Magnesiovesuvianite
A valid IMA mineral species
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Formula:
Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9
The formula is a partial simplification of the full structural formula. The large (VII-IX)-coordinated (X4)2(X3)8(X2)8(X1) sites are here combined (e.g. Ca19) and are typically filled with Ca, although other large cations such as the REE may be present. The square-pyramidal Y1 site can host a variety of M2+ and M3+ ions and is the basis for the distinction of several species. The VI-coordinated Y2 site typically is filled with Al, whereas the also VI-coordinated Y3 site may contain Al, Mg, and other cations of similar charge and size. The tetrahedral T1 site is typically vacant but may contain B (less commonly Al); the trigonal T2 site is also typically vacant but may also contain B. Some of the (SiO4) may be replaced by (H4O4), akin to the Si4+ ↔︎ 4H+ hydrogarnet substitution. Among the oxygen that are not part of the silica tetrahedra, there are eight "O11" that typically occur as OH, two "O10" that are typically O & OH or OH & OH (the latter arrangement notably when Y1 is an M2+ cation). There may also be up to three "O12" that in most vesuvianite-group minerals are absent (and are not included here), but may be present particularly when T1 is occupied.
Colour:
Light pink
Lustre:
Silky
Hardness:
6
Specific Gravity:
3.30
Crystal System:
Tetragonal
Member of:
Name:
For the magnesium analog of vesuvianite.
Type Locality:
The Mg analogue of vesuvianite and cyprine (of Panikorovskii et al., 2017); also the Mg-(OH) analogue of manganvesuvianite.
Unique Identifiers
Mindat ID:
47594
Long-form identifier:
mindat:1:1:47594:5
GUID
(UUID V4):
(UUID V4):
2ef2d4c9-8e17-4581-8a73-f2b6f05496d8
IMA Classification of Magnesiovesuvianite
Approved
IMA Formula:
Ca19Mg(Al11Mg)Si18O69(OH)9
Approval year:
2016
First published:
2017
Type description reference:
Panikorovskii, T.L., Shilovskikh, V.V., Avdontseva, E.Yu., Zolotarev, A.A., Karpenko, V.Yu., Mazur, A.S., Yakovenchuk, V.N., Bazai, A.V., Krivovichev, S.V., Pekov, I.V. (2017) Magnesiovesuvianite, Ca19Mg(Al,Mg)12Si18O69(OH)9, a new vesuvianite-group mineral. Journal of Geosciences, 25-36 doi:10.3190/jgeosci.229
Classification of Magnesiovesuvianite
9.BG.
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Mves | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Magnesiovesuvianite
Silky
Transparency:
Transparent
Colour:
Light pink
Hardness:
6 on Mohs scale
Cleavage:
None Observed
Density:
3.30(1) g/cm3 (Measured) 3.35 g/cm3 (Calculated)
Comment:
Measured by flotation in diluted Clerici solution; calculated using the empirical formula
Optical Data of Magnesiovesuvianite
Type:
Uniaxial (-)
RI values:
nω = 1.725(2) nε = 1.731(2)
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Pleochroism:
Not Visible
Comments:
The Gladstone–Dale compatibility index is –0.018 (superior)
Chemistry of Magnesiovesuvianite
Mindat Formula:
Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9
The formula is a partial simplification of the full structural formula. The large (VII-IX)-coordinated (X4)2(X3)8(X2)8(X1) sites are here combined (e.g. Ca19) and are typically filled with Ca, although other large cations such as the REE may be present. The square-pyramidal Y1 site can host a variety of M2+ and M3+ ions and is the basis for the distinction of several species. The VI-coordinated Y2 site typically is filled with Al, whereas the also VI-coordinated Y3 site may contain Al, Mg, and other cations of similar charge and size. The tetrahedral T1 site is typically vacant but may contain B (less commonly Al); the trigonal T2 site is also typically vacant but may also contain B. Some of the (SiO4) may be replaced by (H4O4), akin to the Si4+ ↔︎ 4H+ hydrogarnet substitution. Among the oxygen that are not part of the silica tetrahedra, there are eight "O11" that typically occur as OH, two "O10" that are typically O & OH or OH & OH (the latter arrangement notably when Y1 is an M2+ cation). There may also be up to three "O12" that in most vesuvianite-group minerals are absent (and are not included here), but may be present particularly when T1 is occupied.
The formula is a partial simplification of the full structural formula. The large (VII-IX)-coordinated (X4)2(X3)8(X2)8(X1) sites are here combined (e.g. Ca19) and are typically filled with Ca, although other large cations such as the REE may be present. The square-pyramidal Y1 site can host a variety of M2+ and M3+ ions and is the basis for the distinction of several species. The VI-coordinated Y2 site typically is filled with Al, whereas the also VI-coordinated Y3 site may contain Al, Mg, and other cations of similar charge and size. The tetrahedral T1 site is typically vacant but may contain B (less commonly Al); the trigonal T2 site is also typically vacant but may also contain B. Some of the (SiO4) may be replaced by (H4O4), akin to the Si4+ ↔︎ 4H+ hydrogarnet substitution. Among the oxygen that are not part of the silica tetrahedra, there are eight "O11" that typically occur as OH, two "O10" that are typically O & OH or OH & OH (the latter arrangement notably when Y1 is an M2+ cation). There may also be up to three "O12" that in most vesuvianite-group minerals are absent (and are not included here), but may be present particularly when T1 is occupied.
Crystallography of Magnesiovesuvianite
Crystal System:
Tetragonal
Class (H-M):
4/m - Dipyramidal
Space Group:
P4/n
Cell Parameters:
a = 15.5362(2) Å, b = 15.5362(2) Å, c = 11.7960(3) Å
Ratio:
a:b:c = 1 : 1 : 0.759
Unit Cell V:
2847.26 ų
Z:
2
Morphology:
Crystals are elongated along [001]; the dominant forms are {100} and/or {110}, both usually with striation along [001]; crystals are terminated by the {111} and {101} or {001} faces.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 10.96 Å | (23) |
| 3.464 Å | (22) |
| 3.038 Å | (33) |
| 2.740 Å | (100) |
| 2.583 Å | (21) |
| 2.365 Å | (94) |
| 2.192 Å | (19) |
| 1.616 Å | (25) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3a: Earth’s earliest Hadean crust | >4.50 |
| 7 : Ultramafic igneous rocks | |
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 13 : Hadean serpentinization |
Geological Setting:
Low temperature hydrothermal solutions poor in iron.
Type Occurrence of Magnesiovesuvianite
General Appearance of Type Material:
Radiating aggregates up to 2 cm across consisting of acicular tetragonal crystals
Place of Conservation of Type Material:
collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia (catalogue
no. 59783)
no. 59783)
Geological Setting of Type Material:
rodingtonite
Associated Minerals at Type Locality:
Reference:
Panikorovskii, T.L., Shilovskikh, V.V., Avdontseva, E.Y., Zolotarev, A.A., Karpenko, V.Y., Mazur, A.S., Yakovenchuk, V.N., Krivovichev, S.V., Bazai, A.V., Krivovichev, S.V., Pekov, I.V. (2017): Magnesiovesuvianite, Ca19Mg(Al,Mg)12Si18O69(OH)9, a new vesuvianite-group mineral. Journal of Geosciences, 62, 25-36.
Synonyms of Magnesiovesuvianite
Relationship of Magnesiovesuvianite to other Species
Member of:
Other Members of this group:
| Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 | Tet. 4/m : P4/n |
| Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 | Tet. 4/m : P4/n |
| Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
| Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
| Manaevite-(Ce) | (Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
| Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 | Tet. 4/m : P4/n |
| Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
| Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
| Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
Related Minerals - Strunz-mindat Grouping
| 9.BG. | Shuiskite-(Cr) | Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O |
| 9.BG. | Alnaperbøeite-(Ce) | Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2 |
| 9.BG. | Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 9.BG. | Zoisite-(Pb) | (CaPb)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG. | Vielleaureite-(Ce) | (Mn2+Ce)(MgAlMn2+)F[Si2O7][SiO4](OH) |
| 9.BG. | Heflikite | (CaCa)(AlAlSc)O[Si2O7][SiO4](OH) |
| 9.BG. | Zilbermintsite-(La) | (CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3 |
| 9.BG.05b | Allanite-(Ce) | (CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(La) | (CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Y) | (CaY)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Clinozoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Dissakisite-(Ce) | (CaCe)(AlAlMg)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Dollaseite-(Ce) | (CaCe)(MgAlMg)F[Si2O7][SiO4](OH) |
| 9.BG.05a | Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Hancockite | (CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Khristovite-(Ce) | (CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH) |
| 9.BG.05a | Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Piemontite | (CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Piemontite-(Sr) | (CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Manganiandrosite-(La) | (Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Tweddillite | (CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriallanite-(Ce) | (CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Niigataite | (CaSr)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Manganiandrosite-(Ce) | (Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Dissakisite-(La) | (CaLa)(AlAlMg)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Vanadoandrosite-(Ce) | (Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Uedaite-(Ce) | (Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05a | Epidote-(Sr) | (CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Nd) | (CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Unnamed (Mg-analogue of Ferriallanite-(Ce)) | (CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce)) | (CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriallanite-(La) | (CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Åskagenite-(Nd) | (Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]O |
| 9.BG.05 | Piemontite-(Pb) | (CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Vanadoallanite-(La) | (CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriakasakaite-(La) | (CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Ferriandrosite-(La) | (Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Androsite-(Ce) | (Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05 | Ferriandrosite-(Ce) | (Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05a v | Unnamed (Ga-analogue of Epidote) | (CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | UM1989-32-SiO:AlCaFeHREE | (Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Manganiakasakaite-(La) | (CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Ferriakasakaite-(Ce) | (CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
| 9.BG.05b | Allanite-(Sm) | (CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH) |
| 9.BG.10 | Zoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
| 9.BG.15 | Macfallite | Ca2Mn3+3(SiO4)(Si2O7)(OH)3 |
| 9.BG.15 | Sursassite | Mn2+2Al3(SiO4)(Si2O7)(OH)3 |
| 9.BG.20 | Julgoldite-(Fe2+) | Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Okhotskite | Ca2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Pumpellyite-(Fe2+) | Ca2Fe2+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
| 9.BG.20 | Pumpellyite-(Fe3+) | Ca2Fe3+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
| 9.BG.20 | Pumpellyite-(Mg) | Ca2MgAl2(Si2O7)(SiO4)(OH)2 · H2O |
| 9.BG.20 | Pumpellyite-(Mn2+) | Ca2Mn2+Al2(Si2O7)(SiO4)(OH)2 · H2O |
| 9.BG.20 | Shuiskite-(Mg) | Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.20 | Julgoldite-(Fe3+) | Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2O |
| 9.BG.20 | Pumpellyite-(Al) | Ca2Al3(Si2O7)(SiO4)(OH,O)2 · H2O |
| 9.BG.20 | Poppiite | Ca2V3+V3+2[Si2O6OH][SiO4](OH)2O |
| 9.BG.20 | Julgoldite-(Mg) | Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH) |
| 9.BG.25 | Ganomalite | Pb9Ca5Mn(Si2O7)4(SiO4)O |
| 9.BG.25 | Wayneburnhamite | Pb9Ca6(Si2O7)3(SiO4)3 |
| 9.BG.30 | Rustumite | Ca10(Si2O7)2(SiO4)(OH)2Cl2 |
| 9.BG.35 | Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 9.BG.35 | Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 |
| 9.BG.35 | Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 9.BG.35 | Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 |
| 9.BG.35 | Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
| 9.BG.35 | Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 |
| 9.BG.35 | Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
| 9.BG.35 | Manaevite-(Ce) | (Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9 |
| 9.BG.40 | Vyuntspakhkite-(Y) | (Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7 |
| 9.BG.45 | Dellaite | Ca6Si3O11(OH)2 |
| 9.BG.50 | Gatelite-(Ce) | CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Perbøeite-(Ce) | CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Ferriperbøeite-(Ce) | CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Ferriperbøeite-(La) | CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.50 | Perbøeite-(La) | CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
| 9.BG.55 | Västmanlandite-(Ce) | CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2 |
| 9.BG.60 | Radekškodaite-(La) | (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
| 9.BG.60 | Radekškodaite-(Ce) | (CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
| 9.BG.60 | Radekškodaite Group | (CaM5)([Fe3+Al3]Fe2+)[Si2O7][SiO4]5O(OH)3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Magnesiovesuvianite
mindat.org URL:
https://www.mindat.org/min-47594.html
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References for Magnesiovesuvianite
Reference List:
Hålenius, U., Hatert, F., Pasero, M., Mills, S.J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 30. Mineralogical Magazine, 80 (2) 407-413 doi:10.1180/minmag.2016.080.081
Panikorovskii, T.L., Shilovskikh, V.V., Avdontseva, E.Yu., Zolotarev, A.A., Karpenko, V.Yu., Mazur, A.S., Yakovenchuk, V.N., Bazai, A.V., Krivovichev, S.V., Pekov, I.V. (2017) Magnesiovesuvianite, Ca19Mg(Al,Mg)12Si18O69(OH)9, a new vesuvianite-group mineral. Journal of Geosciences, 25-36 doi:10.3190/jgeosci.229
Panikorovskii, Taras L., Shilovskikh, Vladimir V., Avdontseva, Evgenia Yu., Zolotarev, Andrey A., Pekov, Igor V., Britvin, Sergey N., Hålenius, Ulf, Krivovichev, Sergey V. (2017) Cyprine, Ca19Cu2+(Al,Mg,Mn)12Si18O69(OH)9, a new vesuvianite-group mineral from the Wessels mine, South Africa. European Journal of Mineralogy, 29 (2) 295-306 doi:10.1127/ejm/2017/0029-2592
Localities for Magnesiovesuvianite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Italy | |
| analysed by Dr. Anthony Kampf +1 other reference |
North Macedonia (TL) | |
| Hålenius et al. (2016) +1 other reference |
Norway | |
| Panikorovskii et al. (2017) |
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