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Cerussite

This page kindly sponsored by Mariusz Oleszczuk
Formula:
PbCO3
Colour:
Colourless, white, gray, blue, or green; colourless in transmitted light
Lustre:
Adamantine, Vitreous, Resinous, Pearly, Dull, Earthy
Hardness:
3 - 3½
Specific Gravity:
6.53 - 6.57
Crystal System:
Orthorhombic
Member of:
Name:
Named in 1845 by Wilhelm Karl von Haidinger from the Latin, cerussa, meaning "white lead."
Aragonite Group.

Cerussite is a lead carbonate mineral, usually found in the oxidized zone of lead ore deposits. It is a very common weathering product of galena and other lead ore minerals.

Visit gemdat.org for gemological information about Cerussite.


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Classification of CerussiteHide

Approved, 'Grandfathered' (first described prior to 1959)
5.AB.15

5 : CARBONATES (NITRATES)
A : Carbonates without additional anions, without H2O
B : Alkali-earth (and other M2+) carbonates
14.1.3.4

14 : ANHYDROUS NORMAL CARBONATES
1 : A(XO3)
11.9.1

11 : Carbonates
9 : Carbonates of Pb, Zr and Th

Pronounciation of CerussiteHide

Pronounciation:
PlayRecorded byCountry
Jolyon & Katya RalphUnited Kingdom

Physical Properties of CerussiteHide

Adamantine, Vitreous, Resinous, Pearly, Dull, Earthy
Transparency:
Transparent, Translucent
Colour:
Colourless, white, gray, blue, or green; colourless in transmitted light
Streak:
White
Hardness:
3 - 3½ on Mohs scale
Tenacity:
Very brittle
Cleavage:
Distinct/Good
On {110} and {021} distinct; on {010} and {012} in traces.
Fracture:
Conchoidal
Density:
6.53 - 6.57 g/cm3 (Measured)    6.558 g/cm3 (Calculated)

Optical Data of CerussiteHide

Type:
Biaxial (-)
RI values:
nα = 1.803 nβ = 2.074 nγ = 2.076
2V:
Measured: 8° to 14°, Calculated: 8°
Max Birefringence:
δ = 0.273
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
relatively strong

Chemical Properties of CerussiteHide

Formula:
PbCO3

Crystallography of CerussiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:
a = 5.179(1) Å, b = 8.492(3) Å, c = 6.141(2) Å
Ratio:
a:b:c = 0.61 : 1 : 0.723
Unit Cell V:
270.08 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystal morphology extremely varied. Simple crystals often tabular {010} and elongated [001] or [100]. Also equant or dipyramidal and then pseudo-hexagonal. Rarely acicular [001] or very thin tabular {001}. {010} and {0kl} usually striated [100]; {111} often striated [110] or [112]. Reticular twin aggregates common. Massive, granular, dense, compact. Stalactitic at times; pulverulent to earthy. Fibrous rare.
Twinning:
Almost universal. Most commonly on {110}, as twin lamellae or as contact twin types producing stellate pseudo-hexagonal groups or reticulated aggregates. On {130} less common, mainly as contact twins with a heart-shaped outline. Both laws may occur simultaneously.
Comment:
Non-standard space group setting (Pmcn). Other source gives cell parameters 5.173, 8.48, 6.13 A.

Crystallographic forms of CerussiteHide

Crystal Atlas:
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Cerussite no.48 - Goldschmidt (1913-1926)
Cerussite no.63 - Goldschmidt (1913-1926)
Cerussite no.140 - Goldschmidt (1913-1926)
Cerussite no.157 - Goldschmidt (1913-1926)
Cerussite no.261 - Goldschmidt (1913-1926)
Cerussite no.460 - Goldschmidt (1913-1926)
3d models and HTML5 code kindly provided by www.smorf.nl.

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X-Ray Powder DiffractionHide

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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
3.593 (100)
3.498 (43)
3.074 (24)
2.522 (20)
2.487 (32)
2.081 (27)
1.859 (21)

Type Occurrence of CerussiteHide

Synonyms of CerussiteHide

Other Language Names for CerussiteHide

Varieties of CerussiteHide

Argentiferous CerussiteA silver-bearing variety of cerussite.
Chrome-CerussiteVariety of Cerussite. Not properly Diagnosed yet. Claimed to be a mixture of Cerussite and Crocoite in Hey's Chemical Index of Minerals.
Zincian CerussiteAragonite group. A zincian variety of Cerussite.
Originally reported from Monteponi Mine, Iglesias, Carbonia-Iglesias Province, Sardinia, Italy.

Relationship of Cerussite to other SpeciesHide

Member of:
Other Members of this group:
AragoniteCaCO3Orth. mmm (2/m 2/m 2/m)
StrontianiteSrCO3Orth. mmm (2/m 2/m 2/m)
WitheriteBaCO3Orth. mmm (2/m 2/m 2/m)
Forms a series with:

Common AssociatesHide

AnglesitePbSO4
GalenaPbS
Limonite(Fe,O,OH,H2O)
MalachiteCu2(CO3)(OH)2
PhosgenitePb2CO3Cl2
PyromorphitePb5(PO4)3Cl
SilverAg
SmithsoniteZnCO3
Associated Minerals Based on Photo Data:
Malachite613 photos of Cerussite associated with Malachite on mindat.org.
Galena475 photos of Cerussite associated with Galena on mindat.org.
Baryte352 photos of Cerussite associated with Baryte on mindat.org.
Azurite266 photos of Cerussite associated with Azurite on mindat.org.
Smithsonite231 photos of Cerussite associated with Smithsonite on mindat.org.
Pyromorphite227 photos of Cerussite associated with Pyromorphite on mindat.org.
Quartz209 photos of Cerussite associated with Quartz on mindat.org.
Mimetite184 photos of Cerussite associated with Mimetite on mindat.org.
Anglesite178 photos of Cerussite associated with Anglesite on mindat.org.
Linarite171 photos of Cerussite associated with Linarite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

5.AB.05CalciteCaCO3Trig. 3m (3 2/m) : R3c
5.AB.05GaspéiteNi(CO3)Hex.
5.AB.05MagnesiteMgCO3Trig. 3m (3 2/m) : R3c
5.AB.05OtaviteCdCO3Trig. 3m (3 2/m)
5.AB.05RhodochrositeMnCO3Trig. 3m (3 2/m) : R3c
5.AB.05SideriteFeCO3Trig. 3m (3 2/m) : R3c
5.AB.05SmithsoniteZnCO3Trig. 3m (3 2/m) : R3c
5.AB.05SpherocobaltiteCoCO3Trig. 3m (3 2/m) : R3c
5.AB.10AnkeriteCa(Fe2+,Mg)(CO3)2Trig. 3 : R3
5.AB.10DolomiteCaMg(CO3)2Trig. 3 : R3
5.AB.10KutnohoriteCa(Mn,Mg,Fe)(CO3)2Trig. 3 : R3
5.AB.10MinrecorditeCaZn(CO3)2Trig. 3 : R3
5.AB.15AragoniteCaCO3Orth. mmm (2/m 2/m 2/m)
5.AB.15StrontianiteSrCO3Orth. mmm (2/m 2/m 2/m)
5.AB.15WitheriteBaCO3Orth. mmm (2/m 2/m 2/m)
5.AB.20VateriteCaCO3Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
5.AB.25HuntiteCaMg3(CO3)4Trig. 3 2 : R3 2
5.AB.30NorsethiteBaMg(CO3)2Trig. 3 2 : R3 2
5.AB.35AlstoniteBaCa(CO3)2Tric.
5.AB.40OlekminskiteSr(Sr,Ca,Ba)(CO3)2Trig.
5.AB.40ParalstoniteBaCa(CO3)2Trig.
5.AB.45BarytocalciteBaCa(CO3)2Mon. 2/m : P21/m
5.AB.50Carbocernaite(Ca,Na)(Sr,Ce,Ba)(CO3)2Orth. mm2
5.AB.55BenstoniteBa6Ca6Mg(CO3)13Trig. 3 : R3
5.AB.60JuangodoyiteNa2Cu(CO3)2Mon. 2/m : P21/b

Related Minerals - Dana Grouping (8th Ed.)Hide

14.1.3.2WitheriteBaCO3Orth. mmm (2/m 2/m 2/m)
14.1.3.3StrontianiteSrCO3Orth. mmm (2/m 2/m 2/m)

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

11.9.2HydrocerussitePb3(CO3)2(OH)2Trig.
11.9.3DundasitePbAl2(CO3)2(OH)4 · H2OOrth. mmm (2/m 2/m 2/m)
11.9.4Gysinite-(Nd)PbNd(CO3)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
11.9.5Schuilingite-(Nd)PbCu(Nd,Gd,Sm,Y)(CO3)3(OH) · 1.5H2O
11.9.6TuliokiteNa6BaTh(CO3)6 · 6H2OTrig.
11.9.7WeloganiteNa2Sr3Zr(CO3)6 · 3H2OTric. 1 : P1
11.9.8SabinaiteNa4Zr2TiO4(CO3)4Mon. 2/m : B2/b

Fluorescence of CerussiteHide

Yellow to golden-yellow, white (best LW UV), also under X-rays.

Other InformationHide

Thermal Behaviour:
Breaks down to a basic carbonate at about 300°, which, in turn, decomposes to PbO at about 500° (?).
Notes:
Soluble in dilute HNO3 with effervescence.

Occurs as alteration pseudomorphs after anglesite, phosgenite, leadhillite, caledonite, hydrocerussite, bournonite, linarite, pyromorphite, vanadinite. Also occurs as incrustation or substitution pseudomorphs after calcite and sphalerite.
Pseudomorphs of pyromorphite, minium, malachite, quartz, galena, limonite, calcite, siderite, phosgenite, dolomite and chrysocolla after crystals of cerussite have been observed.
Health Risks:
Contains lead - wash hands after handling, avoid inhaling dust when breaking.
Industrial Uses:
Ore of lead, and often also of silver.

Cerussite in petrologyHide

Common component of (items highlighted in red)

References for CerussiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Conrad Gesner (1565) De Omni Rervm Fossilivm Genere.
Wallerius, J.G (1747) Mineralogia, eller Mineralriket. Stockholm: 295 (as Minera Plumbi spathacea).
Wallerius, J.G. (1753) French edition of “Mineralogia, eller Mineralriket.” 2 volumes, Paris: 1: 536 (as Plomb spathique).
Bergmann, T. (1780) Opuscula of Tobernus Bergmann: 2: 426 (as Plumbum acido aero mineralisatum).
Beudant, F.S. (1832) Traité élémentaire de Minéralogie, second edition, 2 volumes: 2: 363 (as Céruse).
Karsten (1832) Journal für Chemie und Physik, Nuremberg: 45: 365.
Haidinger, Wm. (1845) Handbuch der bestimmenden Mineralogie. Vienna: 503 (as Cerussit).
Schrauf (1860) Sitzber. Ak. Wien: 42: 120.
Des Cloizeaux, A. (1867) Nouvelles recherches sur les propriétés optique des cristaux, naturels ou artificiels, et sur les variations que ces propriétés éprouvent sous l’influence de la chaleur. 222pp., Paris. (Institut imperial de France, Mémoires 18): 49.
Koksharov, N. von (1870) Materialien zur Mineralogie Russlands. 11 volumes with atlas, vol. 6: 100.
Joulin (1873) Bull. Soc. chim. phys.: 19[2]: 345.
de Luca (1877) Comptes rendus de l’Académie des sciences de Paris: 84: 1457.
Brown (1886) American Journal of Science: 32: 377.
Fletcher (1887) Mineralogical Magazine: 7: 187.
Negri (1889) Rivista di mineralogia e cristallografia italiana, Padua: 4: 53.
Traube (1894) Zeitschrift der Deutschen Geologische Gesellschaft, Berlin: 46: 50.
Hobbs (1895) American Journal of Science: 50: 121.
Ohm (1899) Jb. Min., Beil.-Bd.: 13: 31.
Mügge (1901) Jb. Min., Beil.-Bd.: 14: 259.
Panichi (1902) Reale accademia nazionale dei Lincei, Rome, Mem: 4[5a]: 419.
Rogers (1903) American Geologist, Minneapolis: 31: 45.
Warren (1903) American Journal of Science: 16: 337.
Colson (1905) Comptes rendus de l’Académie des sciences de Paris: 140: 865.
Lacroix (1909): 3: 727.
Doelter, C. (1911) Handbuch der Mineral-chemie (in 4 volumes divided into parts): 1: 510.
Boutwell (1912) USGS Professional Paper 77: 111.
Friedrich (1912) Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 621.
Dübigk (1913) Neues Jahrbuch für Mineralogie, Geologie und Paleontologie, Beil.-Bd., Heidelberg, Stuttgart: 36: 214.
Goldschmidt, V. (1913) Atlas der Krystallformen. 9 volumes, atlas, and text, vol. 2: 107.
Pilipenko (1915) Bulletin of the Imperial Tomsk University: no. 63 [Min. Abs.: 2: 111 (1923)].
Schrader (1917) USGS Bulletin 624.
Ledoux and Walker (1918) Ottawa Nat.: 32: 7.
Buttgenbach (1920) Bulletin de la Société française de Minéralogie: 43: 24.
Stevanovic (1922) Ann. géol. pénin. Balkan.: 7: 85.
Billows (1923) Att. Accad. Veneto.: 14[3]: 89.
Maier (1923) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 58: 75.
Sève (1923) Bulletin de la Société française de Minéralogie: 46: 34.
Barthoux (1924) Bulletin de la Société française de Minéralogie: 47: 36.
Hintze, Carl (1926) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1[3A]: 3045.
Shannon (1926) U.S. National Museum Bulletin 131: 240.
Smith (1926) New South Wales Department of Mines, Mineral Resources, no. 34: 93.
Tokody (1926) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 63: 385.
O'Daniel (1930) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 74: 333.
Laskiewicz (1931) Archiwum Mineralogiczne (Towarzystwo Naukowe Warszawsie): 7: 147.
Colby and La Coste (1933) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 84: 300.
Garrido (1934) Bol. Soc. espan. Hist. nat.: 34: 301.
Vavrinecz (1934) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 89: 521.
Rottenbach (1937) Inaugural Dissertaton, Bonn.
Tokody (1937) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 96: 325.
Lindsay and Hoyt (1938) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 100: 360.
Tokody (1942) Magyar Tudom. Akad. Mat. Termeszett. Ertisitö, Budapest: 61: 1116.
Amaral (1948) Min. e met., Rio de Janeiro: 13: 59.
Palache, C., Berman, H., & Frondel, C. (1951) The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged: 200-207.
Reviews in Mineralogy, Mineralogical Society of America: 11.
Sahl, K. (1974) Verfeinerung der Kristallstruktur von Cerussit, PbCO3. Zeitschrift für Kristallographie, 139, 215-222.
Chevrier, G., G. Giester, G. Heger, D. Jarosch, M. Wildner, and J. Zemann (1992) Neutron single-crystal refinement of cerussite, PbCO3, and comparison with other aragonite-type carbonates. Zeitschrift für Kristallographie 199, 67-74.
Martens, W. N.; Rintoul, L.; Kloprogge, J. T.; Frost, R. L. (2004) Single crystal Raman spectroscopy of cerussite. American Mineralogist 89, 352-358.
Alexander A. Kaminskii, Ladislav Bohatý, Hanjo Rhee, André Kaltenbach, Oliver Lux, Hans J. Eichler, Reinhard Rückamp and Petra Becker (2013) Cerussite, PbCO3 - a new Stimulated Raman Scattering (SRS)-active crystal with high-order Stokes and anti-Stokes lasing. Laser Photonics Rev. 7, 425-431.

Internet Links for CerussiteHide

Localities for CerussiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListShow