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Carrboydite

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About CarrboyditeHide

Formula:
(Ni1-xAlx)(SO4)x/2(OH)2 · nH2O
(x<0.5, n>3x/2)
Colour:
Yellowish-green, blue-green
Crystal System:
Hexagonal
Name:
Named for the Carr Boyd nickel mine, Australia, the type locality.
As part of the recent re-evaluation of the nomenclature of the hydrotalcite supergroup (Mills et al., 2012), carrboydite was identified as a questionable species which needs further investigation.


Classification of CarrboyditeHide

Approved, Questionable
First Published:
1976
7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.10.1.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous
12.2.22

12 : Carbonates with other anions
2 : Carbonates with sulphate

Physical Properties of CarrboyditeHide

Colour:
Yellowish-green, blue-green

Optical Data of CarrboyditeHide

Type:
Uniaxial (-)
RI values:
nω = 1.560 nε = 1.540
Max Birefringence:
δ = 0.020
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemical Properties of CarrboyditeHide

Formula:
(Ni1-xAlx)(SO4)x/2(OH)2 · nH2O

(x<0.5, n>3x/2)
IMA Formula:
(Ni1-xAlx)(SO4)x/2(OH)2 · nH2O (x < 0.5, n > 3x/2)

Crystallography of CarrboyditeHide

Crystal System:
Hexagonal
Cell Parameters:
a = 9.14 Å, c = 10.34 Å
Ratio:
a:c = 1 : 1.131
Unit Cell V:
748.07 ų (Calculated from Unit Cell)

Type Occurrence of CarrboyditeHide

Place of Conservation of Type Material:
Western Australian Museum, Perth, Australia, M.74.1991.
National Museum of Natural History, Washington, D.C., USA, 135930.

Synonyms of CarrboyditeHide

Other Language Names for CarrboyditeHide

German:Carrboydit
Spanish:Carrboydita

Relationship of Carrboydite to other SpeciesHide

Other Members of this group:
Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O

Common AssociatesHide

Associated Minerals Based on Photo Data:
Aurichalcite1 photo of Carrboydite associated with Aurichalcite on mindat.org.
Gaspéite1 photo of Carrboydite associated with Gaspéite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.20KtenasiteZn(Cu,Zn)4(SO4)2(OH)6 · 6H2OMon.
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric.
7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon.
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6·4H2O Mon. 2/m : P21/b
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2•6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m : P21/b
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75Nickelalumite(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2OMon.
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12·3H2OMon.
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig.
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl·6H2OHex.
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

12.2.1BurkeiteNa6(CO3)(SO4)2Orth.
12.2.2HanksiteNa22K(SO4)9(CO3)2ClHex. 6/m : P63/m
12.2.3TychiteNa6Mg2(CO3)4(SO4)Iso. m3 (2/m 3) : Fd3
12.2.4MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
12.2.5FerrotychiteNa6(Fe,Mn,Mg)2(CO3)4(SO4)
12.2.6NakauriiteCu8(SO4)4(CO3)(OH)6 · 48H2OOrth.
12.2.7CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2OOrth.
12.2.8RapidcreekiteCa2(SO4)(CO3) · 4H2OOrth.
12.2.9TatarskiteCa6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2OOrth.
12.2.10Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig.
12.2.11LeadhillitePb4(CO3)2(SO4)(OH)2Mon. 2/m : P21/b
12.2.12MacphersonitePb4(CO3)2(SO4)(OH)2Orth. mmm (2/m 2/m 2/m)
12.2.13SusannitePb4(CO3)2(SO4)(OH)2Trig. 3 : P3
12.2.14WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
12.2.15CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
12.2.16NasledovitePbMn3Al4(CO3)4(SO4)O5 · 5H2O
12.2.17JouravskiteCa3Mn4+(SO4)(CO3)(OH)6 · 12H2OHex.
12.2.18SchröckingeriteNaCa3(UO2)(CO3)3(SO4)F · 10H2OTric. 1 : P1
12.2.19ManganotychiteNa6Mn2(CO3)4(SO4)
12.2.20HauckiteFe3+3(Mg,Mn2+)24Zn18(SO4)4(CO3)2(OH)81Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
12.2.21ParaotwayiteNi(OH)2-x(SO4,CO3)0.5xMon.
12.2.23Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
12.2.24CamérolaiteCu6Al3(OH)18(H2O)2[Sb(OH)6](SO4)Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for CarrboyditeHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Nickel, E.H., Clarke, R.M. (1976) Carrboydite, a hydrated sulfate of nickel and aluminum: a new mineral from Western Australia. American Mineralogist: 61: 366-372.
Nickel, E.H., Wildman, J.E. (1981) Hydrohonessite- a new hydrated Ni-Fe hydroxy-sulphate mineral; its relationship to honessite, carrboydite, and minerals of the pyroaurite group. Mineralogical Magazine: 44: 333-337.
Frost, R.L., Weier, M.L., Kloprogge, J.T. (2003) Raman spectroscopy of some natural hydrotalcites with sulphate and carbonate in the interlayer. Journal of Raman Spectroscopy: 34: 760-768.
Mills, S.J., Christy, A.G., Genin, J.-M.R., Kameda, T., Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine: 76: 1289-1336.

Internet Links for CarrboyditeHide

Localities for CarrboyditeHide

ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Widgiemooltha
[MinRec 25:287]; Nickel E H, Robinson B W, Mumme W G (1993) Widgiemoolthalite: the new Ni analogue of hydromagnesite from Western Australia. American Mineralogist 78, 819-821; Clissold, M. E. (2007) Aspects of the Supergene Geochemistry of Copper, Nickel and Bismuth. PhD Thesis University of Sydney, Australia 162pp.
    • Menzies Shire
      • Menangina Station
CSIRO Min.Res.Lab.,Austr.1974/75 (1975) 12; Amer.Min.(1976) 61, 366-372; Min Mag (1979) 43, 97-98; Matthew J. Sciberras, Peter Leverett, Peter A. Williams, David E. Hibbs, Peter J. Downes, Mark D. Welch and Anthony R. Kampf (2013) Paratacamite-(Ni,Cu3(Ni,Cu)Cl2(OH)6, a new mineral from the Carr Boyd Rocks mine, Western Australia. Australian Journal of Mineralogy 17:39-44
Portugal
 
  • Aveiro District
    • Albergaria-a-Velha
      • Branca
Antonio Jesus Pimentel specimens; www.mindat.org/mesg-25-107652.html
Mineral and/or Locality  
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