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Campigliaite

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Formula:
Mn2+Cu4(SO4)2(OH)6 · 4H2O
Colour:
Light blue
Lustre:
Vitreous
Specific Gravity:
3.06 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
For the locality.
Devilline Group.

The manganese analogue of devilline and lautenthalite.

Unique combination of elements: the only Mn-Cu sulfate mineral.


Hide all sections | Show all sections

Classification of CampigliaiteHide

Approved
Approval Year:
1981
7.DD.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.6.6.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O
25.2.22

25 : Sulphates
2 : Sulphates of Cu and Ag

Physical Properties of CampigliaiteHide

Vitreous
Transparency:
Transparent
Colour:
Light blue
Cleavage:
Perfect
{100}
Density:
3.06 g/cm3 (Calculated)

Optical Data of CampigliaiteHide

Type:
Biaxial (-)
RI values:
nα = 1.589 nβ = 1.645 nγ = 1.659
2V:
Measured: 52° , Calculated: 50°
Max Birefringence:
δ = 0.070
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v weak

Chemical Properties of CampigliaiteHide

Formula:
Mn2+Cu4(SO4)2(OH)6 · 4H2O
IMA Formula:
Cu4Mn2+(SO4)2(OH)6 · 4H2O

Crystallography of CampigliaiteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 21.7 Å, b = 6.09 Å, c = 11.24 Å
β = 100.3°
Ratio:
a:b:c = 3.563 : 1 : 1.846
Unit Cell V:
1464.5 ų
Z:
4

Type Occurrence of CampigliaiteHide

General Appearance of Type Material:
Light blue tufts
Place of Conservation of Type Material:
Museum of Florence University #214/I
Geological Setting of Type Material:
Altered skarn deposit
Associated Minerals at Type Locality:

Synonyms of CampigliaiteHide

Other Language Names for CampigliaiteHide

Relationship of Campigliaite to other SpeciesHide

Member of:
Other Members of this group:
Aldridgeite(Cd,Ca)(Cu,Zn)4(SO4)2(OH)6 · 3H2O Mon. 2/m : B2/b
DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
KobyasheviteCu5(SO4)2(OH)6·4H2OTric. 1 : P1
LautenthalitePbCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
Serpierite1 photo of Campigliaite associated with Serpierite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.20KtenasiteZn(Cu,Zn)4(SO4)2(OH)6 · 6H2OMon.
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric.
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6·4H2O Mon. 2/m : P21/b
7.DD.35Carrboydite[(Ni1-xAlx)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OHex.
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig.
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2•6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig.
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m : P21/b
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75Nickelalumite(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2OMon.
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12·3H2OMon.
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig.
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl·6H2OHex.
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

25.2.1ChalcocyaniteCuSO4Orth. mmm (2/m 2/m 2/m)
25.2.2BonattiteCuSO4 · 3H2OMon.
25.2.3ChalcanthiteCuSO4 · 5H2OTric. 1 : P1
25.2.4BoothiteCuSO4 · 7H2OMon.
25.2.5DolerophaniteCu2(SO4)OMon. 2/m : B2/m
25.2.6AntleriteCu3(SO4)(OH)4Orth. mmm (2/m 2/m 2/m)
25.2.7BrochantiteCu4(SO4)(OH)6Mon. 2/m : P21/b
25.2.8PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
25.2.9LangiteCu4(SO4)(OH)6 · 2H2OMon. m
25.2.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
25.2.11KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
25.2.12NatrochalciteNaCu2(SO4)2(OH) · 2H2OMon. 2/m : B2/m
25.2.13PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet.
25.2.14FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
25.2.15CyanochroiteK2Cu(SO4)2 · 6H2OMon. 2/m
25.2.16EuchlorineKNaCu3(SO4)3OMon.
25.2.17DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
25.2.18LeightoniteK2Ca2Cu(SO4)4 · 2H2OTric.
25.2.19ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
25.2.20CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2OOrth.
25.2.21WoodwarditeCu1-xAlx(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
25.2.23GuilditeCuFe3+(SO4)2(OH) · 4H2OMon.
25.2.24RansomiteCuFe2(SO4)4 · 6H2OMon. 2/m : P21/b
25.2.26KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon.
25.2.27Poitevinite(Cu,Fe,Zn)SO4 · H2OTric.
25.2.28ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for CampigliaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
American Mineralogist: 67: 385-393.

Internet Links for CampigliaiteHide

Localities for CampigliaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Yancowinna Co.
      • Broken Hill
        • Broken Hill South Mine (BHS Mine; South Mine)
Private Collection
Italy
 
  • Piedmont
    • Alessandria Province
      • Voltaggio
Piccoli, G. C., Maletto, G., Bosio, P., & Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo F. Eusebio - Alba, 607 pag.
  • Tuscany
    • Livorno Province
      • Campigliese (Campiglia Mountains; Campiglia Ridge)
        • Campiglia Marittima
Am Min 67:385-393
UK
 
  • Wales
    • Ceredigion
      • Ysgubor-y-coed
        • Furnace
Priv Com Frank Hawthorne, University of Manitoba
USA
 
  • Utah
    • Piute Co.
      • Tushar Mts
        • Cottonwood Creek
          • Mount Baldy District
    • Sevier Co.
Smithsonian specimen USNM Number: 170031
Mineral and/or Locality  
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