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Merlinoite

A valid IMA mineral species
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About MerlinoiteHide

Formula:
(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O
Colour:
Colorless, white
Hardness:
Specific Gravity:
2.14 - 2.27
Crystal System:
Orthorhombic
Member of:
Name:
Named in 1977 by Elio Passaglia, D. Pongiluppi, R. Rinaldi in honor of Stefano Merlino (1938 - ), Professor of crystallography, University of Pisa, Italy.

Unique IdentifiersHide

Mindat ID:
2651
Long-form identifier:
mindat:1:1:2651:8
GUID
(UUID V4):
3da70ecc-f226-4c9d-ad07-0b15069d5c4d

IMA Classification of MerlinoiteHide

Classification of MerlinoiteHide

9.GC.15

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
C : Chains of doubly-connected 4-membered rings
77.1.3.11

77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
16.12.14

16 : Silicates Containing Aluminum and other Metals
12 : Aluminosilicates of Sr, Ba and Zn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
MrlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MerlinoiteHide

Transparency:
Transparent
Colour:
Colorless, white
Streak:
White
Hardness:
4½ on Mohs scale
Density:
2.14 - 2.27 g/cm3 (Measured)    2.21(2) g/cm3 (Calculated)

Optical Data of MerlinoiteHide

Type:
Biaxial (-)
RI values:
nα = 1.499 nβ = 1.500 nγ = 1.501
2V:
Measured: 56° , Calculated: 88°
Max Birefringence:
δ = 0.002
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r > v
Optical Extinction:
X = b; Y = c; Z = a.

Chemistry of MerlinoiteHide

Mindat Formula:
(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O
Common Impurities:
Fe

Crystallography of MerlinoiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Immm
Setting:
Immm
Cell Parameters:
a = 14.116(7) Å, b = 14.229(6) Å, c = 9.946(6) Å
Ratio:
a:b:c = 0.992 : 1 : 0.699
Unit Cell V:
1,997.72 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Rectangular prisms formed by the {100} and {010} pinacoids, terminated by two orthorhombic prisms with different development. Radiating fibrous spheroidal aggregates.
Comment:
Pseudo-tetragonal.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014759MerlinoiteGalli E, Gottardi G, Pongiluppi D (1979) The crystal structure of the zeolite merlinoite Neues Jahrbuch fur Mineralogie, Monatshefte 1979 1-91979in a vug of a lava from Cupaello, Rieti, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.176 Å(100)
7.115 Å(90)
7.080 Å(88)
3.258 Å(44)
3.241 Å(41)
5.359 Å(40)
3.226 Å(38)
Comments:
Cupaello Quarry, Lazio, Italy. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
10 : Basalt-hosted zeolite minerals
Stage 3b: Earth’s earliest hydrosphere>4.45
16 : Low-𝑇 aqueous alteration of Hadean subaerial lithologies (see also #23)
Stage 5: Initiation of plate tectonics<3.5-2.5
42 : Sea-floor Mn nodules

Type Occurrence of MerlinoiteHide

General Appearance of Type Material:
Spheroidal radial aggregates with a diameter less than 1 mm.
Place of Conservation of Type Material:
Municipal Museum of Natural History, Milan, 18078; University of Modena, Modena, Italy; Natural History Museum, Paris, France; National Museum of Natural History, Washington, D.C., USA, 137087.
Geological Setting of Type Material:
In cavities in kalsilite-melilite rock.
Associated Minerals at Type Locality:
Reference:
Passaglia, E., Pongiluppi, D., Rinaldi, R. (1977) Merlinoite, a new mineral of the zeolite group. Neues Jahrbuch für Mineralogie, Monatshefte: 355-364.

Synonyms of MerlinoiteHide

Ba Zeolite (in part)

Other Language Names for MerlinoiteHide

Relationship of Merlinoite to other SpeciesHide

Member of:
Other Members of this group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet. 4/m : I41/a
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
Brewsterite SubgroupZeolite Group.
Chabazite-Levyne SubgroupM[Al2Si4O12] · 6H2O
ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
Clinoptilolite SubgroupM3-6(Si30Al6)O72 · 20H2O
CowlesiteCaAl2Si3O10 · 6H2OOrth. mmm (2/m 2/m 2/m)
Dachiardite SubgroupZeolite Group.
DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 2 2 2 : P21 21 21
EpistilbiteCaAl2Si6O16 · 5H2OMon.
Erionite SubgroupM2[Al4Si14O36] · 15H2O
Faujasite SubgroupM3.5[Al7Si17O48] · 32H2O
Ferrierite SubgroupZeolite Group.
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite Subgroup
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine SubgroupZeolite Group.
Gmelinite SubgroupIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm (2/m 2/m 2/m) : Pnma
GoosecreekiteCa[Al2Si6O16] · 5H2OMon. 2 : P21
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm (2/m 2/m 2/m) : Cmca
Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 4 3 2 : I41 3 2
KirchhoffiteCs(BSi2O6)Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
Loomisite Ba[Be2P2O8] · H2OMon. m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
Mazzite SubgroupZeolite Group.
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth. mm2 : Fdd2
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth. mmm (2/m 2/m 2/m) : Pnma
NabesiteNa2BeSi4O10 · 4H2OOrth. 2 2 2 : P21 21 21
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6 m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 2 3 : I2 3
ParthéiteCa2(Si4Al4) O15 (OH)2 · 4H2OMon. 2/m : B2/b
Paulingite SubgroupPaulingite was originally described in 1960.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
Phillipsite SubgroupZeolite Group.
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m (4/m 3 2/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mcm
Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite SubgroupThe large majority of "thomsonite" is thomsonite-Ca.
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m (4/m 3 2/m) : Fm3m
UM1996-38-SiO:AlCaHNaNa-Ca-Al-Si-O-H
UM1999-33-SiO:AlHKNaK7Na5Al12Si20O64 · 24H2O
UM2002-40-SiO:AlCaHKMgNa(Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2OTet. 4 2 2 : P41 2 2
Unnamed (Ca analogue of Merlinoite)(Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m : B2/m
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6 m2 : P62m
WillhendersoniteKCa[Al3Si3O12] · 5H2OTric. 1 : P1
YugawaraliteCaAl2Si6O16 · 4H2OMon. m : Pb

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Merlinoite associated with Montesommaite(K,Na)9Al9Si23O64 · 10H2O
3 photos of Merlinoite associated with BaryteBaSO4
2 photos of Merlinoite associated with Phillipsite Subgroup
2 photos of Merlinoite associated with Erionite SubgroupM2[Al4Si14O36] · 15H2O
2 photos of Merlinoite associated with CalciteCaCO3
1 photo of Merlinoite associated with AmiciteK2Na2Al4Si4O16 · 5H2O

Related Minerals - Strunz-mindat GroupingHide

9.GC.Garronite-NaNa6(Al6Si10O32) · 8.5H2OMon. 2
9.GC.Gismondine-SrSr4(Si8Al8O32) · 9H2OOrth. 2 2 2 : C2 2 21
9.GC.05AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
9.GC.05Garronite-CaNa2Ca5Al12Si20O64 · 27H2OTet. 4 2m : I4m2
9.GC.05Gismondine-CaCaAl2Si2O8 · 4H2OMon. 2/m : P21/b
9.GC.05GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm (2/m 2/m 2/m) : Pnma
9.GC.05Gismondine-BaBa2Al4Si4O16 · 4-6H2O
9.GC.10HarmotomeBa2(Si12Al4)O32 · 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-CaCa3(Si10Al6)O32 · 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-K(K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2OMon. 2/m : P21/m
9.GC.10Phillipsite-Na(Na,K,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] · 12H2OMon. 2/m : P21/m
9.GC.10Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
9.GC.10MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
9.GC.20Mazzite-Mg(Mg,K,Ca)5(Si26Al10)O72 · 28H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GC.20Mazzite-NaNa8[Al4Si14O36]2 · 30H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GC.25PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
9.GC.30BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
9.GC.35Paulingite-Ca(Ca,K,Na,Ba, ◻)10 (Si, Al)42O84 · 34H2OIso. m3m (4/m 3 2/m)
9.GC.35Paulingite-K(K2,Ca,Na2,Ba)5[Al10Si35O90] · 45H2OIso. m3m (4/m 3 2/m)
9.GC.35Paulingite-Na(Na2,K2,Ca,Ba)5[Al10Si35O90] · 45H2OIso.

Other InformationHide

IR Spectrum:
The IR spectrum distinguishes between merlinoite and phillipsite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MerlinoiteHide

References for MerlinoiteHide

Reference List:

Localities for MerlinoiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France
 
  • Auvergne-Rhône-Alpes
    • Haute-Loire
      • Le Puy-en-Velay
        • Saint-Pierre-Eynac
Galli et al. (2008)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Tuttlingen
        • Immendingen
Tschernich (1992)
  • Bavaria
    • Lower Franconia
      • Haßberge District
        • Maroldsweisach
Wittern (2001)
  • Hesse
    • Darmstadt
      • Wetteraukreis
        • Nidda
          • Unter-Widdersheim
Betz (2019)
        • Ortenberg
Iceland
 
  • Northeastern Region
    • Tjörneshreppur
      • Tjörnes
SCHNORRER-KÖHLER (1990)
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
        • Mount Somma
          • Ercolano
            • San Vito
Elmar Lackner collection +1 other reference
          • Pollena Trocchia
Collection of Alex Earl
          • Sant'Anastasia
Russo et al. (2004) +1 other reference
          • Somma Vesuviana
Badham (1997) +1 other reference
        • Mount Vesuvius
          • Terzigno
Chinellato Matteo
  • Lazio
    • Metropolitan City of Rome Capital
      • Magliano Romano
Giancarlo Della Ventura et al. (1993)
      • Sacrofano
    • Rieti Province
      • Rieti
        • Santa Rufina
Sabatini (1903) +6 other references
Russia
 
  • Murmansk Oblast
    • Khibiny Massif
PEKOV et al. (2013)
Pekov et al. (2004)
Spain
 
  • Canary Islands
    • Las Palmas Province
      • Lanzarote
        • Haría
Strasser et al. (2006)
USA
 
  • California
    • San Bernardino County
Donahoe et al. (1984) +1 other reference
 
Mineral and/or Locality  
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