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Falgarite

A valid IMA mineral species
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Formula:
K4(VO)3(SO4)5
Colour:
Turquoise
Lustre:
Vitreous
Hardness:
2 - 3
Specific Gravity:
2.87
Crystal System:
Monoclinic
Name:
For the Falgar, an ancient Sogdian name of an area in Zeravshan riverhead.
Known synthetic analogue. Unique combination of elements (among the known minerals): the first natural potassium vanadyl sulfate.


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Unique IdentifiersHide

Mindat ID:
53161
Long-form identifier:
mindat:1:1:53161:2
GUID
(UUID V4):
b5fcae1a-0f72-4e1f-8215-e1d2431d2d36

IMA Classification of FalgariteHide

Classification of FalgariteHide

7.BC.55

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
FalIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FalgariteHide

Vitreous
Transparency:
Transparent
Colour:
Turquoise
Streak:
white
Hardness:
2 - 3 on Mohs scale
Cleavage:
None Observed
Parting:
None
Density:
2.87(2) g/cm3 (Measured)    2.89 g/cm3 (Calculated)

Optical Data of FalgariteHide

Type:
Biaxial (+/-)
RI values:
nα = 1.588(3) nβ = 1.600(3) nγ = 1.609(2)
2V:
Measured: 68° to 90°
Max Birefringence:
δ = 0.021
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
Dispersion is strong, v>r
Pleochroism:
Weak
Comments:
Bluish-green (Z) to light-green (X and Y ). Absorption is Z > Y ≥ X.
Comments:
β calculated. Color is varying from bluish-green (Z) to light-green (X and Y). The optical sign changes From positive in yellow and red light on negative in blue.

Chemistry of FalgariteHide

Mindat Formula:
K4(VO)3(SO4)5

Crystallography of FalgariteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 8.709(1) Å, b = 16.146(2) Å, c = 14.450(2) Å
β = 106.785(4)°
Ratio:
a:b:c = 0.539 : 1 : 0.895
Unit Cell V:
1953.77 ų
Z:
4

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.26 Å(40)
3.52 Å(40)
3.34 Å(40)
3.20 Å(70)
3.17 Å(80)
3.14 Å(70)
3.01 Å(50)
2.881 Å(100)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of FalgariteHide

General Appearance of Type Material:
small isometric or pseudo octahedral individual crystals (10-60 microns) of turquoise color and spherical aggregates up to 0.5 mm in diameter and overgrown on the white sulfate crusts
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5234/1
Geological Setting of Type Material:
Coal fire
Associated Minerals at Type Locality:
Reference:
Pautov, L.A., Mirakov, M.A., Siidra, O.I., Faiziev, A.R., Nazarchuk, Е.V., Karpenko, V.Y., Makhmadsharif, S. (2020) Falgarite, K4(VO)3(SO4)5, a new mineral from sublimates of a natural underground coal fire at the tract of Kukhi-Malik, Fan-Yagnob coal deposit, Tajikistan. Mineralogical Magazine: 84: 455-462.

Synonyms of FalgariteHide

Related Minerals - Strunz-mindat GroupingHide

7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 4 3m : I4 3d
7.BC.AgaitePb3CuTeO5(OH)2(CO3) Orth. mm2 : Pca21
7.BC.D'Ansite-(Fe)Na21Fe2+(SO4)10Cl3Iso. 4 3m : I4 3d
7.BC.Acmonidesite(NH4,K,Pb)8NaFe2+4(SO4)5Cl8Orth. 2 2 2 : C2 2 21
7.BC.BackitePb2AlTeO6ClTrig. 3 2 : P3 1 2
7.BC.HagstromitePb8Cu2+(Te6+O6)2(CO3)Cl4Orth. mmm (2/m 2/m 2/m) : Ibam
7.BC.WildcatiteCaFe3+Te6+O5(OH)Trig. 3m (3 2/m) : P3 1m
7.BC.FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
7.BC.ZincochenitePb4Zn(OH)6(SO4)2Tric. 1 : P1
7.BC.ViskontitePb5Cu2(SO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso. 4 3m : I4 3m
7.BC.07ApateliteFe3(SO4)2(OH)5 · 0.5H2O
7.BC.07Unnamed (Ba-Fe Vanadate)Ba, Fe, V, O, H
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Natroalunite-2c(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso. 4 3 2 : I41 3 2
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20PuniniteNa2Cu3O(SO4)3Mon. 2/m : B2/b
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon. 2/m
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet. 4 : I4
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon. 2
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.45BelousoviteKZn(SO4)ClMon. 2/m : P21/b
7.BC.47MülleritePb2Fe3+(Te6+O6)ClTrig. 3 2 : P31 1 2
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.50ElasmochloiteNa3Cu6BiO4(SO4)5Mon. 2/m
7.BC.52Eleomelanite(K2Pb)Cu4O2(SO4)4Mon. 2/m
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.57KrasheninnikoviteKNa2CaMg(SO4)3FHex. 6/mmm (6/m 2/m 2/m) : P63/mcm
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.60WulffiteK3NaCu4O2(SO4)4Orth. mm2
7.BC.60ParawulffiteK5Na3Cu8O4(SO4)8Mon. 2/m : P2/b
7.BC.62ShuvaloviteK2(Ca2Na)(SO4)3FOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.65Therasiaite(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5Mon. m : Bb
7.BC.65SaccoiteCa2Mn3+2F(OH)8 · 0.5(SO4)Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Fluorescence of FalgariteHide

Not fluorescent in SW or LW UV

Other InformationHide

Notes:
The mineral is non-soluble in H2O and 5% HNO3 at room temperature.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FalgariteHide

References for FalgariteHide

Localities for FalgariteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Tajikistan (TL)
 
  • Sughd
    • Zeravshan Range
      • Yagnob River
Hålenius et al. (2018) +1 other reference
 
Mineral and/or Locality  
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