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Calcioancylite-(Ce)

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Formula:
(Ce,Ca,Sr)Ce(CO3)(OH,H2O)
Lustre:
Vitreous, Greasy
Hardness:
4 - 4½
Crystal System:
Orthorhombic
Member of:
Name:
From the Greek αγκυλός ("ankylos") for "curved", in allusion to its usually rounded and distorted crystal shapes, and the prefix "CALCIO-" in allusion to its composition with CALCIum dominant over strontium, plus the "-(Ce)" suffix due to cerium being the dominant REE.
The calcium analogue of Ancylite-(Ce). The cerium analogue of Calcioancylite-(Nd).

Note: The precise type locality is unknown - the mineral was found at an unspecified place in "Western Lands" (Western Russia or possibly Finland) in a glacial erratic boulder of unknown source; for details and discussion see Pekov (1998).


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Classification of Calcioancylite-(Ce)Hide

Approved, 'Grandfathered' (first described prior to 1959)
5.DC.05

5 : CARBONATES (NITRATES)
D : Carbonates with additional anions, with H2O
C : With large cations
16b.1.1.2

16b : HYDRATED CARBONATES CONTAINING HYDROXYL OR HALOGEN
1 : AmBn(XO3)pZqxH2O & with (m+n):p = 1:1
11.8.13

11 : Carbonates
8 : Carbonates of the rare earths

Physical Properties of Calcioancylite-(Ce)Hide

Vitreous, Greasy
Transparency:
Translucent
Hardness:
4 - 4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Splintery

Optical Data of Calcioancylite-(Ce)Hide

Type:
Biaxial (-)
RI values:
nα = 1.654 nβ = 1.733 nγ = 1.772
2V:
Measured: 60° to 70°, Calculated: 66°
Max Birefringence:
δ = 0.118
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r < v

Chemical Properties of Calcioancylite-(Ce)Hide

Formula:
(Ce,Ca,Sr)Ce(CO3)(OH,H2O)
IMA Formula:
(Ce,Ca,Sr)CO3(OH,H2O)

Crystallography of Calcioancylite-(Ce)Hide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:
a = 5.0095(1) Å, b = 8.5006(1) Å, c = 7.2670(1) Å
Ratio:
a:b:c = 0.589 : 1 : 0.855
Unit Cell V:
309.46 ų
Comment:
Space group Pmcn (non-standard setting).

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.54 (30)
4.32 (75)
3.66 (40)
2.94 (100)
2.33 (45)
2.07 (35)
2.00 (30)

Other Language Names for Calcioancylite-(Ce)Hide

Relationship of Calcioancylite-(Ce) to other SpeciesHide

Member of:
Other Members of this group:
Ancylite-(Ce)CeSr(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
Ancylite-(La)LaSr(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
Calcioancylite-(Nd)Ca(Nd,La,Ce)(CO3)2(OH).H2OMon. m : Pm
Gysinite-(Nd)PbNd(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
Kozoite-(La)(La,Nd)(CO3)(OH)Orth.
Kozoite-(Nd)(Nd,La,Sm,Pr)(CO3)(OH)Orth. mmm (2/m 2/m 2/m)
Unnamed (Ce-analogue of Kozoite-(La) and -(Nd))(Ce,La)(CO3)(OH)Orth.

Common AssociatesHide

Associated Minerals Based on Photo Data:
Microcline5 photos of Calcioancylite-(Ce) associated with Microcline on mindat.org.
Micheelsenite3 photos of Calcioancylite-(Ce) associated with Micheelsenite on mindat.org.
Rémondite3 photos of Calcioancylite-(Ce) associated with Rémondite on mindat.org.
Calcite2 photos of Calcioancylite-(Ce) associated with Calcite on mindat.org.
Aegirine2 photos of Calcioancylite-(Ce) associated with Aegirine on mindat.org.
Fluorapatite1 photo of Calcioancylite-(Ce) associated with Fluorapatite on mindat.org.
Titanite1 photo of Calcioancylite-(Ce) associated with Titanite on mindat.org.
Tuperssuatsiaite1 photo of Calcioancylite-(Ce) associated with Tuperssuatsiaite on mindat.org.
Cascandite1 photo of Calcioancylite-(Ce) associated with Cascandite on mindat.org.
Stilbite1 photo of Calcioancylite-(Ce) associated with Stilbite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

5.DC.05Ancylite-(Ce)CeSr(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
5.DC.05Calcioancylite-(Nd)Ca(Nd,La,Ce)(CO3)2(OH).H2OMon. m : Pm
5.DC.05Gysinite-(Nd)PbNd(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
5.DC.05Ancylite-(La)LaSr(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
5.DC.05Kozoite-(Nd)(Nd,La,Sm,Pr)(CO3)(OH)Orth. mmm (2/m 2/m 2/m)
5.DC.05Kozoite-(La)(La,Nd)(CO3)(OH)Orth.
5.DC.10Kamphaugite-(Y)Ca(Y,REE)(CO3)2(OH) · H2OTet. 4 2 2 : P41 21 2
5.DC.15SheldrickiteNaCa3(CO3)2F3 · H2OTrig. 3 : P32
5.DC.20Thomasclarkite-(Y)(Na,Ce)(Y,REE)(HCO3)(OH)3 · 4H2OMon. 2 : P2
5.DC.25Peterbaylissite(Hg+2)1.5(CO3)(OH) · 2H2OOrth.
5.DC.30Clearcreekite(Hg+2)1.5(CO3)(OH) · 2H2OMon.
5.DC.35NiveolaniteNaBe(CO3)(OH) · 2H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mcc

Related Minerals - Dana Grouping (8th Ed.)Hide

16b.1.1.1Ancylite-(Ce)CeSr(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
16b.1.1.3Calcioancylite-(Nd)Ca(Nd,La,Ce)(CO3)2(OH).H2OMon. m : Pm
16b.1.1.4Gysinite-(Nd)PbNd(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

11.8.1Calkinsite-(Ce)(Ce,La)2(CO3)3 · 4H2OOrth.
11.8.2Lanthanite-(La)(La,Ce)2(CO3)3 · 8H2OOrth.
11.8.3Lanthanite-(Ce)(Ce,La,Nd)2(CO3)3 · 8H2OOrth. mmm (2/m 2/m 2/m)
11.8.4Lanthanite-(Nd)(Nd,La)2(CO3)3 · 8H2OOrth.
11.8.5Hydroxylbastnäsite-(Ce)Ce(CO3)(OH)Hex. 6 : P6
11.8.6Hydroxylbastnäsite-(Nd)Nd(CO3)(OH)Hex.
11.8.7Hydroxylbastnäsite-(La)(La,Nd,Ce)(CO3)(OH,F)Hex.
11.8.8Rémondite-(Ce)Na3(Ce,La,Ca,Na,Sr)3(CO3)5Mon. 2 : P21
11.8.9Tengerite-(Y)Y2(CO3)3 · 2-3H2OOrth. mmm (2/m 2/m 2/m) : Pnnm
11.8.10Kimuraite-(Y)Ca(Y,Nd)2(CO3)4 · 6H2OOrth.
11.8.11Lokkaite-(Y)Ca(Y,Gd,Nd,Dy)4(CO3)7 · 9H2OOrth.
11.8.12Calcioancylite-(Nd)Ca(Nd,La,Ce)(CO3)2(OH).H2OMon. m : Pm
11.8.14Burbankite(Na,Ca)3(Sr,Ba,Ce)3(CO3)5Hex. 6mm : P63mc
11.8.15Khanneshite(Na,Ca)3(Ba,Sr,Ce,Ca)3(CO3)5Hex.
11.8.16Donnayite-(Y)NaCaSr3Y(CO3)6 · 3H2OTric. 1 : P1
11.8.17Carbocernaite(Ca,Na)(Sr,Ce,Ba)(CO3)2Orth. mm2
11.8.18Ancylite-(Ce)CeSr(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
11.8.19EwalditeBa(Na,Ca,Y,Ce,K)(CO3)2 · 2.6H2OHex. 6mm
11.8.20Mckelveyite-(Y)NaCaBa3Y(CO3)6 · 3H2OTric. 1 : P1
11.8.21Sahamalite-(Ce)(Mg,Fe)(Ce,La,Nd)2(CO3)4Mon. 2/m : P21/b

Other InformationHide

Notes:
Readily soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Calcioancylite-(Ce)Hide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Tschernik, G.P. (1904) Verh. min. Ges. St. Petersburg: 41: 43 (as Eisenkalkankylit, Mangankalkankylit).
Chernik, G.P. (1904) The nature and chemical composition of a new cerian ancylite-like mineral. Zapiski Imperatorskogo Mineralogichsekogo Obshchestva, 71,43-54.
Palache, C., Berman, H., and Frondel, C. (1951) The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged: 291-293.
Mineralogical Record (1987) 18: 203.
American Mineralogist (1987) 72: 1031 (Appendix 2).
Pekov, I.V., Peterson, O.V., and Voloshin, A.V. (1997) Calcio-ancylite-(Ce) from Ilimaussaq and Narssarssuk, Greenland, Kola peninsula and Polar Urals, Russia; ancylite-(Ce)-calcio-ancylite-(Ce) an isomorphous series. Neues Jahrbuch for Mineralogie, Abhandlungen, 171, 309-322.
Pekov, I.V. (1998) Minerals first discovered on the territory of the former Soviet Union. Ocean Pictures Ltd., Moscow, 369 pp.
Larsen, A.O. and Gault, RA. (2002) Calcio-ancylite-(Ce) from syenite pegmatite at Tvedalen, Oslo Region, Norway. Neues Jahrbuch fur Mineralogie, Monatshefte, 411-423.
Belovitskaya, Y.V., Pekov, I.V., Gobechiya, E.R., and Kabalov, Y.K. (2013) Refinement of the Crystal Structure of Calcioancylite-(Ce) by the Rietveld Method. Crystallography Reports (2013): 56(2),216-219. English translation of original publication in Kristallografiya (2013):58(2),197-200.

Internet Links for Calcioancylite-(Ce)Hide

Localities for Calcioancylite-(Ce)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Austria
 
  • Carinthia
    • Koralpe
      • Packsattel
Handbook of Mineralogy
Belgium
 
  • Luxembourg Province
    • Bertrix
Dehove, J. (2006): Les minéraux de la Carrière de la Flèche, Bertrix, province du Luxembourg, Belgique. Magazine du 4M, 27(261), 7-11.
Brazil
 
  • Minas Gerais
    • Poços de Caldas alkaline complex
      • Poços de Caldas
Horváth, Toft & Menezes specimens XRD, EDS
Horváth, Menezes, Toft ollections - confirmed by XRD & microprobe
Canada
 
  • Nunavut
    • Baffin Island
Hogarth (1997) Canadian Mineralogist 35, 53-78.
  • Québec
    • Abitibi-Témiscamingue
      • Témiscamingue RCM
        • Les Lacs-du-Témiscamingue
Reiner Mielke 2016
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Horváth, L and Gault, R.A. (1990), The mineralogy of Mont Saint-Hilaire Quebec. Mineralogical Record: 21: 284-359.; Belovitskaya, Y. V., Pekov, I. V., Gobechiya, E. R., & Kabalov, Y. K. (2013). Refinement of the crystal structure of calcioancylite-(Ce) by the Rietveld method. Crystallography Reports, 58(2), 216-219.
Finland
 
  • Lapland Region
    • Savukoski
      • Tulppio
        • Sokli carbonatite complex
l-Ani, Thair and Sarapää, Olli 2014. Mineralogical and geochemical study on carbonatites and fenites from the Kaulus drill cores, Sokli, Finland. GTK, tieteelliset posterit, volyymi 360
  • Northern Finland Region
    • Pyhäntä
Al Ani Thair and Torppa Akseli 2011. REE-Nb mineralogy in Katajakangas and Lamujärvi alkaline rocks, Central Finland
  • Western and Inner Finland Region
Al-Ani Thair, Sarapää Olli and Torppa Akseli 2010. Petrography and Mineralogy of REE-bearing minerals of Iivaara, Otanmäki and Korsnäs alkaline rocks. Geologian Tutkimuskeskus arkistoraportti M42/2010/15
Germany
 
  • Rhineland-Palatinate
    • Eifel
Handbook of Mineralogy
Greenland
 
  • Kujalleq
    • Narsaq
      • Igaliku (Igaliko)
        • Narsaarsuup Qaava
McDonald, A.M., Petersen, O.V., Gault, R.A., Johnsen, O., Niedermayr, G., Brandstätter, F. & Giester, G. (2001): Micheelsenite, (Ca,Y)3Al(PO3,OH,CO3)(CO3)(OH)6•12H2O,a new mineral from Mont Saint- Hilaire, Quebec, Canada and the Nanna pegmatite, Narsaarsuup Qaava, South Greenland. Neues Jahrbuch für Mineralogie, Monatshefte, 337-351
Petersen, O.V. (2001): List of all minerals identified in the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin. 190, 25-33
Hungary
 
  • Baranya Co.
    • Mecsek Mts
      • Hosszúhetény
www.geomania.hu
Italy
 
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Baveno
        • Feriolo
Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007): Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" di Alba, Ed., Alba, 607 pp.
        • Oltrefiume
          • Mount Camoscio
Grill, E. (1935): I minerali del granito di Baveno, la fayalite. Periodico di Mineralogia, 129-133. - Gallitelli, P. (1936): Le miche del granito di Baveno. . Periodico di Mineralogia, 61-76 - Pagliani, G. (1948): Le Zeoliti del granito di Baveno. Periodico di Mineralogia, 175-188. - Ravagnani, D. (1974): I giacimenti uraniferi italiani - Gruppo Mineralogico Lombardo - Museo Civico di Storia Naturale di Milano, Ed., Milano, 188 pp. - min. Rec. 14 (3), 157-168 - Am. Min. 83, 1330-1334 (1998) - Am. Min. 84, 782-789 (1999). - Guastoni, A. & Pezzotta, F. (2004): Kristiansenite a Baveno, second ritrovamento Mondiale della specie. Rivista Mineralogica Italiana, 4/2004, 247-251. - Guastoni, A., Demartin, F., Pezzotta, F. (2004): Sekaninaite delle pegmatiti granitiche di Feriolo e Baveno (VB). Atti della Società Italiana di Scienze Naturali e del Museo Civico di Storia Naturale di Milano, 145, 59-68. - Mineralogist americano (2005) 90, 1442-1452.
Orlandi, P., Pasero, M., Vezzalini, G. (1990): Calcio-ancylite-(Nd), a new REE-carbonate from Baveno, Italy. European Journal of Mineralogy, 2, 413-418 Orlandi, P. (1999): Zibaldone di mineralogia italiana 1999. Rivista Mineralogica Italiana, 3/1999, 170-175
  • Sardinia
    • Olbia-Tempio Pausania Province
      • Calangianus
- Gamboni, A., Gamboni, T., Pileri, P. (1997): Su alcuni minerali del massiccio granitico del monte Limbara zona "Furru e Conca", comune di Calangianus. Rivista Mineralogica Italiana, 2/1997, 123-134. Gamboni, A. & Bonacina, E. (2006): Massiccio granitico del Monte Limbara: calcioancylite-(Ce) e kainosite-(Y) di Furru e Conca, Calangianus, Olbia-Tempio Pausania, Sardegna nord-orientale. Micro (località), 1/2006, 137-140.
      • La Maddalena
        • La Maddalena Island
Identification with UK Id. Service of AMI.
Namibia
 
  • Khomas Region
    • Windhoek District
      • Aris
Uwe Kolitsch and Hans Vidar Ellingsen (SXRD + SEM-EDS); Uwe Kolitsch & Joachim Gröbner (SXRD + SEM-EDS); Kolitsch, U., Blaß, G., Jahn, S., Cámara, F., von Bezing, L., Wartha, R. R., Tremmel, G., Sturla, M., Cerea, P., Skebo, M. and Ciriotti, M. E. (2016): Aris - mineralogy of the famous alkaline phonolite. AMI - Associazione Micromineralogica Italiana, Cremona, Italy, 95 pp.
Norway
 
  • Aust-Agder
    • Evje og Hornnes
Husdal, T. (2009): Ancylittmineraler i Norge. Norsk Bergverksmuseum Skrift 41, 33 - 42
  • Nordland
    • Tysfjord
Husdal, T. (2008): The minerals of the pegmatites within the Tysfjord granite, northern Norway. Norsk Bergverksmuseum, skrift 38, 5-28.
Husdal, T. (2008): The minerals of the pegmatites within the Tysfjord granite, northern Norway. Norsk Bergverksmuseum, skrift 38, 5-28.
  • Oslo
    • Grorud
      • Bånkall
Husdal, T. (2009): Ancylittmineraler i Norge. Norsk Bergverksmuseum Skrift 41, 33 - 42
  • Telemark
    • Porsgrunn
      • Bjørkedalen
Knut Eldjarn
  • Vestfold
    • Larvik
      • Malerød
Andresen, P. (2011): Mineralene fra Midtfjellet larvikittbrudd, Malerød, Larvik. Norsk Bergverksmuseum Skrift. 46: 41-47
      • Tvedalen
Larsen, A. O. (ed.) (2010): The Langesundsfjord. History, geology, pegmatites, minerals. Bode Verlag Gmbh, Salzhemmendorf, Germany, 240 p
Andersen, F., Berge, S.A. & Burvald, I. (1996): Die Mineralien des Langesundsfjords und des umgebenden Larvikit-Gebietes, Oslo-Region, Norwegen. Mineralien-Welt 7 (4), 21-100
Larsen, A.O. & Gault, R.A. (2002): Calcio-ancylite-(Ce) from syenite pegmatite at Tvedalen, Oslo region, Norway. Neues Jahrbuch für Mineralogie. Monatshefte, 2002 (9): 411-423; Larsen, A. O. (ed.) (2010): The Langesundsfjord. History, geology, pegmatites, minerals. Bode Verlag Gmbh, Salzhemmendorf, Germany, 240 p
Peter Andresen collection.
Russia
 
  • Eastern-Siberian Region
    • Prebaikalia (Pribaikal'e)
      • Irkutskaya Oblast'
        • Vitim Plateau
          • Biraya and Bya Rivers confluence area (Chara Basin)
            • Biraya Fe-REE ore occurrence
C. Lemanski, Jr. (re-entry of lost Mindat data).
  • Northern Region
    • Murmanskaya Oblast'
Belovitskaya, Y. V., Pekov, I. V., Gobechiya, E. R., & Kabalov, Y. K. (2013). Refinement of the crystal structure of calcioancylite-(Ce) by the Rietveld method. Crystallography Reports, 58(2), 216-219.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 292.
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
  • Southern Siberia
    • Sayan Mts
      • Eastern Sayan
Savel’eva, V.B., and Karmanov, N.S. (2008): Geology of Ore Deposits 50(8), 681-696.
  • Western-Siberian Region
    • Prepolar Ural
      • Tyumenskaya Oblast'
        • Khanty-Mansi Okrug (Khanty Mansiysk)
          • Saranpaul
Belovitskaya, Y. V., Pekov, I. V., Gobechiya, E. R., & Kabalov, Y. K. (2013). Refinement of the crystal structure of calcioancylite-(Ce) by the Rietveld method. Crystallography Reports, 58(2), 216-219.
Belovitskaya, Y. V., Pekov, I. V., Gobechiya, E. R., & Kabalov, Y. K. (2013). Refinement of the crystal structure of calcioancylite-(Ce) by the Rietveld method. Crystallography Reports, 58(2), 216-219.
Slovenia
 
  • Pohorje Mts (Pohorje Massif)
    • Oplotnica (Oplotnitz)
      • Cezlak
Hinterlechner-Ravnik, A., Medenbach, O. & Niedermayr, G. (1995): Calcio-Ankylit-(Ce) aus einem Tonalitsteinbruch bei Cezlak, WSW Slovenska Bistrica, in Slowenien. Mineralien-Welt, 6 (2), 15-18; Postl, W., Bojar, H.-P. & Žorž, Z. (2015): Calcioankylit-(Ce) und Sepiolith aus dem "Tonalit"-Steinbruch in Cezlak bei Oplotnica, Pohorje-Gebirge, Slowenien. Der Steirische Mineralog 30, 42.
Tajikistan
 
  • Region of Republican Subordination
    • Tien Shan Mtn
      • Alai Range (Alayskiy)
http://www.koeln.netsurf.de/~w.steffens/dara.htm
UK
 
  • Scotland
    • Highlands
      • Tomich
Hubbard, N., Green, D.I., and Tindle, A.G. (2008) Barium Zeolites and Calcioancylite-(Ce) From Guisachan Quarry, Tomich, Highland, Scotland. Journal of the Russell Society, vol. 11, 73-79.
USA
 
  • Montana
    • Meagher Co.
Chakhmouradian A.R., Mitchell R.H. (2002): The mineralogy of Ba- and Zr-rich alkaline pegmatites from Gordon Butte, Crazy Mountains (Montana, USA): comparisons between potassic and sodic agpaitic pegmatites. Contrib. Mineral. Petrol., 143, 93-114.
  • New York
    • New York City
www.nysam.org
  • North Carolina
    • Cleveland Co.
      • Kings Mountain District
Mineralogical Record (1987): 18: 203-205.
  • Pennsylvania
    • Chester Co.
      • Wallace Township
        • Cornog
Handbook of Mineralogy
Mineral and/or Locality  
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