Guanajuatite
A valid IMA mineral species - grandfathered
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About Guanajuatite
Formula:
Bi2Se3
Se may be replaced by minor S.
Colour:
Bluish gray
Lustre:
Metallic
Hardness:
2½ - 3
Specific Gravity:
6.25 - 6.98
Crystal System:
Orthorhombic
Member of:
Name:
From the type locality near Guanajuato, Mexico.
Type Locality:
Dimorph of:
The Se (or selenide) analogue of bismuthinite.
Easily distinguishable from the more common (in Guanajuato) paraguanajuatite if macroscopic as the latter has platy/foliated aggregates with perfect cleavage whereas guanajuatite resembles minerals of the stibnite group.
Compare 'UM1987-16-Se:BiPbTe'.
Easily distinguishable from the more common (in Guanajuato) paraguanajuatite if macroscopic as the latter has platy/foliated aggregates with perfect cleavage whereas guanajuatite resembles minerals of the stibnite group.
Compare 'UM1987-16-Se:BiPbTe'.
Unique Identifiers
Mindat ID:
1761
Long-form identifier:
mindat:1:1:1761:5
GUID
(UUID V4):
(UUID V4):
821e74e8-9507-436b-af14-4554a6b283af
IMA Classification of Guanajuatite
Approved, 'Grandfathered' (first described prior to 1959)
Classification of Guanajuatite
2.DB.05
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
B : M:S = 2:3
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
B : M:S = 2:3
2.11.2.4
2 : SULFIDES
11 : AmBnXp, with (m+n):p = 2:3
2 : SULFIDES
11 : AmBnXp, with (m+n):p = 2:3
3.7.19
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
7 : Sulphides etc. of V, As, Sb and Bi
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
7 : Sulphides etc. of V, As, Sb and Bi
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Gj | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Guanajuatite
Metallic
Transparency:
Opaque
Colour:
Bluish gray
Streak:
Shiny gray
Hardness:
2½ - 3 on Mohs scale
Hardness:
VHN10=53 - 82 kg/mm2 - Vickers
Tenacity:
Sectile
Cleavage:
Distinct/Good
Distinct {010}
indistinct {001}
Distinct {010}
indistinct {001}
Density:
6.25 - 6.98 g/cm3 (Measured) 7.54 g/cm3 (Calculated)
Optical Data of Guanajuatite
Anisotropism:
Strong
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
400nm | 41.2% | 51.8% |
420nm | 41.8% | 51.8% |
440nm | 42.3% | 51.9% |
460nm | 42.8% | 51.9% |
480nm | 43.3% | 52.0% |
500nm | 43.3% | 52.0% |
520nm | 43.3% | 52.0% |
540nm | 43.1% | 52.0% |
560nm | 42.9% | 52.0% |
580nm | 42.7% | 52.2% |
600nm | 42.4% | 52.2% |
620nm | 42.2% | 52.1% |
640nm | 41.9% | 51.9% |
660nm | 41.5% | 51.6% |
680nm | 41.2% | 51.2% |
700nm | 40.8% | 50.7% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 52.2%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White with yellowish hue
Pleochroism:
Visible
Chemistry of Guanajuatite
Mindat Formula:
Bi2Se3
Se may be replaced by minor S.
Se may be replaced by minor S.
Elements listed:
Common Impurities:
S
Crystallography of Guanajuatite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 11.37 Å, b = 11.55 Å, c = 4.054 Å
Ratio:
a:b:c = 0.984 : 1 : 0.351
Unit Cell V:
532.39 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Acicular crystals, massive (granular, foliated, fibrous)
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0008969 | Guanajuatite | Caracas R, Gonze X (2005) First-principles study of the electronic properties of A2B3 minerals, with A=Bi,Sb and B=S,Se Physics and Chemistry of Minerals 32 295-300 | 2005 | 0 | 293 | ||
0014181 | Guanajuatite | Atabaeva E Y, Mashkov S A, Popova S V (1973) The crystal structure of a new modification of Bi2Se3-II Kristallografiya 18 173-174 | 1973 | Guanajuato, Mexico | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.19 Å | (100) |
3.65 Å | (90) |
1.989 Å | (70) |
2.88 Å | (60) |
2.58 Å | (50) |
2.31 Å | (50) |
5.16 Å | (40) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Geological Setting:
Low to moderate temperature hydrothermal deposits.
Type Occurrence of Guanajuatite
Place of Conservation of Type Material:
No designated type specimen.
Synonyms of Guanajuatite
Other Language Names for Guanajuatite
Relationship of Guanajuatite to other Species
Member of:
Other Members of this group:
Antimonselite | Sb2Se3 | Orth. mmm (2/m 2/m 2/m) : Pnma |
Bismuthinite | Bi2S3 | Orth. mmm (2/m 2/m 2/m) : Pnma |
Stibnite | Sb2S3 | Orth. mmm (2/m 2/m 2/m) |
Common Associates
Associated Minerals Based on Photo Data:
4 photos of Guanajuatite associated with Bohdanowiczite | AgBiSe2 |
4 photos of Guanajuatite associated with Naumannite | Ag2Se |
1 photo of Guanajuatite associated with Kalungaite | PdAsSe |
1 photo of Guanajuatite associated with Gold | Au |
Related Minerals - Strunz-mindat Grouping
2.DB. | Stangersite | SnGeS3 |
2.DB.05 | Antimonselite | Sb2Se3 |
2.DB.05 | Bismuthinite | Bi2S3 |
2.DB.05 | Metastibnite | Sb2S3 |
2.DB.05 | Pääkkönenite | Sb2AsS2 |
2.DB.05 | Stibnite | Sb2S3 |
2.DB.10 | Ottemannite | Sn2S3 |
2.DB.10 | Suredaite | PbSnS3 |
2.DB.15 | Bowieite | Rh2S3 |
2.DB.15 | Kashinite | Ir2S3 |
2.DB.20 | Montbrayite | (Au,Ag,Sb,Bi,Pb)23(Te,Sb,Bi,Pb)38 |
2.DB.25 | Edgarite | FeNb3S6 |
2.DB.30 | Tarkianite | (Cu,Fe)(Re,Mo)4S8 |
2.DB.35 | Cameronite | Cu5-x(Cu,Ag)3+xTe10 (x = 0.43) |
2.DB.40 | Schreibersite (of Shephard) | Cr2S3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Guanajuatite
mindat.org URL:
https://www.mindat.org/min-1761.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Guanajuatite
Reference List:
Earley, J. W. (1950) Description and synthesis of the selenide minerals. American Mineralogist, 35 (5-6) 337-364
Localities for Guanajuatite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Gilligan et al. (1995) |
Gilligan et al. (1995) | |
Gilligan et al. (1995) | |
Gilligan et al. (1995) | |
Gilligan et al. (1995) | |
Gilligan et al. (1995) | |
| Econ Geol (1997) |
| Sorrell (n.d.) |
Austria | |
| Kolitsch (2015) |
Brazil | |
| Botelho et al. (2006) |
Bulgaria | |
| Lips (2006) |
Canada | |
| Tyson (1989) |
B. J. Kieller (1965) | |
| Charles Normand (2016) |
Chile | |
| Gröpper et al. (1991) |
France | |
| F. Boyer and P.Picot : "Sur la Présence de Maldonite (Au2Bi) |
Germany | |
| Walenta (1992) +1 other reference |
| Weiß (1990) |
| Seeliger et al. (1965) +1 other reference |
| Weiß (1990) +1 other reference |
| Koch (2008) +1 other reference |
| Wittern (2001) |
Mexico | |
| Panczner (1987) |
| Panczner (1987) |
| Earley (1950) +1 other reference |
| Parker (2010) |
Romania | |
| minerals-of-the-carpathians.eu (2008) |
Russia | |
| Sidorov +5 other references |
Tolstykh et al. (2017) +1 other reference | |
| Pekov (1998) |
Goryachev et al. (2014) | |
| Rodionov et al. (2007) |
| American Mineralogist |
| maurice.strahlen.org (2004) |
| Vikent'eva et al. (2016, April) |
Sweden | |
| Scherbina (1941) |
| |
Switzerland | |
| Stalder et al. (1998) |
USA | |
| Stolburg (1984) |
| Hall (1958) +2 other references |
Mineralogical Society of America - ... | |
| Ream (1995) |
| Castor et al. (2004) |
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Santa Catarina Mine, Rancho Calvillo, Santa Rosa, Sierra de Santa Rosa, Guanajuato Municipality, Guanajuato, Mexico