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Denisovite

A valid IMA mineral species
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About DenisoviteHide

Formula:
K14+x(Ca,Na,Mn,Fe)48[Si60O162]F16(Ox,OH4-x) · 2H2O
Colour:
Gray with greenish tint
Lustre:
Pearly
Hardness:
4 - 5
Specific Gravity:
2.76
Crystal System:
Monoclinic
Name:
Named in honor of Alexander Petrovich Denisov (Александр Петрович Денисов) (06 June 1918, Chausy, Tsaritsynsky, Saratov province, Russian SFSR - 31 January 1972, Apatity, USSR), geologist with the Geological Institute, Kola Branch, Acadademy of Science, U.S.S.R. He was an expert in X-ray methods for studying minerals.
The currently accepted formula, K14+x(Ca,Na,Mn,Fe)48[Si60O162]F16(Ox,OH4−x)·2H2O, places the mineral among the most structurally complex ones.


Unique IdentifiersHide

Mindat ID:
1261
Long-form identifier:
mindat:1:1:1261:0
GUID
(UUID V4):
7eafb989-4936-42ff-85f3-f13cf350239a

IMA Classification of DenisoviteHide

Classification of DenisoviteHide

9.HA.85

9 : SILICATES (Germanates)
H : Unclassified silicates
A : With Alkali and Alkali-earth Elements
65.2.1.7

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
2 : Single-Width Unbranched Chains, W=1 with chains P=3
14.6.4

14 : Silicates not Containing Aluminum
6 : Silicates of Ca with alkali or Mg or both

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
DnvIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DenisoviteHide

Pearly
Transparency:
Translucent
Colour:
Gray with greenish tint
Comment:
Colorless under microscope
Hardness:
4 - 5 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Cleavage or parting observed perpendicular to elongation of crystals
Fracture:
Splintery
Density:
2.76 g/cm3 (Measured)    2.81 g/cm3 (Calculated)

Optical Data of DenisoviteHide

Type:
Biaxial (+)
RI values:
nα = 1.567 nβ = 1.568 nγ = 1.576
2V:
Measured: 20° to 30°
Max Birefringence:
δ = 0.009
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r > v strong

Chemistry of DenisoviteHide

Mindat Formula:
K14+x(Ca,Na,Mn,Fe)48[Si60O162]F16(Ox,OH4-x) · 2H2O
Common Impurities:
Ti,Al,Fe,Nb,Mn,Mg,Sr,Ba,Li,Rb,P

Crystallography of DenisoviteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 30.92 Å, b = 7.20 Å, c = 18.27 Å
β = 95°
Ratio:
a:b:c = 4.294 : 1 : 2.538
Unit Cell V:
4,051.86 ų (Calculated from Unit Cell)
Z:
20
Morphology:
As acicular crystals, in parallel columnar aggregates, to 15 cm.
Comment:
Point Group: n.d.; Space Group: n.d.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.65 Å(80)
3.32 Å(100)
3.24 Å(90)
3.08 Å(80)
3.03 Å(90)
2.79 Å(80)
2.78 Å(80)
2.75 Å(100)
2.69 Å(80)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of DenisoviteHide

General Appearance of Type Material:
parallel columnar aggregates up to 10-15 cm across, consisting of acicular individuals
Place of Conservation of Type Material:
Geology Museum, Kola Branch, Academy of Sciences, Apatity, 5774/1{2;
Mining Institute, St. Petersburg, 1295/1{2; Il'menskii Preserve Museum, Miass, 5392;
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 82762, vis4773;
The Natural History Museum, London, England, 1994,7..
Associated Minerals at Type Locality:
Reference:
Men´shikov, Y.P. (1984) Denisovite Ca4(K1.4Na0.6)2 Si6O16(F,OH)2 - a new mineral from the Khibina massif. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 113(6): 718-723.

Synonyms of DenisoviteHide

Other Language Names for DenisoviteHide

German:Denisovit
Spanish:Denisovita

Common AssociatesHide

Associated Minerals Based on Photo Data:
6 photos of Denisovite associated with AegirineNaFe3+Si2O6
4 photos of Denisovite associated with NephelineNa3K(Al4Si4O16)
1 photo of Denisovite associated with FluoriteCaF2
1 photo of Denisovite associated with MicroclineK(AlSi3O8)

Related Minerals - Strunz-mindat GroupingHide

9.HA.QeltiteCa3TiSi2(Fe3+2Si)O14Trig. 3 2 : P3 2 1
9.HA.Kalyuzhnyite-(Ce)NaKCaSrCeTi(Si8O21)OF(H2O)3Mon. 2/m : P2/b
9.HA.ShinichengiteCa5[BSi2O7(OH)2]2 · 6H2OTric. 1 : P1
9.HA.MoragiteCa3TiSi2(Al2Si)O14Trig. 3 2 : P3 2 1
9.HA.05ErtixiiteNa2Si4O9Iso.
9.HA.10KenyaiteNa2Si22O41(OH)8 · 6H2OMon.
9.HA.20WawayandaiteCa6Mn2BBe9Si6O23(OH,Cl)15Mon.
9.HA.25MagbasiteKBaFe3+Mg7Si8O22(OH)2F6Orth. mmm (2/m 2/m 2/m) : Cmma
9.HA.35DemagistrisiteBaCa2Mn3+4(Si3O10)(Si2O7)(OH)4 · 3H2OOrth. mm2 : Amm2
9.HA.37DonwilhelmsiteCaAl4Si2O11Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.HA.40IgumnoviteCa3Al2[SiO4]2[◻Cl4]Iso.
9.HA.40KasatkiniteBa2Ca8B5Si8O32(OH)3 · 6H2O Mon.
9.HA.42PaqueiteCa3TiSi2(Al,Ti,Si)3O14Trig. 3 2 : P3 2 1
9.HA.45RippiteK2(Nb,Ti)2(Si4O12)O(O,F)Tet.
9.HA.47ZagamiiteCaAl2Si3.5O11Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.HA.50α-CarnegieiteNaAlSiO4
9.HA.50RudenkoiteSr3(Al3.5Si3.5)O10(OH,O)8Cl2 · H2OMon.
9.HA.52Atheriastitenear Ca5MgFeAl6Si8O32 · 5H2O
9.HA.55Balvraidite
9.HA.55FoshallasiteCa3[Si2O7] · 3H2O(?)
9.HA.57BhreckiteCa, Mg, Fe, Si, O, H
9.HA.60Bravaisite
9.HA.60NagelschmidtiteCa7(SiO4)2(PO4)2Hex. 6 : P61
9.HA.65Caryochroite(Na,Sr)3(Fe3+,Mg)10[Ti2Si12O37] · (H2O,O,OH)17Mon. 2/m
9.HA.70JuaniteCa10Mg4Al2Si11O39 · 4H2O or nearOrth.
9.HA.75TacharaniteCa12Al2Si18O33 (OH)36Mon.
9.HA.80OyeliteCa10Si8B2O29 · 12.5H2OTric. 1 : P1
9.HA.90TiettaiteK4Na12Fe3+Si16O41(OH)4 · 2H2OOrth. mmm (2/m 2/m 2/m) : Cmcm

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DenisoviteHide

References for DenisoviteHide

Localities for DenisoviteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Aldan Shield
    • Chara and Tokko Rivers Confluence
Konev et al. (1987) +1 other reference
  • Murmansk Oblast
    • Khibiny Massif
Men´shikov (1984) +1 other reference
Men´shikov (1984) +2 other references
 
Mineral and/or Locality  
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