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Sphalerite : ZnS

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minID: KQY-X75

Sphalerite : ZnS

This image is copyrighted. Unauthorized reproduction prohibited.
Dimensions: 3 mm x 3 mm x 3 mm

Typical habit of sphalerite crystal from Falcacci stope.
Cube (red).
Tetrahedra: direct (green) and inverse (blue).
Crystal size: 3 mm.
Collected in 1991, coll. & photo Giuliano Bettini.


This Photo was Mindat.org Photo of the Day - 30th May 2014

This photo has been shown 1167 times
Photo added:2nd May 2014
Dimensions:1953x1383px (2.70 megapixels)

Data Identifiers

Mindat Photo ID:610721 📋 (quote this with any query about this photo)
Long-form Identifier:mindat:1:4:610721:2 📋
GUID:7c45ae82-cbce-4b89-9948-6efcdc3d50d7 📋
Specimen MinIDKQY-X75 (note: this is not unique to this photo, it is unique to the specimen)

Discuss this Photo

PhotosSphalerite - Falcacci stope, Rio Mine, Rio Marina, Elba Island, Livorno Province, Tuscany, Italy

30th May 2014 09:52 UTCJosé Zendrera 🌟 Manager

I think there is a mistake in this image description:


"Typical habit of sphalerite crystal from Falcacci stope.

Cube (red).

Tetrahedra: direct (green) and inverse (blue)."


To my understanding, green and blue faces belongs to octahedron, not to "direct" and "inverse" tetrahedrons.

30th May 2014 12:10 UTCGerhard Niklasch Expert

Sphalerite crystallizes in the hextetrahedral class. The positive and negative tetrahedron are separate, inequivalent forms.


A nice illustration for the ongoing International Year of Crystallography! :)-D


Cheers, Gerhard

30th May 2014 14:40 UTCReiner Mielke Expert

Very nice illustration! Thank you Giuliano! Just the kind of thing we need more of on Mindat.

30th May 2014 16:00 UTCJosé Zendrera 🌟 Manager

Oh, oh, it is clear that I have much to learn, thank you very much for explanations.


One more question: a combination of direct and inverse tetrahedrons will conform an ocahedron or only a bipyramide? I mean, angles between opposed faces measured across a vertice in an octahedron are equal to angles between faces measured perpendiculary to a edge in the tetrahedron?


Thanks again.

30th May 2014 19:36 UTCRob Woodside 🌟 Manager

A positive and negative tetrahedon in equal development give an octahedron. I used to be bothered when photos of sphalerite showing triangular faces were called Octos!!! I'd huff and puff about sphalerite being tetrahedral and not making octos. Then in short order I saw a perched octo from Naica and most Bulgarian sphalerites are also octos, which is much shorter than "positive and negative tetrahedrons in equal development"!

30th May 2014 21:37 UTCEd Clopton 🌟 Expert

Jose:


I'm operating at the very limit of my understanding of crystallography, but here goes: In crystallographic terms, an octahedron is a set of eight faces that occur together, and the crystal structure of the mineral must be such that all eight faces can form at once. Sphalerite does not have that degree of symmetry; the best it can do is a couple of tetrahedrons that may (in fact, usually do) occur one at a time depending on pressure, temperature, pH, trace elements, phase of the moon, and whatever else influences the decisions crystals make about which forms to develop.


If all the stars are properly aligned, both tetrahedron forms develop and the result is what looks to a geometrically oriented person like an octahedron--but a crystallographer recognizes it (especially if the faces are color-coded) as two equally developed tetrahedrons.


A similar thing happens with the terminal faces on quartz. Ordinary (alpha) quartz is terminated most often by two rhombohedron forms. Sometimes you see only one of them, resulting in a trigonal pyramid on top of the prism, and sometimes you see both equally developed, resulting in what looks like a hexagonal pyramid. Usually they are unequally developed, resulting in a termination with three large faces and three small faces. High-temperature beta quartz has true hexagonal symmetry, which produces a genuine six-sided pyramid, as opposed to alpha quartz's two intersecting forms that may coincidentally produce a pyramid-like form with six sides.

30th May 2014 22:09 UTCJosé Zendrera 🌟 Manager

05450560016029242949657.jpg
Thank you Rob and Ed, now I understand. Is amazing (and to me a little confusing!) how some minerals can do forms belonging to a superior crystallographic class than his own class.


sphalerite {111}, {1-11}, {100}

Although here are also present positive and negative tetrahedrons plus the hexahedron, is not confusing due to different development of tetrahedrons.

image Β©: smorf http://www.smorf.nl/crystals_az_naam.php?crystal=Sphalerite_009

5th Jun 2014 00:08 UTCJosé Zendrera 🌟 Manager

07533790016029242945576.jpg
Today I was rereading an old book (Minerals from Spain, Calderon, 1910) and I meet this drawing that shows sphalerite twins:


If these forms are really twins now I understand why the picture which start this thread has a octahedral simetry, which would not be possible in a single crystal belonging to hexatetrahedral class.


Is this a twin as stated in this old book?


Thanks for your comments.

5th Jun 2014 00:25 UTCRob Woodside 🌟 Manager

Fig 10 is not a twin, but it seems that Fig. 11 is on 111. Notice that if you only saw a smooth pyrite cube, you would say it is hexoctahedral like fluorite or galena and miss the fact that it is in the pyritohedral class. If only a few simple forms develop, a crystal can mimic a higher symmetry class as in a pyrite cube or sphalerite octo.

5th Jun 2014 17:08 UTCJosé Zendrera 🌟 Manager

Thank you Rob, pyrite example is very clarifying to understand that some crystal forms have a superior simmetry than his theorical simmetry class.

Anyway this sphalerite with both regular and inverse tetrahedrons is still very baffling to me...

7th Jun 2014 21:19 UTCJosé Zendrera 🌟 Manager

Just to comment that in the book Mineralogy for amateurs (J. Sinkankas, 1964) in pag. 296 there is a figure similar to Fig. 10 viewed above and says: "Twinning very common on o<111>, and repeated, manifested by narrow striations and bands of slightly differing luster on crystal surfaces and cleavage planes."

Perhaps Calderon and Sinkankas they refers to a polisynthetic twinning?

7th Jun 2014 22:01 UTCUwe Kolitsch Manager

Yes, they do. The result can be some strange "hexagonal prisms" such as http://www.mindat.org/photo-21209.html.

8th Jun 2014 01:53 UTCRob Woodside 🌟 Manager

Thanks Uwe, without a x-ray most would think that wurtzite. Copper can make similar polysynthetic hexagonal prisms and there is no question there about some kind of pseudomorph. Years ago it was reported that the Wurtzite from Thomaston Dam in Connecticut had all pseudoed to sphalerite. I guess the polysynthetic twin lines here argue against any pseudomorphism here.

8th Jun 2014 11:12 UTCJosé Zendrera 🌟 Manager

08320680016029242948634.jpg
Let me show what I think is another example of polysynthetic twinning in sphalerite. Unfortunately, in this case, the crystal faces are not appreciated.


Sphalerite

Las Manforas Mine (Aliva Mine), CamaleΓ±o, Cantabria, Spain

8,5 x 6 x 4,5 cm

 
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