Turquoise
A valid IMA mineral species - grandfathered
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About Turquoise
Formula:
CuAl6(PO4)4(OH)8 · 4H2O
Colour:
bright blue, sky-blue, pale green, blue-green, turquoise-blue, apple-green, green-gray
Lustre:
Sub-Vitreous, Resinous, Waxy, Dull, Earthy
Hardness:
5 - 6
Specific Gravity:
2.6 - 2.8
Crystal System:
Triclinic
Member of:
Name:
Named from French "turques" or "turquois" meaning "Turkish" the original material found on the south slopes of the Al-Mirsah-Kuh Mountains (Iran), but which found its way to Europe via Turkey. The name was known at least as early as the 17th century C.E. Turquoise and members of its group were redefined by Foord and Taggert in 1998, with turquoise reserved for an end-member composition. Foord and Taggert (1998) also noted that most of the gem material labeled "turquoise" is inhomogeneous and that planerite is the most common constituent in commercial "turquoise".
Isostructural with:
Turquoise Group. Chalcosiderite-Turquoise Series. Planerite-Turquoise Series. The copper analogue of Faustite.
A secondary mineral occurring in the potassic alteration zone of hydrothermal porphyry copper deposits. Also formed by the action of meteoric waters, usually in arid regions, on aluminous igneous or sedimentary rocks (as vein filling in volcanic rocks and phosphatic sediments).
A secondary mineral occurring in the potassic alteration zone of hydrothermal porphyry copper deposits. Also formed by the action of meteoric waters, usually in arid regions, on aluminous igneous or sedimentary rocks (as vein filling in volcanic rocks and phosphatic sediments).
Visit gemdat.org for gemological information about Turquoise.
Unique Identifiers
Mindat ID:
4060
Long-form identifier:
mindat:1:1:4060:6
GUID
(UUID V4):
(UUID V4):
620499e2-37b8-44f1-b03e-ff0489cd0deb
IMA Classification of Turquoise
Approved, 'Grandfathered' (first described prior to 1959)
Classification of Turquoise
8.DD.15
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
D : With only medium-sized cations, (OH, etc.):RO4= 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
D : With only medium-sized cations, (OH, etc.):RO4= 2:1
Dana 7th ed.:
42.9.3.1
42.9.3.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
9 : (AB)7(XO4)4Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
9 : (AB)7(XO4)4Zq·xH2O
19.2.8
19 : Phosphates
2 : Phosphates of Cu
19 : Phosphates
2 : Phosphates of Cu
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Tqu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Turquoise
Pronunciation:
Play | Recorded by | Country |
---|---|---|
Jolyon Ralph | United Kingdom |
Physical Properties of Turquoise
Sub-Vitreous, Resinous, Waxy, Dull, Earthy
Transparency:
Transparent, Translucent, Opaque
Comment:
Dull to waxy in massive varieties, subvitreous in crystals.
Colour:
bright blue, sky-blue, pale green, blue-green, turquoise-blue, apple-green, green-gray
Comment:
Ferric iron substitution may cause the color to be green.
Streak:
Pale greenish blue to white
Hardness:
5 - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
on {001}, good on {010}
on {001}, good on {010}
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
2.6 - 2.8 g/cm3 (Measured) 2.91 g/cm3 (Calculated)
Optical Data of Turquoise
Type:
Biaxial (+)
RI values:
nα = 1.610 nβ = 1.615 nγ = 1.650
2V:
Measured: 40° , Calculated: 44°
Birefringence:
0.040
Max Birefringence:
δ = 0.040
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v strong
Pleochroism:
Weak
Comments:
X= colorless
Z= pale blue or pale green
Z= pale blue or pale green
Chemistry of Turquoise
Mindat Formula:
CuAl6(PO4)4(OH)8 · 4H2O
Common Impurities:
Fe,Ca
Chemical Analysis
Oxide wt%:
1 | |
---|---|
P2O5 | 23.41 % |
Al2O3 | 28.31 % |
Fe2O3 (total) | 9.60 % |
CuO | 6.37 % |
Total: | 67.69 % |
Sample references:
ID | Locality | Reference | Notes |
---|---|---|---|
1 | Mt. Vohidraty, Antaly, Ampanihy District, Atsimo-Andrefana, Madagascar | Analyzed by P. Ruf. Analyse only partial |
Crystallography of Turquoise
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.409(1) Å, b = 7.635(1) Å, c = 9.914(2) Å
α = 111.356°, β = 114.973°, γ = 69.532°
α = 111.356°, β = 114.973°, γ = 69.532°
Ratio:
a:b:c = 0.97 : 1 : 1.298
Unit Cell V:
449.39 ų
Z:
1
Morphology:
Crystals rare. Steep pinacoidal crystals exhibiting {010}, {110} and {001}. Fine granular, globular crusts, veinlets, massive.
Crystallographic forms of Turquoise
Crystal Atlas:
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0010612 | Turquoise | Cid-Dresdner H (1965) Determination and refinement of the crystal structure of turquois, CuAl6(PO4)4(OH)8*4H2O Zeitschrift fur Kristallographie 121 87-113 | 1965 | Virginia, USA | 0 | 293 | |
0014545 | Turquoise | Kolitsch U, Giester G (2000) The crystal structure of faustite and its copper analogue turquoise Mineralogical Magazine 64 905-913 | 2000 | Iron Monarch iron ore deposit, South Australia | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
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Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
9.09 Å | (50) |
6.17 Å | (70) |
4.80 Å | (60) |
3.68 Å | (100) |
3.44 Å | (70) |
3.28 Å | (70) |
2.91 Å | (80) |
2.02 Å | (60) |
Comments:
ICDD 6-214; A very weak d(010) peak near d = 9.0 is indicative of A-site vacant material, such as planerite.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47c : [Carbonates, phosphates, borates, nitrates] |
Geological Setting:
Secondary mineral in potassic alteration zone of porphyry copper deposits. Vein fillings in volcanic rocks and phosphate-rich sediments.
Synonyms of Turquoise
Other Language Names for Turquoise
Arabic:فيروز
Basque:Turkesa
Catalan:Turquesa
Czech:Tyrkys
Dutch:Turkoois
Esperanto:Turkiso
Estonian:Türkiis
Finnish:Turkoosi
Galician:Turquesa
Georgian:ფირუზი
Hebrew:טורקיז
Hindi:फीरोजा़
Hungarian:Türkiz
Lithuanian:Turkis
Navajo:Dootłʼizhii
Polish:Turkus
Portuguese:Turquesa
Quechua:Anqas umiña
Russian:Бирюза
Simplified Chinese:绿松石
Slovak:Tyrkys
Swedish:Turkos
Turkish:Turkuaz
Ukrainian:Бірюза
Vietnamese:Ngọc lam
Varieties of Turquoise
Agaphite | A vitreous variety of Iranian turquoise. |
Ferriturquoise | A variety of crystallized turquoise containing 5% Fe2O3 ; ascribed to "Lynch, Virginia" by Spencer in 1943, which was an apparently incorrect reference to Lynch Station, which is an unincorporated community in Campbell County. |
Rashleighite | Turquoise Group . A ferrian Turquoise variety, intermediate on the Chalcosiderite-Turquoise Series. Originally reported from Bunny Mine (Bonny Mine; St Austell Hills Mine; Shelton Mine), Bugle, Hensbarrow Downs, Luxulyan Area (Luxulian Area), St Austell... |
Relationship of Turquoise to other Species
Member of:
Other Members of this group:
Aheylite | (Fe2+,Zn)Al6(PO4)4(OH)8 · 4H2O | Tric. 1 : P1 |
Chalcosiderite | CuFe3+6(PO4)4(OH)8 · 4H2O | Tric. 1 : P1 |
Faustite | ZnAl6(PO4)4(OH)8 · 4H2O | Tric. 1 : P1 |
Planerite | Al6(PO4)2(PO3OH)2(OH)8 · 4H2O | Tric. 1 : P1 |
UM1981-32-PO:FeH | Fe2+Fe3+6(PO4)4-x[PO3(OH)]x(OH)8 · 4H2O |
Forms a series with:
Common Associates
Associated Minerals Based on Photo Data:
145 photos of Turquoise associated with Senegalite | Al2(PO4)(OH)(OH)2 · H2O |
139 photos of Turquoise associated with Quartz | SiO2 |
112 photos of Turquoise associated with Wavellite | Al3(PO4)2(OH,F)3 · 5H2O |
41 photos of Turquoise associated with Variscite | AlPO4 · 2H2O |
38 photos of Turquoise associated with Libethenite | Cu2(PO4)(OH) |
31 photos of Turquoise associated with Crandallite | CaAl3(PO4)(PO3OH)(OH)6 |
28 photos of Turquoise associated with Fluorapatite | Ca5(PO4)3F |
26 photos of Turquoise associated with Strengite | FePO4 · 2H2O |
18 photos of Turquoise associated with Pyrite | FeS2 |
17 photos of Turquoise associated with Jarosite | KFe3+3(SO4)2(OH)6 |
Related Minerals - Strunz-mindat Grouping
8.DD. | Bettertonite | [Al6(AsO4)3(OH)9(H2O)5] · 11H2O |
8.DD. | Penberthycroftite | [Al6(AsO4)3(OH)9(H2O)5] · 8H2O |
8.DD. | Vargite | Cu2Mn3(AsO4)2(OH)4(H2O)4 |
8.DD. | Galeaclolusite | Al6(AsO4)3(OH)9(H2O)4 · 8H2O |
8.DD.05 | Chenevixite | Cu2Fe3+2(AsO4)2(OH)4 |
8.DD.05 | Luetheite | Cu2Al2(AsO4)2(OH)4 |
8.DD.10 | Akrochordite | (Mn2+,Mg)5(AsO4)2(OH)4 · 4H2O |
8.DD.10 | Guanacoite | Cu2Mg3(AsO4)2(OH)4 · 4H2O |
8.DD.15 | Aheylite | (Fe2+,Zn)Al6(PO4)4(OH)8 · 4H2O |
8.DD.15 | Chalcosiderite | CuFe3+6(PO4)4(OH)8 · 4H2O |
8.DD.15 | Coeruleolactite | |
8.DD.15 | Faustite | ZnAl6(PO4)4(OH)8 · 4H2O |
8.DD.15 | Planerite | Al6(PO4)2(PO3OH)2(OH)8 · 4H2O |
8.DD.15 | Afmite | Al3(OH)4(H2O)3(PO4)(PO3OH) · H2O |
8.DD.15 | UM1981-32-PO:FeH | Fe2+Fe3+6(PO4)4-x[PO3(OH)]x(OH)8 · 4H2O |
8.DD.20 | Childrenite | Fe2+Al(PO4)(OH)2 · H2O |
8.DD.20 | Eosphorite | Mn2+Al(PO4)(OH)2 · H2O |
8.DD.20 | Ernstite | (Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2O |
8.DD.20 | Lefontite | Fe2Al2Be(PO4)2(OH)6 |
8.DD.25 | Kobokoboite | Al6(PO4)4(OH)6 · 11H2O |
8.DD.30 | Smamite | Ca2Sb(OH)4[H(AsO4)2] · 6H2O |
8.DD.35 | Gutsevichite | Al3(PO4)2(OH)3 · 8H2O |
8.DD.40 | Laubmannite (of Moore) | (Fe3+,Fe2+,M)8+x(OH,H2O)9(H2O)2(PO4)5, M = Fe3+, Cu2+ or other metal cation, x ~ 0.1. |
Fluorescence of Turquoise
Not fluorescent in UV
Other Information
Notes:
Soluble with difficulty in HCl.
Often found as pseudomorphs after orthoclase; also after apatite, bone, and teeth.
Often found as pseudomorphs after orthoclase; also after apatite, bone, and teeth.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Jewelry stone.
Internet Links for Turquoise
mindat.org URL:
https://www.mindat.org/min-4060.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Turquoise
Reference List:
Carnot, Adolphe (1894) Sur la composition chimique des wavellites et des turquoises. Comptes rendus de l’Académie des sciences de Paris, 118 (14-26) 995-998
Pearl, Richard Maxwell (1941) Turquois deposits of Colorado. Economic Geology, 36 (3) 335-344 doi:10.2113/gsecongeo.36.3.335
Cid-Dresdner, Hilda (1965) Determination and refinement of the crystal structure of turquois, CuAl6(PO4)4(OH)8·4H2O. Zeitschrift für Kristallographie - Crystalline Materials, 121 (2) 87-113 doi:10.1524/zkri.1965.121.2-4.87
IMA (1967) International Mineralogical Association: Commission on New Minerals and Mineral Names. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (277) 131-136 doi:10.1180/minmag.1967.036.277.20
Foord, Eugene E., Taggart, Joseph E. (1998) A reexamination of the turquoise group: the mineral aheylite, planerite (redefined), turquoise and coeruleolactite. Mineralogical Magazine, 62 (1) 93-111 doi:10.1180/002646198547495
Abdu, Y. A., Hull, S. K., Fayek, M., Hawthorne, F. C. (2011) The turquoise-chalcosiderite Cu(Al,Fe3+)6(PO4)4(OH)8·4H2O solid-solution series: A Mössbauer spectroscopy, XRD, EMPA, and FTIR study. American Mineralogist, 96 (10) 1433-1442 doi:10.2138/am.2011.3658
Eastman, Kyle A., Gammons, Christopher H., Goemann, Karsten, Griffith, Amanda (2022) Supergene Turquoise and Associated Phosphate Minerals of the Porphyry-Lode System at Butte, Montana, USA. The Canadian Mineralogist, 60 (6) 1013-1026 doi:10.3749/canmin.2100068
Tong, Shuoyun, Chen, Guodong, Hu, Weikang, Pan, Shiyang, Zhu, Dan, Liu, Shuang, Lu, Li, Zhou, Shunchao, Zhou, Wanfeng (2023) Determination of Geographic Origin of Turquoise by Combining Laser Ablation Inductively Coupled Plasma Mass Spectrometry Analysis and Chemometrics. Minerals, 13 (10) doi:10.3390/min13101338
Localities for Turquoise
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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Miguel Vacas Mine, Nossa Senhora da Conceição e São Bartolomeu, Vila Viçosa, Évora, Portugal