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Vonbezingite

A valid IMA mineral species
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About VonbezingiteHide

Formula:
Ca6Cu3(SO4)3(OH)12 · 2H2O
Colour:
Deep blue
Lustre:
Vitreous, Sub-Vitreous
Hardness:
4
Specific Gravity:
2.82
Crystal System:
Monoclinic
Name:
Named after K. Ludi Von Bezing, physician and mineral collector.
This page provides mineralogical data about Vonbezingite.


Unique IdentifiersHide

Mindat ID:
4206
Long-form identifier:
mindat:1:1:4206:8
GUID
(UUID V4):
5f037b2d-967b-43dc-98e0-02d9e2f7c10d

Classification of VonbezingiteHide

Approved
Approval year:
1991
First published:
1992
7.DD.65

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.5.1.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
5 : (AB)3(XO4)Zq·xH2O

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
VbzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of VonbezingiteHide

Vitreous, Sub-Vitreous
Comment:
Vitreous on fractured surfaces, subvitreous on crystal faces.
Colour:
Deep blue
Streak:
Light blue
Hardness:
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed
Fracture:
Sub-Conchoidal
Density:
2.82(2) g/cm3 (Measured)    2.81 g/cm3 (Calculated)

Optical Data of VonbezingiteHide

Type:
Biaxial (-)
RI values:
nα = 1.590(2) nβ = 1.610(3) nγ = 1.619(2)
2V:
Measured: 65° to 67°, Calculated: 66°
Max Birefringence:
δ = 0.029
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v distinct
Optical Extinction:
X = b, Y ∧ a = 30.2° and Z ∧ c = - 11.5°.
Pleochroism:
Strong
Comments:
X = pale blue; Y = grayish blue; Z = dark blue

Chemical Properties of VonbezingiteHide

Formula:
Ca6Cu3(SO4)3(OH)12 · 2H2O

Crystallography of VonbezingiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 15.122(2) Å, b = 14.358(1) Å, c = 22.063(4) Å
β = 108.68(1)°
Ratio:
a:b:c = 1.053 : 1 : 1.537
Unit Cell V:
4,538.01 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Common forms are {110}, {010}, {100}, {111}, and {101}.
Twinning:
On {001} by merohedry

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001543VonbezingiteDai Y S, Harlow G E (1992) Description and crystal structure of vonbezingite, a new Ca-Cu-SO4-H2O mineral from the Kalahari manganese field, South Africa American Mineralogist 77 1292-13001992Wessels mine, South Africa0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.393 Å(100)
3.368 Å(55)
3.120 Å(85)
3.200 Å(53)
3.188 Å(65)
3.098 Å(57)
2.769 Å(41)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]

Type Occurrence of VonbezingiteHide

General Appearance of Type Material:
Dark blue euhedral crystals to 1 cm with other species lining a pocket.
Place of Conservation of Type Material:
American Museum of Natural History, New York, New York, USA, T100748
Geological Setting of Type Material:
Probably crystallized from surface or ground water during a period of evaporation at ambient temperature and atmospheric pressure.
Associated Minerals at Type Locality:
Reference:
Dai, Y. & Harlow, G. E. (1992): Description and crystal structure of vonbezingite, a new Ca-Cu-SO4-H2O mineral from the Kalahari manganese field, South Africa. American Mineralogist: 77: 1292-1300.

Synonyms of VonbezingiteHide

Other Language Names for VonbezingiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Vonbezingite associated with EttringiteCa6Al2(SO4)3(OH)12 · 26H2O
1 photo of Vonbezingite associated with ThaumasiteCa3(SO4)[Si(OH)6](CO3) · 12H2O
1 photo of Vonbezingite associated with CalciteCaCO3
1 photo of Vonbezingite associated with TobermoriteCa4Si6O17(H2O)2 · (Ca · 3H2O)

Related Minerals - Strunz-mindat GroupingHide

7.DD.AsagiiteNiCu4(SO4)(OH)6 · 6H2OMon. 2/m : P21/b
7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.07LlantenesiteCu6Al[SeO4](OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.10GobeliniteCoCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/m
7.DD.10FehriteMgCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/b
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.15KobyasheviteCu5(SO4)2(OH)6 · 4H2OTric. 1 : P1
7.DD.15Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.20KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/b
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric. 1 : P1
7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon. 2 : B2
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6 · 4H2O Mon. 2/m : P21/b
7.DD.35Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
7.DD.40IsseliteCu6(SO4)(OH)10 · 5H2OOrth. mm2 : Pmn21
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.45Hodgesmithite(Cu,Zn)6Zn(SO4)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.47LahnsteiniteZn4(SO4)(OH)6 · 3H2O Tric. 1 : P1
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.50Minohlite(Cu,Zn)7(SO4)2(OH)10 · 8H2OHex.
7.DD.52LauraniiteCu6Cd2(SO4)2(OH)12 · 5H2OMon. 2/m : P21/b
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75NickelalumiteNiAl4(SO4)(OH)12(H2O)3Mon. 2/m
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12 · 3H2OMon. 2/m
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig. 3
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl · 6H2OTrig. 3 : P3
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Fluorescence of VonbezingiteHide

Not fluorescent

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for VonbezingiteHide

References for VonbezingiteHide

Reference List:

Localities for VonbezingiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
South Africa (TL)
 
  • Northern Cape
    • Kalahari manganese field
      • Hotazel
 
Mineral and/or Locality  
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