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Fritsch, Emmanuel, Balan, Etienne, Petit, Sabine, Juillot, Farid (2021) Structural, textural, and chemical controls on the OH stretching vibrations in serpentine-group minerals. European Journal of Mineralogy, 33 (4) 447-462 doi:10.5194/ejm-33-447-2021

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Reference TypeJournal (article/letter/editorial)
TitleStructural, textural, and chemical controls on the OH stretching vibrations in serpentine-group minerals
JournalEuropean Journal of MineralogyISSN0935-1221
AuthorsFritsch, EmmanuelAuthor
Balan, EtienneAuthor
Petit, SabineAuthor
Juillot, FaridAuthor
Year2021 (August 3)Volume33
Page(s)447-462Issue4
PublisherCopernicus GmbH
URL
Download URLhttps://ejm.copernicus.org/articles/33/447/2021/ejm-33-447-2021.pdf+
DOIdoi:10.5194/ejm-33-447-2021Search in ResearchGate
Classification
Not set
LoC
Not set
Mindat Ref. ID17069006Long-form Identifiermindat:1:5:17069006:7
GUID19e9d1b4-05fd-4b43-96eb-efedbf0f684d
Full ReferenceFritsch, Emmanuel, Balan, Etienne, Petit, Sabine, Juillot, Farid (2021) Structural, textural, and chemical controls on the OH stretching vibrations in serpentine-group minerals. European Journal of Mineralogy, 33 (4) 447-462 doi:10.5194/ejm-33-447-2021
Plain TextFritsch, Emmanuel, Balan, Etienne, Petit, Sabine, Juillot, Farid (2021) Structural, textural, and chemical controls on the OH stretching vibrations in serpentine-group minerals. European Journal of Mineralogy, 33 (4) 447-462 doi:10.5194/ejm-33-447-2021
In(2021) European Journal of Mineralogy Vol. 33 (4) Schweizerbart
Abstract/NotesThe OH stretching vibrational properties of eight serpentine samples from veins of the New Caledonian ophiolite have been investigated by Fourier-transform infrared spectroscopy (FTIR) in the mid-infrared and near-infrared ranges and by Raman spectroscopy. The samples were selected for their monophasic composition (Lz: lizardite; Ctl: chrysotile; and Atg: antigorite) making them representative of the three serpentine species. Comparison of fundamental and overtone spectra allowed us to interpret most of the observed bands and to propose consistent spectral decomposition in individual components. The OH stretching bands related to intrinsic vibrational properties of the minerals are distinguished from those associated with chemical substitutions in octahedral sites (mainly Fe and Ni for Mg substitutions). Observations made on the most symmetric Lz are consistent with previous interpretations and underline the effect of macroscopic parameters on OH stretching bands in the FTIR spectra. The major importance of the distribution of OH bond lengths in the broadening of the vibrational signals of the less symmetric and more distorted Atg is confirmed. The combination of the three spectroscopic methods makes it possible to unravel the occurrence of two different types of interlayer OH environments in Ctl nanotubes. One corresponds to the features observed at 3684 and 7171 cm−1 in the fundamental and overtone spectra, respectively, and is similar to the local OH environment observed in Lz. The other corresponds to broader signals observed at 3693 and 7200 cm−1 in the fundamental and overtone spectra, respectively. It reflects a distribution of OH bond lengths likely related to local structural misfits between adjacent layers in the tubular structure of Ctl.

References Listed

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Not Yet Imported: European Journal of Mineralogy - journal-article : 10.5194/ejm-33-209-2021

If you would like this item imported into the Digital Library, please contact us quoting Journal ID 22404
Not Yet Imported: European Journal of Mineralogy - journal-article : 10.5194/ejm-33-389-2021

If you would like this item imported into the Digital Library, please contact us quoting Journal ID 22404
Brindley, G. W. and Wan, H. M.: Composition, structures and thermal behaviour of nickel-containing minerals in the lizardite-nepouite series, Am. Mineral., 60, 863–871, 1975.
Chernosky, J. V.: Aggregate refractive indices and unit cell parameters of synthetic serpentine in the System MgO-Al2O3-SiO2-H2O, Am. Mineral., 60, 200–208, 1975.
Not Yet Imported: Chemical Communications - journal-article : 10.1039/b203430a

If you would like this item imported into the Digital Library, please contact us quoting Journal ID 12837
Not Yet Imported: - book : 10.1180/mono-4

If you would like this item imported into the Digital Library, please contact us quoting Book ID 9780903056052
Not Yet Imported: Advanced Functional Materials - journal-article : 10.1002/adfm.200400355

If you would like this item imported into the Digital Library, please contact us quoting Journal ID 1597
Not Yet Imported: Applied Spectroscopy - journal-article : 10.1177/0003702818764446

If you would like this item imported into the Digital Library, please contact us quoting Journal ID 5941
Kunze, G.: Antigorit: Strucktur theoretische Grundlagen und ihre praktische Bedeutung fĂŒr die weitere Serpentinforschung, Fortschritte der Mineralogie, 39, 206–324, 1961.
Lemaire, C.: Application des spectroscopies vibrationnelles à la détection d'amiante dans les matériaux et à l'étude des serpentines, PhD, Université de Paris 7, Paris, 157 pp., 2000.
Luce, R. W.: Identification of serpentine varieties by infra-red absorption: U.S.G.S. Prof. Paper, 750B, 199–201, 1971.
Page, N. J.: Chemical differences among the serpentine “polymorphs”, Am. Mineral., 53, 201–215, 1968.
Whittaker, E, J. W., and Wicks, F. J.: Chemical differences among the serpentine “polymorphs”: A discussion, Am. Mineral., 55, 1025–1047, 1970.
Not Yet Imported: Hydrous Phyllosilicates - book-chapter : 10.1515/9781501508998-010

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Wilkins, R. W. T. and Ito, J.: Infrared spectra of some synthetic talcs, Am. Mineral., 52, 1649–1661, 1967.

Mineral Pages

MineralCitation Details
Antigorite
Chrysotile
Lizardite
Serpentine Subgroup


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