Tschermigite
A valid IMA mineral species - grandfathered
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About Tschermigite
Formula:
(NH4)Al(SO4)2 · 12H2O
Colour:
Colourless, white; colourless in transmitted light
Lustre:
Vitreous, Silky
Hardness:
1½ - 2
Specific Gravity:
1.645
Crystal System:
Isometric
Member of:
Name:
Named after its discovery locality, Tschermig (now Cermniky), near Kadan, Czech Republic.
Note: Specimens frequently offered for sale of 'tschermigite' as large, good quality purple crystals on matrix are artificially created specimens made by growing crystals of this ammonium alum in a laboratory.
Godovikovite is a dehydration product of tschermigite sometimes occuring on burning coal dumps.
Godovikovite is a dehydration product of tschermigite sometimes occuring on burning coal dumps.
Unique Identifiers
Mindat ID:
4036
Long-form identifier:
mindat:1:1:4036:1
GUID
(UUID V4):
(UUID V4):
9d64c18f-6a7d-4f1e-a831-9d3406238942
Classification of Tschermigite
Approved, 'Grandfathered' (first described prior to 1959)
7.CC.20
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.5.5.3
29 : HYDRATED ACID AND NORMAL SULFATES
5 : AB(XO4)2·xH2O
29 : HYDRATED ACID AND NORMAL SULFATES
5 : AB(XO4)2·xH2O
25.6.20
25 : Sulphates
6 : Sulphates of Al and Tl
25 : Sulphates
6 : Sulphates of Al and Tl
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Tmi | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Tschermigite
Vitreous, Silky
Transparency:
Transparent
Comment:
Crystals vitreous; fibrous masses silky
Colour:
Colourless, white; colourless in transmitted light
Hardness:
1½ - 2 on Mohs scale
Fracture:
Conchoidal
Density:
1.645 g/cm3 (Measured) 1.641 g/cm3 (Calculated)
Optical Data of Tschermigite
Type:
Isotropic
RI values:
n = 1.458
Birefringence:
Anomalous - due to strain arising in mechanical deformation or compositional variation.
Surface Relief:
Moderate
Chemical Properties of Tschermigite
Formula:
(NH4)Al(SO4)2 · 12H2O
Crystallography of Tschermigite
Crystal System:
Isometric
Class (H-M):
m3 (2/m 3) - Diploidal
Space Group:
Pa3
Setting:
Pa3
Cell Parameters:
a = 12.242``(1) Å
Unit Cell V:
1,834.67 Ă
Âł (Calculated from Unit Cell)
Z:
4
Morphology:
Octahedral (artificial crystals from pure water solutions); fibrous, columnar massive; as efflorescences.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0019048 | Tschermigite | Larson A C, Cromer D T (1967) Refinement of the alum structures. III. X-ray study of the a alums, K, Rb and NH4Al(SO4)2*12H2O Acta Crystallographica 22 793-800 | 1967 | Synthetic | 0 | 293 | |
0010843 | Tschermigite | Abdeen A M, Will G, Schaefer W, Kirfel A, Bargouth M O, Recker K, Weiss A (1981) X-ray and neutron diffraction study of alums II. The crystal structure of methylammonium aluminium alum III. The crystal structure of ammonium aluminium alum Zeitschrift fur Kristallographie 157 147-166 | 1981 | synthetic | 0 | 293 | |
0010844 | Tschermigite | Abdeen A M, Will G, Schafer W, Kirfel A, Bargouth M O, Recker K, Weiss A (1981) X-ray and neutron diffraction study of alums: II. The crystal structure of methylammonium aluminium alum III. The crystal structure of ammonium aluminium alum Zeitschrift fur Kristallographie 157 147-166 | 1981 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
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Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
4.327 Ă | (100) |
4.079 Ă | (80) |
3.273 Ă | (75) |
7.07 Ă | (55) |
5.48 Ă | (55) |
4.998 Ă | (35) |
3.691 Ă | (35) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
45a : [Sulfates, arsenates, selenates, antimonates] | |
45b : [Other oxidized fumarolic minerals] | |
47a : [Near-surface hydration of prior minerals] | |
47b : [Sulfates and sulfites] | |
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
50 : Coal and/or oil shale minerals | <0.36 |
53 : Other minerals with taphonomic origins | <0.4 |
Stage 10b: Anthropogenic minerals | <10 Ka |
54 : Coal and other mine fire minerals (see also #51 and #56) | |
55 : Anthropogenic mine minerals |
Geological Setting:
In lignite (brown-coal) beds and bituminous shales; in fumaroles; in burning coal seams and coal mine waste heaps.
Type Occurrence of Tschermigite
Reference:
von Kobel F (1858) Es sind in SalzsĂ€ure, einige auch in Wasser, ohne merklichen RĂŒckstand auflöslich. Die Aufl. bildet keine Gallerte. in Tafeln zur Bestimmung der Mineralien mittelst einfacher chemischer Versuche auf trockenem und nassem Wege., Joseph Lindauer'sche Buchhandlung (MĂŒnchen) 47-47
Synonyms of Tschermigite
Other Language Names for Tschermigite
Relationship of Tschermigite to other Species
Member of:
Other Members of this group:
Alum-(K) | KAl(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
Alum-(Na) | NaAl(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
Lanmuchangite | Tl+Al(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
Common Associates
Associated Minerals Based on Photo Data:
4 photos of Tschermigite associated with Mohrite | (NH4)2Fe(SO4)2 · 6H2O |
3 photos of Tschermigite associated with Ammoniomagnesiovoltaite | (NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2O |
3 photos of Tschermigite associated with Godovikovite | (NH4)Al(SO4)2 |
2 photos of Tschermigite associated with Alunogen | Al2(SO4)3 · 17H2O |
2 photos of Tschermigite associated with Hexahydrite | MgSO4 · 6H2O |
2 photos of Tschermigite associated with Metavoltine | K2Na6Fe2+Fe3+6O2(SO4)12 · 18H2O |
2 photos of Tschermigite associated with Sabieite | (NH4)Fe3+(SO4)2 |
2 photos of Tschermigite associated with Boussingaultite | (NH4)2Mg(SO4)2 · 6H2O |
1 photo of Tschermigite associated with Efremovite | (NH4)2Mg2(SO4)3 |
1 photo of Tschermigite associated with Berndtite | SnS2 |
Related Minerals - Strunz-mindat Grouping
7.CC. | Cobaltoblödite | Na2Co(SO4)2 · 4H2O | Mon. 2/m : P21/b |
7.CC. | Andychristyite | PbCu2+Te6+O5(H2O) | Tric. 1 : P1 |
7.CC. | Ammoniovoltaite | (NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18 | Iso. m3m (4/m 3 2/m) : Fd3c |
7.CC.05 | Krausite | KFe(SO4)2 · H2O | Mon. 2/m : P21/m |
7.CC.10 | Tamarugite | NaAl(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.15 | Kalinite | KAl(SO4)2 · 11H2O | Mon. 2/m : B2/b |
7.CC.15 | Mendozite | NaAl(SO4)2 · 11H2O | Mon. 2/m : B2/b |
7.CC.20 | Lonecreekite | (NH4)Fe3+(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
7.CC.20 | Alum-(K) | KAl(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
7.CC.20 | Alum-(Na) | NaAl(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
7.CC.20 | Lanmuchangite | Tl+Al(SO4)2 · 12H2O | Iso. m3 (2/m 3) : Pa3 |
7.CC.25 | Voltaite | K2Fe2+5Fe3+3Al(SO4)12 · 18H2O | Iso. m3m (4/m 3 2/m) : Fd3c |
7.CC.25 | Zincovoltaite | K2Zn5Fe3+3Al(SO4)12 · 18H2O | Iso. m3m (4/m 3 2/m) : Fd3c |
7.CC.25 | Pertlikite | K2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2O | Tet. 4/mmm (4/m 2/m 2/m) : I41/acd |
7.CC.25 | Ammoniomagnesiovoltaite | (NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2O | Iso. m3m (4/m 3 2/m) : Fd3c |
7.CC.25 | Magnesiovoltaite | K2Mg5Fe3+3Al(SO4)12 · 18H2O | Iso. m3m (4/m 3 2/m) : Fd3c |
7.CC.30 | Kröhnkite | Na2Cu(SO4)2 · 2H2O | Mon. 2/m : P21/b |
7.CC.35 | Ferrinatrite | Na3Fe(SO4)3 · 3H2O | Trig. 3 : P3 |
7.CC.40 | Goldichite | KFe(SO4)2 · 4H2O | Mon. 2/m : P21/b |
7.CC.45 | Löweite | Na12Mg7(SO4)13 · 15H2O | Trig. 3 : R3 |
7.CC.50 | Blödite | Na2Mg(SO4)2 · 4H2O | Mon. 2/m : P21/b |
7.CC.50 | Nickelblödite | Na2(Ni,Mg)(SO4)2 · 4H2O | Mon. 2/m : P21/b |
7.CC.50 | Changoite | Na2Zn(SO4)2 · 4H2O | Mon. 2/m : P21/b |
7.CC.55 | Leonite | K2Mg(SO4)2 · 4H2O | Mon. 2/m : B2/m |
7.CC.55 | Mereiterite | K2Fe(SO4)2 · 4H2O | Mon. 2/m : B2/m |
7.CC.60 | Boussingaultite | (NH4)2Mg(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.60 | Cyanochroite | K2Cu(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.60 | Mohrite | (NH4)2Fe(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.60 | Nickelboussingaultite | (NH4)2Ni(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.60 | Picromerite | K2Mg(SO4)2 · 6H2O | Mon. 2/m : P2/b |
7.CC.60 | Nickelpicromerite | K2Ni(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.60 | Katerinopoulosite | (NH4)2Zn(SO4)2 · 6H2O | Mon. 2/m : P21/b |
7.CC.65 | Polyhalite | K2Ca2Mg(SO4)4 · 2H2O | Tric. 1 |
7.CC.70 | Leightonite | K2Ca2Cu(SO4)4 · 2H2O | Mon. 2/m : B2/b |
7.CC.75 | Amarillite | NaFe(SO4)2 · 6H2O | Mon. 2/m : B2/b |
7.CC.80 | Konyaite | Na2Mg(SO4)2 · 5H2O | Mon. 2/m : P21/b |
7.CC.85 | Wattevilleite | Na2Ca(SO4)2 · 4H2O (?) | Orth. |
7.CC.85 | Xocolatlite | Ca2Mn4+2(Te6+O6)2 · H2O | Mon. 2/m : P2/m |
7.CC.90 | Eckhardite | (Ca,Pb)Cu2+Te6+O5(H2O) | Mon. 2/m |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tschermigite
mindat.org URL:
https://www.mindat.org/min-4036.html
Please feel free to link to this page.
Please feel free to link to this page.
External Links:
Mineral Dealers:
References for Tschermigite
Reference List:
Localities for Tschermigite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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PĂ©cs-Vasas, PĂ©cs District, Baranya County, Hungary