Ferripyrophyllite
A valid IMA mineral species
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About Ferripyrophyllite
Formula:
Fe3+Si2O5(OH)
Colour:
brownish yellow
Hardness:
1½ - 2
Specific Gravity:
2.97 - 3.01
Crystal System:
Monoclinic
Member of:
Name:
for the ferric iron analogue of pyrophyllite
Unique Identifiers
Mindat ID:
1498
Long-form identifier:
mindat:1:1:1498:0
GUID
(UUID V4):
(UUID V4):
1a73e95f-9a34-49d7-9f99-e61a6bdc582a
IMA Classification of Ferripyrophyllite
Approved
Approval year:
1978
Classification of Ferripyrophyllite
9.EC.10
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.1.2
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
14.19.5
14 : Silicates not Containing Aluminum
19 : Silicates of Fe
14 : Silicates not Containing Aluminum
19 : Silicates of Fe
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMAâCNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMAâCNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Fprl | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Fprl | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261â264 doi:10.1180/clm.2020.30 |
Physical Properties of Ferripyrophyllite
Transparency:
Translucent
Colour:
brownish yellow
Hardness:
1½ - 2 on Mohs scale
Tenacity:
Waxy
Density:
2.97 - 3.01 g/cm3 (Measured) 3.05 g/cm3 (Calculated)
Optical Data of Ferripyrophyllite
Type:
Biaxial
RI values:
nα = 1.650 - 1.660 nβ = 1.676 - 1.678 nγ = 1.686 - 1.688
Max Birefringence:
δ = 0.036
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r < v weak
Pleochroism:
Visible
Comments:
X = Y = greenish; Z = bright yellow.
Chemistry of Ferripyrophyllite
Mindat Formula:
Fe3+Si2O5(OH)
Elements listed:
Common Impurities:
Mg,Ca,Al,K,Na
Crystallography of Ferripyrophyllite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 5.26 Å, b = 9.1 Å, c = 10.01 Å
β = 95.5°
β = 95.5°
Ratio:
a:b:c = 0.578 : 1 : 1.1
Unit Cell V:
476.93 Ă
Âł (Calculated from Unit Cell)
Z:
4
Comment:
Space Group: n.d.
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
9.6 Ă | (8) |
4.54 Ă | (10) |
3.17 Ă | (7) |
2.62 Ă | (4) |
2.47 Ă | (4) |
1.725 Ă | (3) |
1.518 Ă | (8) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 3b: Earthâs earliest hydrosphere | >4.45 |
17 : Marine authigenic Hadean minerals (see also #24) | |
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47h : [Near-surface oxidized, dehydrated minerals] |
Type Occurrence of Ferripyrophyllite
Place of Conservation of Type Material:
Moscow University, Moscow; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 79071, vis5430, 5431.
Reference:
Chukhrov F V, Zvyagin B B, Drits V A, Gorshkov A I, Ermilova L P, Goilo E A, Rudnitskaya E S (1978) The ferric analogue of pyrophyllite and related phases. Proceedings of the International Clay Conference, Oxford 1978, 55-64
Synonyms of Ferripyrophyllite
Other Language Names for Ferripyrophyllite
German:Ferripyrophyllit
Spanish:Ferripyrophyllita
Relationship of Ferripyrophyllite to other Species
Member of:
Other Members of this group:
Minnesotaite | Fe2+3Si4O10(OH)2 | Tric. 1 : P1 |
Pyrophyllite | Al2Si4O10(OH)2 | Tric. 1 |
Talc | Mg3Si4O10(OH)2 | Tric. 1 : P1 |
Willemseite | Ni3Si4O10(OH)2 | Mon. |
Common Associates
Associated Minerals Based on Photo Data:
3 photos of Ferripyrophyllite associated with Quartz | SiO2 |
1 photo of Ferripyrophyllite associated with Cerite-(CeCa) | (Ce7Ca2)â»Mg(SiO4)3(SiO3OH)4(OH)3 |
1 photo of Ferripyrophyllite associated with Törnebohmite-(Ce) | Ce2Al(SiO4)2(OH) |
1 photo of Ferripyrophyllite associated with Ferriallanite-(Ce) | (CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
Related Minerals - Strunz-mindat Grouping
9.EC. | Balestraite | KLi2V5+Si4O12 |
9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
9.EC.05 | Minnesotaite | Fe2+3Si4O10(OH)2 |
9.EC.05 | Talc | Mg3Si4O10(OH)2 |
9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
9.EC.9.EC. | Voloshinite | Rb(LiAl1.5â»0.5)(Al0.5Si3.5)O10F2 |
9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
9.EC.10 | Manganiceladonite | K(MgMn3+â»)(Si4O10)(OH)2 |
9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
9.EC.15 | Celadonite | K(MgFe3+â»)(Si4O10)(OH)2 |
9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
9.EC.15 | Montdorite | (K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4 |
9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
9.EC.15 | Roscoelite | K(V3+,Al)2(AlSi3O10)(OH)2 |
9.EC.15 | Tobelite | (NH4,K)Al2(AlSi3O10)(OH)2 |
9.EC.15 | Aluminoceladonite | K(MgAlâ»)(Si4O10)(OH)2 |
9.EC.15 | Chromphyllite | K(Cr,Al)2(AlSi3O10)(OH,F)2 |
9.EC.15 | Ferroaluminoceladonite | K(Fe2+Alâ»)(Si4O10)(OH)2 |
9.EC.15 | Ferroceladonite | K(Fe2+Fe3+â»)(Si4O10)(OH)2 |
9.EC.15 | Chromceladonite | K(MgCrâ»)(Si4O10)(OH)2 |
9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
9.EC.15 | Ganterite | (Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2 |
9.EC.15 | UM1988-22-SiO:AlCaFFeHKLiMg | KLiMgAl2Si3O10F2 |
9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
9.EC.20 | Masutomilite | (K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2 |
9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
9.EC.20 | Tetraferriphlogopite | KMg3(Fe3+Si3O10)(OH,F)2 |
9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
9.EC.20 | Wonesite | (Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4 |
9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
9.EC.20 | UM2004-49-SiO:AlCsFHKLi | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
9.EC.20 | Orlovite | KLi2Ti(Si4O10)OF |
9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
9.EC.20 | Chloroferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
9.EC.22 | Pimelite | Ni3Si4O10(OH)2 · 4H2O |
9.EC.30 | Chlorophaeite | (Ca,Mg,Fe)2Fe2Si4O13 · 10H2O |
9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
9.EC.40 | Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O |
9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
9.EC.45 | Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 |
9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
9.EC.52 | Tarasovite | near NaKAl11Si13O40(OH)9 · 3H2O |
9.EC.55 | Baileychlore | (Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8 |
9.EC.55 | Chamosite | (Fe2+)5Al(Si,Al)4O10(OH,O)8 |
9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
9.EC.55 | Cookeite | (LiAl4â»)[AlSi3O10](OH)8 |
9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
9.EC.55 | Gonyerite | (Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8 |
9.EC.55 | Nimite | (Ni,Mg,Al)6((Si,Al)4O10)(OH)8 |
9.EC.55 | Orthochamosite | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
9.EC.55 | Sudoite | Mg2Al3(Si3Al)O10)(OH)8 |
9.EC.55 | Donbassite | Al4.33(Si3Al)O10(OH)8 |
9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
9.EC.55 | Borocookeite | (LiAl4â»)[BSi3O10](OH)8 |
9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
9.EC.60 | Tosudite | Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O |
9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ferripyrophyllite
mindat.org URL:
https://www.mindat.org/min-1498.html
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References for Ferripyrophyllite
Reference List:
Localities for Ferripyrophyllite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Brazil | |
| |
Czech Republic | |
| M.E. Ciriotti |
Germany | |
| Habel (2009) |
| Tschuchrow +5 other references |
Italy | |
| Fernando Caboni et al. (2023) |
| Batacchi C. et al. (2016) |
Kazakhstan | |
| Tschuchrow +6 other references |
Red Sea | |
Badaut et al. (1992) | |
Russia | |
| Filina et al. (2019) |
Sweden | |
| Ulf Nyberg collection. Identification ... |
USA | |
| FĂ€rber (n.d.) |
Mars | |
| Tu VM et al. (2021) |
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Tulagai Pb-Cu deposit, Akshatau, Shet District, Karaganda Region, Kazakhstan