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Alluaivite

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Formula:
Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl · 2H2O
Colour:
Colorless to weak brownish pink
Lustre:
Vitreous
Hardness:
5 - 6
Crystal System:
Trigonal
Member of:
Name:
After the type locality occurrence on Mt. Alluaiv, Lovozero massif, Kola Peninsula, Russia.
This page provides mineralogical data about Alluaivite.


Hide all sections | Show all sections

Classification of AlluaiviteHide

Approved
9.CO.10

9 : SILICATES (Germanates)
C : Cyclosilicates
O : [Si9O27]18- 9-membered rings
64.1b.1.1

64 : CYCLOSILICATES Rings with Other Anions and Insular Silicate Groups
1b :
17.3.7

17 : Silicates Containing other Anions
3 : Silicates with chloride (including aluminosilicates)

Physical Properties of AlluaiviteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless to weak brownish pink
Hardness:
5 - 6 on Mohs scale
Tenacity:
Brittle
Fracture:
Conchoidal

Optical Data of AlluaiviteHide

Type:
Uniaxial (+)
RI values:
nω = 1.618 nε = 1.626
Max Birefringence:
δ = 0.008
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate

Chemical Properties of AlluaiviteHide

Formula:
Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl · 2H2O
IMA Formula:
Na19(Ca,Mn2+)6(Ti,Nb)3Si26O74Cl · 2H2O
Common Impurities:
Zr,La,Ce,TR,Sr,Ba,K

Crystallography of AlluaiviteHide

Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 14.04 Å, c = 60.6 Å
Ratio:
a:c = 1 : 4.316
Unit Cell V:
10,345.17 ų (Calculated from Unit Cell)
Morphology:
Irregular accumulations, to 1 mm.

Type Occurrence of AlluaiviteHide

Place of Conservation of Type Material:
Mining Museum, St. Petersburg Mining Institute, 1993/1{2; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia; The Natural History Museum, London, England, 1994,1.
Geological Setting of Type Material:
In ultra-agpaitic pegmatites in a di®erentiated alkalic massif.
Associated Minerals at Type Locality:

Synonyms of AlluaiviteHide

Other Language Names for AlluaiviteHide

Relationship of Alluaivite to other SpeciesHide

Member of:
Other Members of this group:
AndrianoviteNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5Trig. 3m : R3m
Aqualite(H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9ClTrig. 3 : R3
CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
DavinciiteNa12K3Ca6Fe2+3Zr3(Si26O73OH)Cl2 Trig. 3m : R3m
DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m
EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
FeklicheviteNa11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5Trig. 3m : R3m
FengchengiteNa123(Ca,Sr)6Fe3+3 Zr3Si(Si25O73)(H2O,OH)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m
GolysheviteNa10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3 · H2OTrig. 3m : R3m
Hydrorastsvetaevite(Na11(H3O)11K6(H2O)1.5Sr)Ca12Fe3Na2MnZr6Si52O144(OH)4.5Cl3.5Trig. 3m : R3m
Ikranite(Na,H3O)15(Ca,Mn2+)6Fe3+2Zr3-4[Cl|(H0-3Si3O9)2|{(Si9O27)2,(Si9O27)2SiO}] · 2-3H2OTrig. 3m : R3m
Ilyukhinite(H3O,Na)14Ca6Mn2Zr3Si26O72(OH)2·3H2OTrig. 3m : R3m
Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
KhomyakoviteNa12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
ManganoeudialyteNa14Ca6Mn3Zr3[Si26O72(OH)2](H2O,Cl,O,OH)6Trig. 3m : R3m
ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
MogoviditeNa9(Ca,Na)12Fe2Zr3Si25O72(CO3) (OH)4Trig. 3m : R3m
OneilliteNa15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2Trig. 3 : R3
RaslakiteNa15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5[(Cl,OH)|(Si3O9)2|(Si9O27)2SiO] · 3(OH,H2O)Trig. 3
RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
TaseqiteNa12Sr3Ca6Fe3Zr3Nb[Cl2|(Si3O9)2|(Si9O27)2SiO] · 3(O,OH,H2O)Trig. 3m : R3m
UM1971-22-SiO:CaClFeHMgMnNaNbZrNa12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2[Si3O9]2ClTrig. 3m : R3m
UM1990-79-SiO:CaClFeHMnNaNbREEZrNa14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl)
UM1990-80-SiO:CaFeHMnNaNbREEZrNa14Ca4(Mn,Ca)2Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Mn,Al,Ti)3(Na,Ce,La,Y,Mn)(Na,H2O,K,Sr)(OH)7-8
UM1998-21-SiO:CaCeClHMnNaZrNa16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4Trig. 3m : R3m
UM1999-36-SiO:CaCeHMnNaNbSrZrNa17(Ca,Ce,Sr)2Mn3(Zr,Nb)4Si25O73(O,OH,F,Cl)5Trig. 3 : R3
UM2000-66-SiO:CaClFeHMnNaNbSrZrNa12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11Trig. 3m : R3m
UM2003-39-SiO:CaClFeHHfNaNbSrTaTiZrNa12(Na,K,Mn,Sr)2Ca5(Ca,Mn)(Zr,Hf)3(Fe,◻,Ta)3(Si,Nb,W)(Si,Al,Ti)Si24O72(OH,O)3.5Cl•1.2H2O
UM2004-51-SiO:CaClFFeHNaNbTiNa16Ca6(Fe,Mn)3Zr3(Ti,Nb)Si26O72FCl0.5•nH2O
UM2006-17-SiO:CaClFFeHMnNaZrNa15(Ca3Mn3)Zr3(Fe,Zr)3SiSi(Si3O9)2(Si9O27)2O2(OH,F,Cl)3•2H2O
UM2006-18-SiO:CaClFFeHMnNaZrNa15Ca3(Mn,Fe)3Zr3(Zr,Na)3(Si,Nb)(S,Ti,Si)(Si3O9)2(Si9O27)2(O,OH)5(Cl,F,H2O)
UM2006-28-SiO:CaHMnNaZrNa33Ca12Zr6Mn3(Mn,Nb,Ti)2Si50O132(O,OH)12(OH,H2O,Cl)10
Unnamed (Eudialyte 3248)Na29Ca12Zr6[Si48O132(O,OH)12]{[Na]4[Si]2}{[Mn]3[Mn,Nb,Ti]2}(OH,H2O,Cl)10Trig. 3m (3 2/m) : R3m
Unnamed (Hydrated Hydrous Na-Ca-Mn-Fe-Zr-Ti Silicate Chloride)Na37Ca10Mn2FeZr6Si50(Ti,Nb)2O144(OH)5Cl3·H2OTrig. 3m : R3m
VoronkoviteNa15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2OTrig. 3 : R3
Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2OTrig. 3m : R3m

Common AssociatesHide

Associated Minerals Based on Photo Data:
Eudialyte4 photos of Alluaivite associated with Eudialyte on mindat.org.
Cancrisilite4 photos of Alluaivite associated with Cancrisilite on mindat.org.
Thermonatrite2 photos of Alluaivite associated with Thermonatrite on mindat.org.
Villiaumite1 photo of Alluaivite associated with Villiaumite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

9.CO.10EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
9.CO.10FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
9.CO.10Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
9.CO.10KhomyakoviteNa12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
9.CO.10ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
9.CO.10OneilliteNa15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2Trig. 3 : R3
9.CO.10RaslakiteNa15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5[(Cl,OH)|(Si3O9)2|(Si9O27)2SiO] · 3(OH,H2O)Trig. 3
9.CO.10FeklicheviteNa11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5Trig. 3m : R3m
9.CO.10CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
9.CO.10Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2OTrig. 3m : R3m
9.CO.10Ikranite(Na,H3O)15(Ca,Mn2+)6Fe3+2Zr3-4[Cl|(H0-3Si3O9)2|{(Si9O27)2,(Si9O27)2SiO}] · 2-3H2OTrig. 3m : R3m
9.CO.10TaseqiteNa12Sr3Ca6Fe3Zr3Nb[Cl2|(Si3O9)2|(Si9O27)2SiO] · 3(O,OH,H2O)Trig. 3m : R3m
9.CO.10RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
9.CO.10GolysheviteNa10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3 · H2OTrig. 3m : R3m
9.CO.10Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
9.CO.10Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
9.CO.10MogoviditeNa9(Ca,Na)12Fe2Zr3Si25O72(CO3) (OH)4Trig. 3m : R3m
9.CO.10GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m
9.CO.10Aqualite(H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9ClTrig. 3 : R3
9.CO.10DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m
9.CO.10AndrianoviteNa12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5Trig. 3m : R3m
9.CO.10VoronkoviteNa15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2OTrig. 3 : R3
9.CO.10UM1999-36-SiO:CaCeHMnNaNbSrZrNa17(Ca,Ce,Sr)2Mn3(Zr,Nb)4Si25O73(O,OH,F,Cl)5Trig. 3 : R3
9.CO.10UM2000-66-SiO:CaClFeHMnNaNbSrZrNa12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11Trig. 3m : R3m
9.CO.10ManganoeudialyteNa14Ca6Mn3Zr3[Si26O72(OH)2](H2O,Cl,O,OH)6Trig. 3m : R3m
9.CO.10UM1990-78-SiO:CaClFeHKNaZr(H3O)7(Na,K)5(Ca,Sr,Mn)6Zr3[Si3O7(O,OH)2]2[Si9O23(O,OH)4]2[SiNaFe(Zr,Ti,Al,Nb)□]Cl1.5(O,OH)Trig. 3m : R3m
9.CO.10UM1990-79-SiO:CaClFeHMnNaNbREEZrNa14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl)
9.CO.10UM1971-22-SiO:CaClFeHMgMnNaNbZrNa12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2[Si3O9]2ClTrig. 3m : R3m
9.CO.10UM1998-21-SiO:CaCeClHMnNaZrNa16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4Trig. 3m : R3m

Related Minerals - Dana Grouping (8th Ed.)Hide

64.1b.1.2RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
64.1b.1.3Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
64.1b.1.4DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

17.3.1RustumiteCa10(Si2O7)2(SiO4)(OH)2Cl2Mon.
17.3.2ZunyiteAl13Si5O20(OH,F)18ClIso. 4 3m : F4 3m
17.3.3SodaliteNa8(Al6Si6O24)Cl2Iso. 4 3m : P4 3n
17.3.4MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
17.3.5TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
17.3.6EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
17.3.8NasonitePb6Ca4(Si2O7)3Cl2Hex.
17.3.9AsisitePb7SiO9Cl2 Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
17.3.10JagoitePb18Fe3+4[Si4(Si,Fe3+)6][Pb4Si16(Si,Fe)4]O82Cl6Hex.
17.3.11FriedeliteMn2+8Si6O15(OH,Cl)10Mon. 2/m : B2/m
17.3.12Pyrosmalite-(Fe)Fe2+8Si6O15(OH,Cl)10Trig. 3m (3 2/m) : P3m1
17.3.13Pyrosmalite
17.3.14Pyrosmalite-(Mn)Mn2+8Si6O15(OH,Cl)10Trig.
17.3.16Mcgillite(Mn,Fe)8Si6O15(OH)8Cl2Mon. 2/m : B2/m
17.3.17TraskiteBa21Ca(Fe2+,Mn,Ti)4(Ti,Fe,Mg)12(Si12O36)(Si2O7)6(O,OH)30Cl6·14H2O Hex.
17.3.18MuiriteBa10Ca2Mn2+Ti[(OH,Cl,F)|HSi2O7]5Tet. 4/mmm (4/m 2/m 2/m) : P4/mmm
17.3.19VerplanckiteBa2(Mn,Fe,Ti)Si2O6(O,OH,Cl,F)2 · 3H2O or nearHex.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for AlluaiviteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Khomyakov, A.P., Netschelyustov, G.N., Rastsvetaeva, R.K. (1990) Alluaivite Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl·2H2O–a new titanosilicate of of eudialyte–like structure. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 119(1): 117-120.
Rastsvetaeva, R.K., Khomyakov, A.P., Andrianov, V.I., Gusev, A.I. (1990) Crystal structure of alluaivite. Doklady Akademii Nauk SSSR: 312: 1379-1383.
Jambor, J.L., Puziewicz, J. (1991) New mineral names. American Mineralogist: 76: 1728-1735.
New Mins. (1997) New Minerals 1990-1994.
Johnsen, O., Ferraris, G., Gault, R.A., Grice, J.D., Kampf, A.R., Pekov, I.V. (2003) The nomenclature of eudialyte-group minerals. The Canadian Mineralogist: 41: 785-794.

Internet Links for AlluaiviteHide

Localities for AlluaiviteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Russia
 
  • Northern Region
    • Murmanskaya Oblast'
      • Khibiny Massif
O.A. Ageeva e.a. Alluaivite and genetic aspect of the forming of enriched in titanium eudialytes in Khibina massif, - ZVMO, 2002, N1, pp.99-106.
      • Lovozero Massif
[ZVMO (1990) 119,1 117-120; World of Stones 95:5-6, p. 64]; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Ivanyuk, G. Y., Pakhomovsky, Y. A., & Yakovenchuk, V. N. (2015). Eudialyte-group minerals in rocks of Lovozero layered complex at Mt. Karnasurt and Mt. Kedykvyrpakhk. Geology of Ore Deposits, 57(7), 600-613.
Ivanyuk, G. Y., Pakhomovsky, Y. A., & Yakovenchuk, V. N. (2015). Eudialyte-group minerals in rocks of Lovozero layered complex at Mt. Karnasurt and Mt. Kedykvyrpakhk. Geology of Ore Deposits, 57(7), 600-613.
Mineral and/or Locality  
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