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Chirvinskyite

A valid IMA mineral species
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01894050015858239634416.jpg
Chirvinskyite

Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
08766570016099274822074.jpg
Chirvinskyite

Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
01894050015858239634416.jpg
Chirvinskyite

Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
08766570016099274822074.jpg
Chirvinskyite

Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
01894050015858239634416.jpg
Chirvinskyite

Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
08766570016099274822074.jpg
Chirvinskyite

Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
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About ChirvinskyiteHide

03229880016125770976844.jpg
Petr N. Chirvinsky
Formula:
(Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O
Colour:
cream
Lustre:
Silky
Hardness:
5
Specific Gravity:
3.07
Crystal System:
Triclinic
Name:
Named in honor of Petr Nikolaevich Chirvinsky (Пётр Никола́евич Чирви́нский) (26 January (7 February) 1880, Moscow, Russian Empire - 21 June 1955, Molotov, USSR), geologist and petrographer, head of the Petrography Department of the Perm State University (1943–1953), for his contributions to mineralogy and petrology, including studies of the Khibiny alkaline massif.
New structure type. Chemically somewhat similar to nafertisite, narsarsukite, and selivanovite. wöhlerite–related zirconotitano–sorosilicate.


Unique IdentifiersHide

Mindat ID:
50349
Long-form identifier:
mindat:1:1:50349:7
GUID
(UUID V4):
92114cc4-b1d6-4258-a8b0-ac68c9c0547f

IMA Classification of ChirvinskyiteHide

Classification of ChirvinskyiteHide

Strunz-mindat (2024):
9.BE.92

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CvsIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ChirvinskyiteHide

Lustre:
Silky
Transparency:
Transparent
Colour:
cream
Streak:
white
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Fibrous
Density:
3.07(2) g/cm3 (Measured)    3.41 g/cm3 (Calculated)
Comment:
The difference between calculated and observed values may be caused by numerous inclusions

Optical Data of ChirvinskyiteHide

Type:
Biaxial (-)
RI values:
nα = 1.670(2) nβ = 1.690(2) nγ = 1.705(2)
2V:
Calculated: 80.9°
Max Birefringence:
δ = 0.035
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
None
Pleochroism:
Non-pleochroic

Chemistry of ChirvinskyiteHide

Mindat Formula:
(Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O
Elements listed:
Ca, Fe, H, Mn, Na, O, Si, Ti, Zr - search for minerals with similar chemistry

Crystallography of ChirvinskyiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.0477(5) Å, b = 9.8725(2) Å, c = 12.2204(9) Å
α = 77.995(5)°, β = 82.057(6)°, γ = 89.988(5)°
Ratio:
a:b:c = 0.714 : 1 : 1.238
Unit Cell V:
823.34 ų (Calculated from Unit Cell)
Z:
1

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.00 Å(34)
5.907 Å(17)
3.956 Å(23)
3.416 Å(33)
2.886 Å(57)
2.796 Å(100)
1.741 Å(25)
1.646 Å(16)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of ChirvinskyiteHide

Type Locality:
ⓘ Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia
General Appearance of Type Material:
forms sheaf–like and radiated aggregates (up to 6 mm in diameter) of split fibrous crystal
Place of Conservation of Type Material:
(1) collections of the Mineralogical Museum, St. Petersburg State University, Russia, catalogue No. 19657; (2) the Geological and the Mineralogical Museum, Geological Institute, Kola Science Centre, Apatity, Russia, catalogue No. 7609
Geological Setting of Type Material:
albitized alkaline pegmatite
Associated Minerals at Type Locality:
FluorapatiteAlbite
Reference:
Yakovenchuk, V.N.; Pakhomovsky, Y.A.; Panikorovskii, T.L.; Zolotarev, A.A.; Mikhailova, J.A.; Bocharov, V.N.; Krivovichev, S.V.; Ivanyuk, G.Y. (2019) Chirvinskyite, (Na,Ca)13(Fe,Mn,□)2(Ti,Nb)2(Zr,Ti)3-(Si2O7)4(OH,O,F)12, a New Mineral with a Modular Wallpaper Structure, from the Khibiny Alkaline Massif (Kola Peninsula, Russia). Minerals: 2019(9): 219.
Download:
https://www.mdpi.com/2075-163X/9/4/219/pdf

Synonyms of ChirvinskyiteHide

Related Minerals - Strunz-mindat GroupingHide

9.BE.ParalomonosoviteNa6◻4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF)Tric. 1 : P1
9.BE.CámaraiteBa3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7Tric. 1
9.BE.Christofschäferite-(Ce)Ce3CaMnTiFe(3+)Ti2(Si2O7)2O8 Mon. 2/m : P21/m
9.BE.BobshannoniteNa2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2Tric.
9.BE.Calciomurmanite(Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4Tric. 1 : P1
9.BE.Batievaite-(Y)Y2Ca2Ti(Si2O7)2(OH)2(H2O)4Tric. 1 : P1
9.BE.Delhuyarite-(Ce)Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2Mon. 2/m : B2/m
9.BE.XAsimowiteFe2+4O(Si2O7)Orth. mmm (2/m 2/m 2/m) : Imma
9.BE.MoxuanxueiteNaCa6Zr(Si2O7)2OF3Tric. 1 : P1
9.BE.Alexkuznetsovite-(Ce)Ce2Mn(CO3)(Si2O7)Mon. 2/m : P21/b
9.BE.Biraite-(La)La2Fe2+(CO3)(Si2O7)Mon. 2/m : P21/b
9.BE.ZinkgruvaniteBa4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2Tric. 1 : P1
9.BE.MadeiraiteNa2Ca2Fe2Zr2(Si2O7)2O2F2Mon. 2/m : P21/b
9.BE.BortolaniteCa2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2Tric. 1 : P1
9.BE.Nacareniobsite-(Y)Na3Ca3YNb(Si2O7)2OF3Mon. 2/m : P21/b
9.BE.PilanesbergiteNa2Ca2Fe2Ti2(Si2O7)2O2F2Mon. 2/m : P21/b
9.BE.AlfredcaspariteSr2TiO(Si2O7)Tet. 4mm : P4bm
9.BE.02WadsleyiteMg4O(Si2O7)Orth. mmm (2/m 2/m 2/m) : Imma
9.BE.05HennomartiniteSrMn3+2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.05LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.05NoelbensoniteBaMn3+2(Si2O7)(OH)2 · H2OOrth. mm2
9.BE.05ItoigawaiteSrAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.05CortesognoiteCaV2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.07IlvaiteCaFe3+Fe2+2(Si2O7)O(OH)Orth. mmm (2/m 2/m 2/m)
9.BE.07ManganilvaiteCaFe2+Fe3+Mn2+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.07Amamoorite CaMn2+2Mn3+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.10SuoluniteCa2(H2Si2O7) · H2OOrth. mm2 : Fdd2
9.BE.12JaffeiteCa6(Si2O7)(OH)6Trig. 3 : P3
9.BE.15FresnoiteBa2Ti(Si2O7)OTet. 4mm : P4bm
9.BE.17BaghdaditeCa6Zr2(Si2O7)2O4Mon. 2/m : P21/b
9.BE.17BurpaliteNa2CaZr(Si2O7)F2Mon. 2/m : P21/b
9.BE.17CuspidineCa8(Si2O7)2F4Mon. 2/m : P21/b
9.BE.17HiortdahliteNa2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3Tric. 1 : P1
9.BE.17Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2Mon. 2/m : P21/m
9.BE.17LåveniteNa2Ca2Mn2Zr2(Si2O7)2O2F2Mon. 2/m : P21/b
9.BE.17Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2Mon. m
9.BE.17NormanditeNaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OFMon. 2/m : P21/b
9.BE.17WöhleriteNa2Ca4ZrNb(Si2O7)2O3FMon. 2 : P21
9.BE.20Mosandrite-(Ce)(Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2Mon. 2/m : P21/b
9.BE.20Nacareniobsite-(Ce)Na3Ca3(Ce,REE)Nb(Si2O7)2OF3Mon. 2/m : P21/b
9.BE.20Roumaite(Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3Mon. m : Bb
9.BE.20Rinkite-(Y)Na2Ca4YTi(Si2O7)2OF3Mon. 2/m : P21/b
9.BE.22GötzeniteNaCa6Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22Hainite-(Y)Na2Ca4(Y,REE)Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22RosenbuschiteNa6Ca6Zr3Ti(Si2O7)4O2F6Tric. 1 : P1
9.BE.22KochiteNa3Ca2MnZrTi(Si2O7)2OF3Tric. 1 : P1
9.BE.22Fogoite-(Y)Na3Ca2Y2Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.23DovyreniteCa6Zr(Si2O7)2(OH)4Orth. mmm (2/m 2/m 2/m) : Pnnm
9.BE.25Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
9.BE.25EricssoniteBaMn2+2Fe3+(Si2O7)O(OH)Mon. 2/m : B2/m
9.BE.25Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon. 2/m
9.BE.25Ericssonite-2OBaMn2+2Fe3+(Si2O7)O(OH)Orth.
9.BE.25SeidozeriteNa4MnZr2Ti(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25Nabalamprophyllite(BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2Mon. 2/m : P2/m
9.BE.25GrenmariteNa4MnZr3(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25SchülleriteBa2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4Tric. 1 : P1
9.BE.25KazanskyiteBaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
9.BE.25LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25EmmerichiteBa2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25SaamiteBa◻Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2Tric. 1 : P1
9.BE.25FluorlamprophylliteNa3(SrNa)Ti3(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25Fluorbarytolamprophyllite(Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2]Mon. 2/m : B2/m
9.BE.27MurmaniteNa2Ti2(Si2O7)O2 · 2H2OTric. 1 : P1
9.BE.27VigrishiniteNaZnTi4(Si2O7)2O3(OH)(H2O)4Tric. 1 : P1
9.BE.27KolskyiteCaNa2Ti4(Si2O7)2O4(H2O)7Tric. 1 : P1
9.BE.27SelivanovaiteNaFe3+Ti4(Si2O7)2O4(H2O)4Tric. 1 : P1
9.BE.30Epistolite(Na◻)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
9.BE.32LomonosoviteNa5Ti2(Si2O7)(PO4)O2Tric. 1 : P1
9.BE.35VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
9.BE.37SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
9.BE.40Innelite Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)]Tric. 1 : P1
9.BE.40PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
9.BE.42YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
9.BE.45QuadruphiteNa6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2Tric. 1 : P1
9.BE.47PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
9.BE.50BornemaniteNa6BaTi2Nb(Si2O7)2(PO4)O2(OH)F Tric. 1 : P1
9.BE.50Shkatulkalite Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3Tric. 1 : P1
9.BE.55BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
9.BE.55HejtmaniteBa2Mn2+4Ti2(Si2O7)2O2(OH)2F2Tric. 1
9.BE.55Bykovaite(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2OMon. 2/m
9.BE.55Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
9.BE.60Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon. 2/m : B2/m
9.BE.62Orthochevkinite(Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22Orth.
9.BE.62 vaStrontium Perrierite(Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8
9.BE.62Chevkinite-(Nd)(Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ?
9.BE.62Perrierite-(Nd)Nd4MgFe3+2Ti2(Si2O7)2O8 ?
9.BE.65BusseniteNa2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3FTric. 1 : P1
9.BE.67JinshajiangiteBaNaFe2+4Ti2(Si2O7)2O2(OH)2FTric. 1 : P1
9.BE.67PerraultiteBaNaMn2+4Ti2(Si2O7)2O2(OH)2FTric. 1
9.BE.70Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2OAmor.
9.BE.70Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Chevkinite-(Ce)Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2Mon. 2/m : P21/b
9.BE.70Polyakovite-(Ce)(Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70RengeiteSr4ZrTi4(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70MatsubaraiteSr4Ti5(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Dingdaohengite-(Ce)(Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Maoniupingite-(Ce)(Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70Perrierite-(La)(La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2Mon. 2/m : P21/b
9.BE.70UM2008-53-SiO:SrTiZrSr4ZrTi4(Si2O7)2O8Orth. mmm (2/m 2/m 2/m) : Pbca
9.BE.70Hezuolinite(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.72FersmaniteCa4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3Tric.
9.BE.75BelkoviteBa3(Nb,Ti)6(Si2O7)2O12Hex. 6 m2 : P62m
9.BE.77NasonitePb6Ca4(Si2O7)3Cl2Hex. 6/m : P63/m
9.BE.80KentrolitePb2Mn3+2(Si2O7)O2Orth. mmm (2/m 2/m 2/m) : Pbcm
9.BE.80MelanotekitePb2Fe3+2(Si2O7)O2Orth. 2 2 2 : C2 2 21
9.BE.82TilleyiteCa5(Si2O7)(CO3)2Mon. 2/m : P21/b
9.BE.82Alexkuznetsovite-(La)La2Mn(CO3)(Si2O7)Mon. 2/m : P21/b
9.BE.85KillalaiteCa6.4(H0.6Si2O7)2(OH)2Mon. 2/m : P21/m
9.BE.87Stavelotite-(La)(La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30Trig. 3 : P31
9.BE.90Biraite-(Ce)Ce2Fe2+(Si2O7)(CO3)Mon. 2/m : P21/b
9.BE.90Magnesiorowlandite-(Y)Y4(Mg,Fe)(Si2O7)2F2Tric. 1 : P1
9.BE.92Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)Trig. 3m : R3m
9.BE.95BatisiviteBaV3+8Ti6(Si2O7)O22Tric. 1 : P1
9.BE.95RusinoviteCa10(Si2O7)3Cl2 Orth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.97Schlüterite-(Y)(Y,REE)2AlSi2O7(OH)2FMon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ChirvinskyiteHide

References for ChirvinskyiteHide

Localities for ChirvinskyiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Murmansk Oblast
    • Khibiny Massif
Mineralogical Magazine: 80: 1135–1144 +2 other references
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