Penkvilksite

Penkvilksite, etc.

Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada

Penkvilksite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Penkvilksite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Penkvilksite, etc.

Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada

Penkvilksite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Penkvilksite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Penkvilksite, etc.

Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada

Penkvilksite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

About PenkvilksiteHide

Unique IdentifiersHide

IMA Classification of PenkvilksiteHide

Classification of PenkvilksiteHide

Mineral SymbolsHide

Physical Properties of PenkvilksiteHide

Optical Data of PenkvilksiteHide

Type:

Biaxial (+)

RI values:

n_α = 1.640 n_β = 1.646 n_γ = 1.675

2V:

Measured: 50° , Calculated: 50°

Max Birefringence:

δ = 0.035

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Moderate

Dispersion:

relatively weak

Chemistry of PenkvilksiteHide

Crystallography of PenkvilksiteHide

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4

Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks

Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan

View
CIF File    Best | x | y | z | a | b | c

Rotation
Stop | Start

Labels
Console Off | On | Grey | Yellow

Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0001688	Penkvilksite	Merlino S, Pasero M, Artioli G, Khomyakov A P (1994) Penkvilksite, a new kind of silicate structure: OD character, X-ray single-crystal (1M), and powder Rietveld (2O) refinements of two MDO polytypes American Mineralogist 79 1185-1193		1994		0	293
0001689	Penkvilksite	Merlino S, Pasero M, Artioli G, Khomyakov A P (1994) Penkvilksite, a new kind of silicate structure: OD character, X-ray single-crystal (1M), and powder Rietveld (2O) refinements of two MDO polytypes Data has been corrected according to the ICSD American Mineralogist 79 1185-1193		1994		0	293
0010347	Penkvilksite	Cadoni M, Ferraris G (2008) Penkvilksite-2O: Na2TiSi4O11*2H2O Acta Crystallographica C64 i87-i90		2008	synthetic	0	293

CIF Raw Data - click here to closedata_global _chemical_name_mineral 'Penkvilksite' loop_ _publ_author_name 'Merlino S' 'Pasero M' 'Artioli G' 'Khomyakov A P' _journal_name_full 'American Mineralogist' _journal_volume 79 _journal_year 1994 _journal_page_first 1185 _journal_page_last 1193 _publ_section_title ; Penkvilksite, a new kind of silicate structure: OD character, X-ray single-crystal (1M), and powder Rietveld (2O) refinements of two MDO polytypes Note: polytype 2O ; _database_code_amcsd 0001688 _chemical_formula_sum '(Ti.9 Zr.1) Si4 Na2 O13 H4' _cell_length_a 16.3721 _cell_length_b 8.7492 _cell_length_c 7.4020 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 1060.283 _exptl_crystal_density_diffrn 2.647 _symmetry_space_group_name_H-M 'P n c a' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,y,-z' '1/2-x,-y,z' 'x,1/2-y,1/2+z' '-x,1/2+y,1/2-z' '1/2-x,1/2+y,1/2+z' '1/2+x,1/2-y,1/2-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv Ti 0.00000 0.50000 0.00000 0.90000 0.03100 Zr 0.00000 0.50000 0.00000 0.10000 0.03100 Si1 0.08250 0.16130 0.12470 1.00000 0.03120 Si2 0.15670 0.43990 0.26030 1.00000 0.01610 Na 0.10230 0.69110 0.62200 1.00000 0.06300 O1 0.15990 0.26120 0.20060 1.00000 0.02500 O2 0.05010 0.03720 0.26950 1.00000 0.02800 O3 0.00740 0.27040 0.06330 1.00000 0.02500 O4 0.11620 0.05070 -0.03890 1.00000 0.03300 O5 0.11150 0.53940 0.10520 1.00000 0.02100 O6 0.25000 0.50000 0.27050 1.00000 0.01600 OW 0.19540 0.68440 -0.15480 1.00000 0.04900 H1 0.17300 0.58600 -0.10800 1.00000 0.10000 H2 0.24200 0.65000 -0.23200 1.00000 0.14000

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of PenkvilksiteHide

Synonyms of PenkvilksiteHide

Other Language Names for PenkvilksiteHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

Other InformationHide

Internet Links for PenkvilksiteHide

References for PenkvilksiteHide

Reference List:

Year ⬇Author Title Publisher

Bussen, I.V., Men'shikov, Yu.P., Merkov, A.M., Nedorezova, A.P., Uspenskaya, E.I., Khomyakov, A.P. (1974) Penkvilksite, a new hydrous silicate of titanium and sodium.Doklady Akademii Nauk SSSR: 217: 1161-1164 (in Russian). English translation: Doklady Akademii Nauk SSSR. Earth Sciences Section: 217: 126-129.

Bussen, I.V., Men'shikov, Yu.P., Merkov, A.M., Nedorezova, A.P., Uspenskaya, E.I., Khomyakov, A.P. (1974) Penkvilksite, a new hydrous silicate of titanium and sodium.Doklady Akademii Nauk SSSR: 217: 1161-1164.

Fleischer, Michael (1975) New mineral names. American Mineralogist, 60 (3-4) 340-341

Merlino, Stefano, Pasero, Marco, Artioli, Gilberto, Khomyakov, Alexander P. (1994) Penkvilksite, a new kind of silicate structure: OD character, X-ray single-crystal (1M), and powder Rietveld (2O) refinements of two MDO polytypes. American Mineralogist, 79 (11-12). 1185-1193

Subbotin, V.V., et al. (2000) Tumchaite - a new mineral from carbonatites of the Vuoriyarvi alkali-ultrabasic massif, Murmansk Region, Russia. American Mineralogist: 85: 1516-1520.

Sherriff, B.L., Zhou, B. (2004) 29Si and 23Na MAS NMR spectroscopic study of the polytypes of the titanosilicate penkvilksite. The Canadian Mineralogist: 42: 1027-1035.

Cadoni, M., Ferraris, G. (2008) Penkvilskite-2O: Na2TiSi4O11·2H2O. Acta Crystallographica: C64: i87-i90.

Frost, R.L., Xi, Y. (2013) Vibrational spectroscopic study of the mineral penkvilksite Na2TiSi4O11·2H2O – a mineral used for the uptake of radionuclides. Radiation Effects and Defects in Solids, 168(1), 72-79.

Localities for PenkvilksiteHide

This section is currently hidden. Click the show button to view.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

This section is currently hidden. Click the show button to view.

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Canada
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire ⓘ Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH)	Horváth, László, Gault, Robert A. (1990) The Mineralogy of Mont Saint-Hilaire, Quebec. The Mineralogical Record, 21 (4) 281-359 Horváth, L., Gault, R.A., Pfenninger-Horváth, E., Poirier, G. (2019) Mont Saint-Hilaire: History, Geology, Mineralogy - Special Publication No. 14. The Canadian Mineralogist, Ottawa.pp.343-344
Russia
Murmansk Oblast Khibiny Massif ⓘ Restin'yun Mt	YAKOVENCHUK, V.N., IVANYUK, G.YU., PAKHOMOVSKY, YA.A. & MEN’SHIKOV, YU.P. (2005): Khibiny. Published by Laplandia Minerals, Apatity. [penkvilksite-1M] p. 293.
ⓘ Kovdor Massif	Mikhailova, J. A., Kalashnikov, A. O., Sokharev, V. A., Pakhomovsky, Y. A., Konopleva, N. G., Yakovenchuk, V. N., ... & Ivanyuk, G. Y. (2016). 3D mineralogical mapping of the Kovdor phoscorite–carbonatite complex (Russia). Mineralium Deposita, 51(1), 131-149.
Lovozersky District Karnasurt Mountain ⓘ Yubileinaya pegmatite (TL)	Bussen, I.V., Men'shikov, Yu.P., Merkov, A.M., Nedorezova, A.P., Uspenskaya, E.I., Khomyakov, A.P. (1974) Penkvilksite, a new hydrous silicate of titanium and sodium.Doklady Akademii Nauk SSSR: 217: 1161-1164 (in Russian). English translation: Doklady Akademii Nauk SSSR. Earth Sciences Section: 217: 126-129. Pluth, J. J., Smith, J. V., Pushcharovsky, D. Y., Semenov, E. I., Bram, A., Riekel, C., ... & Broach, R. W. (1997). Third-generation synchrotron x-ray diffraction of 6-μm crystal of raite,≈ Na3Mn3Ti0. 25Si8O20 (OH) 2⋅ 10H2O, opens up new chemistry and physics of low-temperature minerals. Proceedings of the National Academy of Sciences, 94(23), 12263-12267. Pekov, Igor V. (1998) Minerals first discovered on the territory of the former Soviet Union. Ocean Pictures, Moscow. 369pp. Pekov, I.V. (2000): Lovozero Massif. Moscow, Ocean Pictures Ltd, 480 pp. Zubkova, N. V., Pekov, I. V., Pushcharovsky, D. Y., & Chukanov, N. V. (2009). The crystal structure and refined formula of mountainite, KNa2Ca2 [Si8O19 (OH)]⊙ 6 H2O. Zeitschrift für Kristallographie, 224(8), 389-396.