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Ferripyrophyllite

A valid IMA mineral species
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About FerripyrophylliteHide

Formula:
Fe3+Si2O5(OH)
Colour:
brownish yellow
Hardness:
1½ - 2
Specific Gravity:
2.97 - 3.01
Crystal System:
Monoclinic
Name:
for the ferric iron analogue of pyrophyllite
Pyrophyllite-Talc Group.
The ferric iron analogue of pyrophyllite.
Compare also minnesotaite.


Unique IdentifiersHide

Mindat ID:
1498
Long-form identifier:
mindat:1:1:1498:0
GUID
(UUID V4):
1a73e95f-9a34-49d7-9f99-e61a6bdc582a

IMA Classification of FerripyrophylliteHide

Classification of FerripyrophylliteHide

9.EC.10

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.1.2

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
14.19.5

14 : Silicates not Containing Aluminum
19 : Silicates of Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
FprlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
FprlWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of FerripyrophylliteHide

Transparency:
Translucent
Colour:
brownish yellow
Hardness:
1½ - 2 on Mohs scale
Tenacity:
Waxy
Density:
2.97 - 3.01 g/cm3 (Measured)    3.05 g/cm3 (Calculated)

Optical Data of FerripyrophylliteHide

Type:
Biaxial
RI values:
nα = 1.650 - 1.660 nβ = 1.676 - 1.678 nγ = 1.686 - 1.688
Max Birefringence:
δ = 0.036
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r < v weak
Pleochroism:
Visible
Comments:
X = Y = greenish; Z = bright yellow.

Chemistry of FerripyrophylliteHide

Mindat Formula:
Fe3+Si2O5(OH)
Common Impurities:
Mg,Ca,Al,K,Na

Crystallography of FerripyrophylliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 5.26 Å, b = 9.1 Å, c = 10.01 Å
β = 95.5°
Ratio:
a:b:c = 0.578 : 1 : 1.1
Unit Cell V:
476.93 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space Group: n.d.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.6 Å(8)
4.54 Å(10)
3.17 Å(7)
2.62 Å(4)
2.47 Å(4)
1.725 Å(3)
1.518 Å(8)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3b: Earth’s earliest hydrosphere>4.45
17 : Marine authigenic Hadean minerals (see also #24)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47h : [Near-surface oxidized, dehydrated minerals]

Type Occurrence of FerripyrophylliteHide

Place of Conservation of Type Material:
Moscow University, Moscow; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 79071, vis5430, 5431.
Reference:
Chukhrov F V, Zvyagin B B, Drits V A, Gorshkov A I, Ermilova L P, Goilo E A, Rudnitskaya E S (1978) The ferric analogue of pyrophyllite and related phases. Proceedings of the International Clay Conference, Oxford 1978, 55-64

Synonyms of FerripyrophylliteHide

Other Language Names for FerripyrophylliteHide

Relationship of Ferripyrophyllite to other SpeciesHide

Other Members of this group:
MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
PyrophylliteAl2Si4O10(OH)2Tric. 1
TalcMg3Si4O10(OH)2Tric. 1 : P1
WillemseiteNi3Si4O10(OH)2Mon.

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Ferripyrophyllite associated with QuartzSiO2
1 photo of Ferripyrophyllite associated with Cerite-(CeCa)(Ce7Ca2)◻Mg(SiO4)3(SiO3OH)4(OH)3
1 photo of Ferripyrophyllite associated with Törnebohmite-(Ce)Ce2Al(SiO4)2(OH)
1 photo of Ferripyrophyllite associated with Ferriallanite-(Ce)(CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)

Related Minerals - Strunz-mindat GroupingHide

9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15UM1988-22-SiO:AlCaFFeHKLiMgKLiMgAl2Si3O10F2Mon.
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon. 2 : B2
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2Mon. 2/m : B2/m
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20Chloroferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.22PimeliteNi3Si4O10(OH)2 · 4H2OHex.
9.EC.30Chlorophaeite(Ca,Mg,Fe)2Fe2Si4O13 · 10H2O
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.52Tarasovitenear NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+)5Al(Si,Al)4O10(OH,O)8Mon. 2/m : B2/m
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon. 2/m : B2/m
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon. 2/m : B2/m
9.EC.55DonbassiteAl4.33(Si3Al)O10(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m : B2/m
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FerripyrophylliteHide

References for FerripyrophylliteHide

Localities for FerripyrophylliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Bahia
Czech Republic
 
  • Karlovy Vary Region
    • Sokolov District
      • BƙezovĂĄ
M.E. Ciriotti
Germany
 
  • Bavaria
    • Lower Bavaria
      • Freyung-Grafenau District
        • Röhrnbach
Habel (2009)
  • Saxony
    • Erzgebirgskreis
      • Eibenstock
Tschuchrow +5 other references
Italy
 
  • Sardinia
    • Metropolitan City of Cagliari
      • Sarroch
Fernando Caboni et al. (2023)
  • Tuscany
    • Metropolitan City of Florence
Batacchi C. et al. (2016)
Kazakhstan
 
  • Karaganda Region
    • Shet District
      • Akshatau (Aqshatau)
Tschuchrow +6 other references
Red Sea
 
Badaut et al. (1992)
Russia
 
  • Murmansk Oblast
Filina et al. (2019)
Sweden
 
  • VĂ€stmanland County
    • Skinnskatteberg
      • Riddarhyttan
Ulf Nyberg collection. Identification ...
USA
 
  • California
    • Mendocino County
      • Cloverdale area
FĂ€rber (n.d.)
Mars
 
  • Aeolis quadrangle
Tu VM et al. (2021)
 
Mineral and/or Locality  
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