.
    • Liberec Region
      • Česká Lípa (Böhmisch Leipa)
P.Pauliš,L.Hrůzek,O.Janeček,J.Sejkora,R.Malíková,F.Fedyuk-Zeolite mineralization from Nový Oldřichov near Kamenický Šenov (Czech republic).Bulletin mineralogicko-petrologického oddělení Národního muzea v Praze,vol.24,num.1(Prag 2016) P.Pauliš,L.Hrůzek,O.Janeček,Z.Dvořák,J.Toman-The most interesting mineralogical localities of Bohemia zeolities and accompanying mineralization-Kuttna 2014
P.Pauliš,L.Hrůzek,O.Janeček,J.Sejkora,R.Malíková,O.Pour,F.Fedyuk-Zeolite mineralization from Svor near Nový Bor (Czech rep.).Bulletin mineralogicko-petrologického oddělení Národního muzea v Praze 24,2,2016,(Prag 2016)
    • Ústí Region
      • Litoměřice
P.Zeman,P.Pauliš,P.Pour,R.Malíková (2017) Zeolites of Pohorský Hill and district. mag.Minerál 2017/2
  • Moravia (Mähren; Maehren)
    • South Moravia Region
      • Moravský Krumlov
        • Jamolice
Hrazdil, V.: Minerální asociace alpských žil od Templštejna u Jamolic, západní Morava. Acta Musei Moraviae, Scientiae geologicae, 2001, roč. 86, s. 75 - 84.
France
 
  • Auvergne-Rhône-Alpes
    • Puy-de-Dôme
      • Brousse
Leconte J. (2015) La carrière de Montboissier, Brousse, Puy-de-Dôme. In ʺLa revue des Micromonteursʺ n°23 – p.33-54.
Germany
 
  • Baden-Württemberg
    • Kaiserstuhl
      • Sasbach
WEISENBERGER, T. & SPÜRGIN, S. (2009): Zeolites in alkaline rocks of the Kaiserstuhl Volcanic Complex, SW Germany – new microprobe investigation and the relationship of zeolite mineralogy to the host rock. Geologica Belgica, 12, 75-91.
  • Bavaria
    • Franconia
      • Fichtelgebirge
        • Selb
          • Längenau
Keck, E. (2008): Der Wartberg bei Längenau, nordöstlich von Selb, in Oberfranken. Aufschluss 59, 109-128.
    • Upper Palatinate
      • Kemnath
        • Waldeck
Pöllmann et al. (2007): Aufschluss 58, 227-233.
  • Hesse
    • Greifenstein
      • Allendorf
Betz, V., Leinweber, A., Klein, E. und Wahl, H. (2011): Prächtige Zeolithe: Die Mineralien des Steinbruchs "Alter Stein" bei Allendorf im Ulmtal, Westerwald, Hessen. Lapis, 36 (2), 15-38; 54.
    • Vogelsberg
      • Nidda
Doelter, C. (1921) Handbuch der Mineralchemie, Band 2, 3. Teil 472 pp, Dresden und Leipzig
  • Rhineland-Palatinate
    • Eifel
      • Andernach
        • Nickenich
Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
      • Daun
        • Üdersdorf
[Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag München, 1983] [Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors]
      • Gerolstein
        • Roth
Blaß, G. & Schüller, W. (2012): Der Rother Kopf in der Vulkaneifel. Lapis, 37 (3), 20-29.
      • Hillesheim
Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
      • Kelberg
        • Drees
Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
        • Höchstberg
Blass, G., Graf, H.W., Kolitsch, U., Neue Funde aus der Vulkaneifel - ein Rückblick auf die Sammelsaison 2002, Mineralien-Welt 13/5, 2003
      • Laach lake volcanic complex
        • Mendig
          • Niedermendig
- Blass, G., (2010): Die neuen Mineralienfunde aus der Vulkaneifel, Mineralienwelt, Vol. 05
      • Mayen
        • Ettringen
          • Bellerberg volcano
Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
      • Niederzissen
        • Brenk
Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
        • Glees
- Blass, G., (2010): Die neuen Mineralienfunde aus der Vulkaneifel, Mineralienwelt, Vol. 05
    • Siegerland
      • Herdorf
        • Malscheid (Mahlscheid; Mahlscheiderkopf; Mahlscheider Kopf)
Klein, E. (2011): Der Steinbruch Mahlscheid bei Herdorf im Siegerland. Mineralien Welt. 22 (3): 28-35
  • Saxony
    • Erzgebirge
      • Niederschlag-Bärenstein District
        • Bärenstein
T. Witzke (1994): Neufunde aus Sachsen (II): Nordstrandit vom Bärenstein bei Annaberg in Sachsen.- Lapis 19, 10, 36-39 (XRD and SEM-EDX analysis)
Hungary
 
  • Nógrád Co.
    • Mátra Mts
      • Hasznos
GEODA, 2002
  • Veszprém Co.
    • Balaton Uplands
      • Tapolcai Basin
        • Zalahaláp
Kónya, P. and Szakáll, S. (2011): Occurrence, composition and paragenesis of the zeolites and associated minerals in the alkaline basalt of a maar-type volcano at Haláp Hill, Balaton Highland, Hungary. Mineralogical Magazine 75, 2869-2885.
Italy
 
  • Campania
    • Naples Province
      • Somma-Vesuvius Complex
        • Monte Somma
          • Ercolano
            • San Vito
Russo, M., Punzo, I. (2004): I minerali del Somma-Vesuvio, AMI
          • Pollena - Trocchia area
Russo, M., Punzo, I. (2004): I Minerali del Somma-Vesuvio, AMI
          • Sant'Anastasia
Russo, M., Punzo, I. (2004): I minerali del Somma-Vesuvio, AMI
        • Mt Vesuvius
          • Terzigno
Luigi Chiappino data
          • Torre del Greco
Russo, M. (2003): Mineralogia Vesuviana - Villa Inglese. Micro (località), 2003, 1-10
  • Latium
    • Rome Province
The Canadian Mineralogist Vol. 35, pp. 1571-1606 (1997)
      • Rome
        • Valleranello
Gualtieri, A.F. (2000): Accuracy of XRPD QPA using the combined Rietveld-RIR method. Journal of Applied Crystallography, 33, 267-278.
    • Viterbo Province
      • Làtera volcano
        • Onano
Cresta, S., Duronio, F., Mancinella, D. (2002): Geositi e sistema delle arre protette del Lazio: idee per la geoconservazione. Il Cercapietre, 1-2/2002, 48-55 M.E. Ciriotti (G. Blass analysis) 2007.
      • Vico Lake
AMI UK service
Ciriotti, M.E. & Biagioni, C. (2011): Pot-pourri 2011: identificazioni di minerali di interesse. Micro, 3/2011, 125-133
  • Liguria
    • Genova Province
      • Tiglieto
Balestra C. (2014): Sistematica ligure 2014. Prie, 10, 35-37.
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Baveno
        • Oltrefiume
          • Mount Camoscio
Grill, E. (1935): I minerali del granito di Baveno, la fayalite. Periodico di Mineralogia, 129-133. - Gallitelli, P. (1936): Le miche del granito di Baveno. . Periodico di Mineralogia, 61-76 - Pagliani, G. (1948): Le Zeoliti del granito di Baveno. Periodico di Mineralogia, 175-188. - Ravagnani, D. (1974): I giacimenti uraniferi italiani - Gruppo Mineralogico Lombardo - Museo Civico di Storia Naturale di Milano, Ed., Milano, 188 pp. - min. Rec. 14 (3), 157-168 - Am. Min. 83, 1330-1334 (1998) - Am. Min. 84, 782-789 (1999). - Guastoni, A. & Pezzotta, F. (2004): Kristiansenite a Baveno, second ritrovamento Mondiale della specie. Rivista Mineralogica Italiana, 4/2004, 247-251. - Guastoni, A., Demartin, F., Pezzotta, F. (2004): Sekaninaite delle pegmatiti granitiche di Feriolo e Baveno (VB). Atti della Società Italiana di Scienze Naturali e del Museo Civico di Storia Naturale di Milano, 145, 59-68. - Mineralogist americano (2005) 90, 1442-1452.
sergio varvello collection
  • Sicily
    • Catania Province
      • Northern Iblean plateau
Sicurella, G., Russo, S., Ciriotti, M.E., Blass, G. (2010): Mineralogia della formazione di Monte Caliella, Palagonia (Catania, Sicilia). Micro (località), 2/2010, 371-408
Sicurella, G., Russo, S., Ciriotti, M.E., Blass, G. (2010): Mineralogia della formazione di Monte Caliella, Palagonia (Catania, Sicilia). Micro (località), 2/2010, 371-408.
  • Tuscany
    • Grosseto Province
      • Pitigliano
AMI UK service
  • Veneto
    • Vicenza Province
      • Fara Vicentino
        • San Giorgio di Perlena
Boscardin M.,Daleffe A.,Rocchetti I., Zordan A. (2011) " Minerali del Vicentino - Aggiornamenti, località e nuove determinazioni " Museo di Archeologia e Scienze Naturali “G. Zannato” – Montecchio Maggiore (Vicenza), pp.183
Japan
 
  • Honshu Island
    • Chugoku region
      • Shimane Prefecture
        • Hamada City
Matsubara, S. et al (1998) Koubutsugaku Zasshi, 27, 195-202.
New Zealand
 
  • South Island
    • Canterbury
S. J. Mills, Museum Victoria
    • Otago
      • Dunedin
Graham, I.T. , Pogson, R.E., Colchester, D.M. & Baines, A. (2003) Zeolite crystal habits , composition, and paragenesis; Blackhead Quarry, Dunedin, New Zealand - Mineralogical Magazine, 67, 625-737
J. Thornton in Micro-Scope, March 2007
Russia
 
  • Northern Region
    • Murmanskaya Oblast'
      • Khibiny Massif
PEKOV, I.V. & NIKOLAEV, A.P. (2013) Minerals of the pegmatites and hydrothermal assemblages of the Koashva deposit (Khibiny, Kola Peninsula, Russia). Mineralogical Almanac 189(2), 7-65.
Pekov, I.V. & Podlesnyi, A.S. (2004): Kukisvumchorr Deposit: Mineralogy of Alkaline Pegmatites and Hydrotermalites. Mineralogical Almanac, vol. 7, 140 pages + xxiv photo's pages
www.koeln.netsurf.de/~w.steffens/lovo.htm
Yakovenchik, V.N., Ivaniuk, G.Yu., Pakhomovsky, Ya.A., Selivanova, E.A., Men'shikov, Yu.P., Korchak, J.A., Krivovichev, S.V., Spiridonova, D.V., Zalkind, O.A. (2010): Punkaruaivite, Li{Ti2(OH)2[Si4O11(OH)]}•H2O, a new mineral species from hydrothermalites of Khibiny and Lovozero alkaline massifs (Kola Peninsula, Russia). Canadian Mineralogist, 48, 41-50.
        • Suoluaiv Mt
Igor Pekov data
  • Urals Region
    • Middle Urals
      • Sverdlovskaya Oblast'
        • Asbest
Antonov A.A. [Антонов А.А.] (2003): Mineralogy of rodingites of the Bazhenovsk ultrabasic massif [Минералогия родингитов Баженовского гипербазитого массива]. Nauka, Sankt-Peterburg, 129 pp. (in Russian).
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Santa Cruz de Tenerife
          • Anaga Mts.
Analyzed by XRD by Dr. Joan Vinals (Barcelona)- Col. Agustin Agudo Espinosa
  • Castile-La Mancha
    • Ciudad Real
      • Campo de Calatrava volcanoes
Calvo, M., Viñals, J., Sanz, A. and Martí, J. (2013). Zeolites and asociated minerals in the vacuoles of some of the Campo de calatrava volcanoes - Ciudad Real, Spain. Mineral Up,3, 54-69
Switzerland
 
  • Grischun (Grisons; Graubünden)
    • Vorderrhein Valley
      • Tujetsch (Tavetsch)
        • Strem Valley
Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Wepf (Basel), p. 302.
USA
 
  • Arizona
    • Maricopa Co.
AM61_853
  • Hawaii
    • Honolulu Co.
      • Oahu Island
        • Honolulu
Dunham, K.C. (1933): Crystal cavities in lavas from the hawaiian islands, The American Mineralogist, Vol. 18, 369-385.
  • Oregon
    • Clackamas Co.
      • Clackamas River localities
Tschernich, R. (1992): Zeolites of the World: 423; Howard, Don & Thornton, Jocelyn (1998) MicroProbe: 8(7), Spring 1998: 7-9; Tschernich, Rudy (2001) MicroProbe: 9(9), Spring 2001: 20-23; Gladwell, Jon ( ), Crystals & Minerals, Vol 3: 24-25.
    • Tillamook Co.
Micro Probe Volume VI Number 4
  • Washington
    • Douglas Co.
Tschernich (1991): Zeolites of Washington State. Rock & Minerals, 66(4); American Mineralogist, Volume 67, pages 799-803, 1982
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