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Kukisvumite

A valid IMA mineral species
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About KukisvumiteHide

Formula:
Na6ZnTi4(Si8O24)O4 · 4H2O
Colour:
White to colorless, some grains with a silver tint
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
2.90
Crystal System:
Orthorhombic
Name:
Named for Mount Kukisvumchorr, Russia, the type locality.
The Zn analogue of manganokukisvumite and (the Zn0.5-analogue of) lintisite. AM-4 family of natural titanosilicates.

Compare the other two group members: eliseevite and punkaruaivite.


Unique IdentifiersHide

Mindat ID:
2283
Long-form identifier:
mindat:1:1:2283:1
GUID
(UUID V4):
d45f76b3-b4e5-4ccb-83a6-40c93da0f9f5

IMA Classification of KukisvumiteHide

Classification of KukisvumiteHide

9.DB.20

9 : SILICATES (Germanates)
D : Inosilicates
B : Inosilicates with 2-periodic single chains, Si2O6; Pyroxene-related minerals
65.1.6.2

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
1 : Single-Width Unbranched Chains, W=1 with chains P=2

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KkiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KukisvumiteHide

Vitreous
Transparency:
Transparent
Colour:
White to colorless, some grains with a silver tint
Streak:
White
Hardness:
5½ - 6 on Mohs scale
Hardness:
VHN20=517 - 571 kg/mm2 - Vickers
Tenacity:
Elastic
Cleavage:
None Observed
Parting:
{010}
Fracture:
Irregular/Uneven, Splintery
Comment:
Crushes into thin fibers along the elongation
Density:
2.90 g/cm3 (Measured)    2.95 g/cm3 (Calculated)

Optical Data of KukisvumiteHide

Type:
Biaxial (-)
RI values:
nα = 1.676(3) nβ = 1.746(3) nγ = 1.795(3)
2V:
Measured: 77° , Calculated: 76°
Max Birefringence:
δ = 0.119
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
weak
Pleochroism:
Non-pleochroic

Chemistry of KukisvumiteHide

Mindat Formula:
Na6ZnTi4(Si8O24)O4 · 4H2O
Common Impurities:
Nb,Fe,F

Crystallography of KukisvumiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pccn
Setting:
Pccn
Cell Parameters:
a = 28.889(4) Å, b = 8.604(4) Å, c = 5.215(3) Å
Ratio:
a:b:c = 3.358 : 1 : 0.606
Unit Cell V:
1,296.25 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Elongate [001], flattened [100], up to 7 mm long and 0.1 mm thick (type material)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0011086KukisvumiteMerlino S, Pasero M, Ferro O (2000) The crystal structure of kukisvumite, Na6ZnTi4(Si2O6)4O4*4H2O Zeitschrift fur Kristallographie 215 352-3562000Kukisvumtschorr deposit, Khibiny alkaline massif, Kola peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
14.49 Å(90)
6.42 Å(60)
4.815 Å(80)
3.722 Å(65)
3.009 Å(100)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of KukisvumiteHide

General Appearance of Type Material:
Fan-shaped intergrowths of long prismatic crystals.
Place of Conservation of Type Material:
Fersman Mineralogical Museum, Moscow, Russia.
Mining Museum, St. Petersburg, Russia.
Geological Setting of Type Material:
Arfvedsonite-microcline pegmatite vein that cuts ijolitic/urtitic rocks.
Associated Minerals at Type Locality:
Reference:
Yakovenchuk, V.N., Pakhomovskii, Y.A., Bogdanova, A.N. (1991) Kukisvumite - A new mineral from the alkaline pegmatites of the Khibiny massif (Kola Peninsula). Mineralogicheskii Zhurnal: 13(2): 63-67.

Synonyms of KukisvumiteHide

Other Language Names for KukisvumiteHide

German:Kukisvumit
Simplified Chinese:羟硅锌钛钠石
Spanish:Kukisvumita
Traditional Chinese:羥矽鋅鈦鈉石

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Kukisvumite associated with ManganokukisvumiteNa6MnTi4(Si8O24)O4 · 4H2O
2 photos of Kukisvumite associated with Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2
2 photos of Kukisvumite associated with Labuntsovite Supergroup
1 photo of Kukisvumite associated with Nenadkevichite(Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2O
1 photo of Kukisvumite associated with AegirineNaFe3+Si2O6

Related Minerals - Strunz-mindat GroupingHide

9.DB.05BalipholiteBaLiMg2Al3(Si2O6)2(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05CarpholiteMn2+Al2(Si2O6)(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05FerrocarpholiteFe2+Al2Si2O6(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05MagnesiocarpholiteMgAl2Si2O6(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05PotassiccarpholiteK(Mn2+,Li)2Al4Si4O12(OH,F)8Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05VanadiocarpholiteMn2+V3+Al(Si2O6)(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.10LorenzeniteNa2Ti2(Si2O6)O3Orth. mmm (2/m 2/m 2/m) : Pbcn
9.DB.15LintisiteLiNa3Ti2(Si2O6)2O2 · 2H2OMon. 2/m : B2/b
9.DB.15PunkaruaiviteLiTi2(HSi4O12)(OH)2 · H2OMon. 2/m : B2/b
9.DB.17EliseeviteLiNa1.5Ti2(H1.5Si4O12)O2 · 2H2OMon. 2/m : B2/b
9.DB.20ManganokukisvumiteNa6MnTi4(Si8O24)O4 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pccn
9.DB.25VinogradoviteNa4Ti4(Si2O6)2[(Si,Al)4O10]O4 · (H2O,Na,K)3Mon. 2/m : B2/b
9.DB.25ParavinogradoviteNa1-2(Ti,Fe3+)4(Si2O6)2(AlSi3O10)(OH)4 · H2OTric. 1 : P1
9.DB.30NchwaningiteMn2+2(SiO3)(OH)2 · H2OOrth. mm2 : Pca21
9.DB.35PlancheiteCu8(Si8O22)(OH)4 · H2OOrth. mmm (2/m 2/m 2/m)
9.DB.40ShattuckiteCu5(Si2O6)2(OH)2Orth. mmm (2/m 2/m 2/m)
9.DB.40UM2005-31-SiO:CuHCu11(SiO4)(OH)18 · 9H2O (?)
9.DB.45Aerinite(Ca5.1Na0.5)(Fe3+,Al,Fe2+,Mg)4(Al,Mg)6[HSi12O36(OH)12][(CO3)1.2(H2O)12]Trig. 3m : P3c1
9.DB.50CapranicaiteKCaNaAl4B4Si2O18Mon. 2/m : P21/m

Other InformationHide

Notes:
Yellow-green luminescence in the electron microprobe beam
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KukisvumiteHide

References for KukisvumiteHide

Localities for KukisvumiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Murmansk Oblast
    • Khibiny Massif
Min.Zhurnal (1991)
Pekov (1998)
Yakovenchuk et al. (2005)
...
 
Mineral and/or Locality  
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