Cobaltarthurite
A valid IMA mineral species
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About Cobaltarthurite
Formula:
(Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2O
Colour:
Yellowish brown to straw yellow
Lustre:
Vitreous, Silky
Hardness:
3½ - 4
Specific Gravity:
3.22
Crystal System:
Monoclinic
Member of:
Name:
Named as the cobalt analogue of arthurite.
Type Locality:
Unique Identifiers
Mindat ID:
11113
Long-form identifier:
mindat:1:1:11113:5
GUID
(UUID V4):
(UUID V4):
c798e9e9-0e33-4cc5-acad-4a23b29fd6bc
IMA Classification of Cobaltarthurite
Approved
IMA Formula:
CoFe3+2(AsO4)2(OH)2 · 4H2O
Approval year:
2001
First published:
2002
Classification of Cobaltarthurite
8.DC.15
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.11.20.5
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Caru | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Cobaltarthurite
Pronunciation:
Play | Recorded by | Country |
---|---|---|
Jolyon Ralph | United Kingdom |
Physical Properties of Cobaltarthurite
Vitreous, Silky
Transparency:
Translucent
Colour:
Yellowish brown to straw yellow
Streak:
White to pale brown
Hardness:
3½ - 4 on Mohs scale
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
None Observed
none
none
Fracture:
None observed
Density:
3.22 g/cm3 (Measured)
Optical Data of Cobaltarthurite
Type:
Biaxial (+)
RI values:
nα = 1.741 nβ = 1.762 nγ = 1.797
Max Birefringence:
δ = 0.056
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Optical Extinction:
Parallel extinction and length slow. Z ≃ c.
Pleochroism:
Strong
Comments:
X = almost colorless; Z = medium yellow.
Comments:
Absorption: Z > X, Y.
Chemistry of Cobaltarthurite
Mindat Formula:
(Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2O
Crystallography of Cobaltarthurite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Cell Parameters:
a = 10.27 Å, b = 9.72 Å, c = 5.545 Å
β = 94.46°
β = 94.46°
Ratio:
a:b:c = 1.057 : 1 : 0.57
Unit Cell V:
551.85 ų
Z:
2
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Display Options
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2D | Stereo | Red-Blue | Red-Cyan
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CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0005772 | Cobaltarthurite | Raudsepp M, Pani E (2002) The crystal structure of cobaltarthurite, CoFe2(AsO4)2(OH)2.4H2O: A Rietveld refinement The Canadian Mineralogist 40 733-737 | 2002 | 0 | 293 | ||
0006049 | Cobaltarthurite | Kampf A R (2005) The crystal structure of cobaltarthurite from the Bou Azzer district, Morocco: The location of hydrogen atoms in the arthurite structure-type The Canadian Mineralogist 43 1387-1391 | 2005 | Bou Azzer district, Morocco | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.04 Å | (100) |
10.2 Å | (95) |
4.81 Å | (65) |
4.24 Å | (60) |
2.87 Å | (55) |
2.89 Å | (25) |
4.51 Å | (20) |
Comments:
Dolores showing, near Pastrana, Spain. Data are from the type description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Cobaltarthurite
General Appearance of Type Material:
Globular and pellet-like aggregates up to 1.5 mm in diameter, consisting of radial fibers and non-fibrous material.
Place of Conservation of Type Material:
Canadian Museum of Nature, Ottawa, Ontario, Canada, NMNMC 83399.
Geological Setting of Type Material:
Oxidation zone of a presumed prior sulfide deposit.
Associated Minerals at Type Locality:
Reference:
Jambor, J.L., Vinals, J., Groat, L.A., Raudsepp, M. (2002) Cobaltarthurite, Co2+Fe3+2(AsO4)2(OH)2.4H2O, a new member of the arthurite group. The Canadian Mineralogist: 40: 725-732.
Synonyms of Cobaltarthurite
Other Language Names for Cobaltarthurite
German:Cobaltarthurit
Kobaltarthurit
Kobaltarthurit
Russian:Кобальтартурит
Simplified Chinese:水砷铁钴石
Spanish:Cobaltarthurita
Traditional Chinese:水砷鐵鈷石
Relationship of Cobaltarthurite to other Species
Member of:
Other Members of this group:
Arthurite | CuFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
UKI-2006-(PO:AlCuFeH) | Fe2+Al3+2(PO4)2(OH)2 · 4H2O | |
UM2006-27-PO:FeHZn | ZnFe3+2(PO4)2(OH)2 · 4H2O | Mon. |
Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O | Mon. 2/m : P21/b |
Common Associates
Associated Minerals Based on Photo Data:
13 photos of Cobaltarthurite associated with Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
5 photos of Cobaltarthurite associated with Arsenocrandallite | CaAl3(AsO4)(AsO3OH)(OH)6 |
5 photos of Cobaltarthurite associated with Barahonaite-(Fe) | (Ca,Cu,Na,Fe3+,Al)12Fe3+2(AsO4)8(OH,Cl)x · nH2O |
5 photos of Cobaltarthurite associated with Yukonite | Ca3Fe3+(AsO4)2(OH)3 · 5H2O |
2 photos of Cobaltarthurite associated with Olivenite | Cu2(AsO4)(OH) |
2 photos of Cobaltarthurite associated with Arsenogoyazite | SrAl3(AsO4)(AsO3OH)(OH)6 |
1 photo of Cobaltarthurite associated with Barahonaite-(Al) | (Ca,Cu,Na,Fe3+,Al)12Al2(AsO4)8(OH,Cl)x · nH2O |
Related Minerals - Strunz-mindat Grouping
8.DC. | Ianbruceite | Zn2(AsO4)(OH) · 3H2O |
8.DC. | Césarferreiraite | Fe2+ Fe3+2(AsO4)2(OH)2 · 8H2O |
8.DC. | Ferrivauxite | Fe3+Al2(PO4)2(OH)3 · 5H2O |
8.DC.05 | Nissonite | Cu2Mg2(PO4)2(OH)2 · 5H2O |
8.DC.07 | Euchroite | Cu2(AsO4)(OH) · 3H2O |
8.DC.10 | Legrandite | Zn2(AsO4)(OH) · H2O |
8.DC.12 | Strashimirite | Cu8(AsO4)4(OH)4 · 5H2O |
8.DC.15 | Arthurite | CuFe3+2(AsO4)2(OH)2 · 4H2O |
8.DC.15 | Earlshannonite | Mn2+Fe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | Ojuelaite | ZnFe3+2(AsO4)2(OH)2 · 4H2O |
8.DC.15 | Whitmoreite | Fe2+Fe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | Bendadaite | Fe2+Fe3+2(AsO4)2(OH)2 · 4H2O |
8.DC.15 | Kunatite | CuFe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | UM2006-27-PO:FeHZn | ZnFe3+2(PO4)2(OH)2 · 4H2O |
8.DC.15 | UKI-2006-(PO:AlCuFeH) | Fe2+Al3+2(PO4)2(OH)2 · 4H2O |
8.DC.17 | Kleemanite | ZnAl2(PO4)2(OH)2 · 3H2O |
8.DC.20 | Bermanite | Mn2+Mn3+2(PO4)2(OH)2 · 4H2O |
8.DC.20 | Coralloite | Mn2+Mn3+2(AsO4)2(OH)2 · 4H2O |
8.DC.20 | Magnesiobermanite | MgMn3+2(PO4)2(OH)2 · 4H2O |
8.DC.22 | Kovdorskite | Mg2(PO4)(OH) · 3H2O |
8.DC.25 | Ferristrunzite | Fe3+Fe3+2(PO4)2(OH)3 · 5H2O |
8.DC.25 | Ferrostrunzite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
8.DC.25 | Metavauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
8.DC.25 | Metavivianite | Fe2+Fe3+2(PO4)2(OH)2 · 6H2O |
8.DC.25 | Strunzite | Mn2+Fe3+2(PO4)2(OH)2 · 6H2O |
8.DC.25 | Zincostrunzite | ZnFe3+2(PO4)2(OH)2 · 6.5H2O |
8.DC.27 | Beraunite | Fe3+6(PO4)4O(OH)4 · 6H2O |
8.DC.27 | Tvrdýite | Fe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2O |
8.DC.27 | Zincoberaunite | ZnFe3+5(PO4)4(OH)5 · 6H2O |
8.DC.30 | Gordonite | MgAl2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Laueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Mangangordonite | Mn2+Al2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Paravauxite | Fe2+Al2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Pseudolaueite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Sigloite | Fe3+Al2(PO4)2(OH)3 · 7H2O |
8.DC.30 | Stewartite | Mn2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Ushkovite | MgFe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Ferrolaueite | Fe2+Fe3+2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Kastningite | (Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2O |
8.DC.30 | Maghrebite | MgAl2(AsO4)2(OH)2 · 8H2O |
8.DC.30 | Nordgauite | MnAl2(PO4)2(F,OH)2 · 5H2O |
8.DC.30 | Kayrobertsonite | [MnAl2(PO4)2(OH)2(H2O)4] · 2H2O |
8.DC.30 | Kummerite | Mn2+Fe3+Al(PO4)2(OH)2 · 8H2O |
8.DC.32 | Tinticite | Fe3+3(PO4)2(OH)3 · 3H2O |
8.DC.32 | Kamarizaite | Fe3+3(AsO4)2(OH)3 · 3H2O |
8.DC.35 | Vauxite | Fe2+Al2(PO4)2(OH)2 · 6H2O |
8.DC.37 | Vantasselite | Al4(PO4)3(OH)3 · 9H2O |
8.DC.40 | Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
8.DC.45 | Gormanite | (Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
8.DC.45 | Souzalite | (Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2O |
8.DC.47 | Kingite | Al3(PO4)2F2(OH) · 7H2O |
8.DC.50 | Wavellite | Al3(PO4)2(OH,F)3 · 5H2O |
8.DC.50 | Allanpringite | Fe3+3(PO4)2(OH)3 · 5H2O |
8.DC.50 | Fluorwavellite | Al3(PO4)2(OH)2F · 5H2O |
8.DC.52 | Kribergite | Al5(PO4)3(SO4)(OH)4 · 4H2O |
8.DC.55 | Mapimite | Zn2Fe3+3(AsO4)3(OH)4 · 10H2O |
8.DC.57 | Ogdensburgite | Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O |
8.DC.60 | Nevadaite | (Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2O |
8.DC.60 | Cloncurryite | Cu0.5(VO)0.5Al2(PO4)2F2 · 5H2O |
8.DC.62 | Kenngottite | Mn2+3Fe3+4(PO4)4(OH)6(H2O)2 |
8.DC.67 | Molinelloite | Cu(H2O)(OH)V4+O(V5+O4) |
8.DC.70 | Whitecapsite | H16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2O |
8.DC.75 | Heimite | PbCu2(AsO4)(OH)3 · 2H2O |
8.DC.80 | Lednevite | Cu[PO3(OH)] · H2O |
Fluorescence of Cobaltarthurite
Not fluorescent.
Other Information
Notes:
Readily soluble in 1:1 HCl, which rapidly turns yellowish.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Cobaltarthurite
mindat.org URL:
https://www.mindat.org/min-11113.html
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References for Cobaltarthurite
Reference List:
Jambor, J. L., Vinals, J., Groat, L. A., Raudsepp, M. (2002) Cobaltarthurite, Co2+Fe3+2(AsO4)2(OH)2·4H2O, a new member of the arthurite group. The Canadian Mineralogist, 40 (2) 725-732 doi:10.2113/gscanmin.40.2.725
Raudsepp, M., Pani, E. (2002) The crystal structure of cobaltarthurite, Co2+Fe3+2(AsO4)2(OH)2·4H2O: a Rietveld refinement. The Canadian Mineralogist, 40 (2) 733-737 doi:10.2113/gscanmin.40.2.733
Localities for Cobaltarthurite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Brazil | |
| deMelo et al. (2017) |
Finland | |
| Tuisku |
Italy | |
| Caboni et al. (2018) |
Morocco | |
| Georges Favreau collection - 2007. +1 other reference |
| Kampf (2004) |
Spain (TL) | |
| Lapis 2002 (11) +1 other reference |
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La Reconquistada claim, Pastrana, Mazarrón, Murcia, Spain