Ilmajokite-(Ce)
A valid IMA mineral species
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About Ilmajokite-(Ce)
Formula:
Na11KBaCe2Ti12Si37.5O94(OH)31 · 29H2O
formerly given as (Na,Ce,Ba)2TiSi3O5(OH)10.nH2O and (Na,Ce,Ba)10Ti5Si14O22(OH)44.nH2O
Colour:
Bright yellow
Lustre:
Vitreous
Hardness:
1
Crystal System:
Monoclinic
Name:
Named for the Ilmajok River, Russia, located near the type locality. It was originally named simply ilmajokite and renamed in 2020 after new data showed a REE as a species-forming element. The new name follows the IMA nomenclature (Levinson rule) for REEs.
The crystal structure is based upon complex porous titanosilicate framework in which the SiO4 tetrahedra form a three-dimensional structure with a previously unknown topology.
Third (?) most structurally complex mineral after ewingite and morrisonite (also compare batoniite).
Structural complexity: 8.468 bits per atom; 11990.129 bits per cell.
The most complex mineral framework structure (complexity comparable to that of paulingite-Ca).
Compare heamanite-(Ce), that, however, is not a silicate but an oxide.
Third (?) most structurally complex mineral after ewingite and morrisonite (also compare batoniite).
Structural complexity: 8.468 bits per atom; 11990.129 bits per cell.
The most complex mineral framework structure (complexity comparable to that of paulingite-Ca).
Compare heamanite-(Ce), that, however, is not a silicate but an oxide.
Unique Identifiers
Mindat ID:
2012
Long-form identifier:
mindat:1:1:2012:7
GUID
(UUID V4):
(UUID V4):
4984d162-a8de-4ea3-917e-9f6665bd0d79
IMA Classification of Ilmajokite-(Ce)
Approved
IMA status notes:
Redefined by the IMA, Renamed by the IMA
IMA Formula:
Na11KBaCe2Ti12Si37.5O94(OH)30 · 29H2O
Approval year:
1971
First published:
1972
Approval history:
Approved as IMA1971-027, as Ilmajokite.
2019: Revised chemical formula as Na11KBaCe2Ti12Si37.5O94(OH)31·29H2O and renamed as Ilmajokite-(Ce). (CNMNC Newsletter 53)
2019: Revised chemical formula as Na11KBaCe2Ti12Si37.5O94(OH)31·29H2O and renamed as Ilmajokite-(Ce). (CNMNC Newsletter 53)
Classification of Ilmajokite-(Ce)
9.HB.05
9 : SILICATES (Germanates)
H : Unclassified silicates
B : With Ti, V, Cr
9 : SILICATES (Germanates)
H : Unclassified silicates
B : With Ti, V, Cr
78.7.5.1
78 : Unclassified Silicates
7 :
78 : Unclassified Silicates
7 :
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Ijk-Ce | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Ilmajokite-(Ce)
Vitreous
Transparency:
Transparent, Translucent
Colour:
Bright yellow
Hardness:
1 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
Optical Data of Ilmajokite-(Ce)
Type:
Biaxial (+)
RI values:
nα = 1.573 nβ = 1.576 nγ = 1.579
2V:
Measured: 90° , Calculated: 88°
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r < v strong
Chemistry of Ilmajokite-(Ce)
Mindat Formula:
Na11KBaCe2Ti12Si37.5O94(OH)31 · 29H2O
formerly given as (Na,Ce,Ba)2TiSi3O5(OH)10.nH2O and (Na,Ce,Ba)10Ti5Si14O22(OH)44.nH2O
formerly given as (Na,Ce,Ba)2TiSi3O5(OH)10.nH2O and (Na,Ce,Ba)10Ti5Si14O22(OH)44.nH2O
Common Impurities:
Zr,Al,TR,Fe,Nb,Ta,Ca,Sr,K,C
Crystallography of Ilmajokite-(Ce)
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 35.908(5) Å, b = 27.784(3) Å, c = 33.126(4) Å
β = 96.494(3)°
β = 96.494(3)°
Ratio:
a:b:c = 1.292 : 1 : 1.192
Unit Cell V:
32,836.70 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
11.5 Å | (100) |
10.9 Å | (70) |
10.2 Å | (90) |
4.3 Å | (100) |
3.7 Å | (70) |
3.1 Å | (90) |
2.44 Å | (100) |
Comments:
Lovozero massif, Russia. The data are from the type description.
Type Occurrence of Ilmajokite-(Ce)
General Appearance of Type Material:
Granular deposits, crusts, and brushes of crystals.
Place of Conservation of Type Material:
Geology Museum, Kola Branch, Academy of Sciences, Russia, 3152, 3153.
Mining Institute, St. Petersburg, Russia, 1061/1-2.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 74041, 74080, 74490, 74491.
National School of Mines, Paris, France.
Mining Institute, St. Petersburg, Russia, 1061/1-2.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 74041, 74080, 74490, 74491.
National School of Mines, Paris, France.
Geological Setting of Type Material:
Alkaline pegmatite.
Reference:
Bussen, I.V., Gannibal, L.F., Goiko, E.A., Mer'kov, A.N., Nedorezova, A.P. (1972) Ilmajokite, a new mineral from the Lovozero Tundra. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 101(1): 75-79.
Synonyms of Ilmajokite-(Ce)
Other Language Names for Ilmajokite-(Ce)
German:Ilmajokit
Spanish:Ilmajokita
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
9.HB. | Waipouaite | Ca3V4+5O9[Si2O5(OH)2][Si3O7(OH)2] · 11H2O |
9.HB.10 | Rilandite | Cr6SiO11 · 5H2O (?) |
Other Information
Notes:
Decomposes in water at 20°C, giving amorphous silica and in acid, giving slight effervescence and amorphous silica gel.
Special Storage/
Display Requirements:
Display Requirements:
Unstable in ambient conditions.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ilmajokite-(Ce)
mindat.org URL:
https://www.mindat.org/min-2012.html
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References for Ilmajokite-(Ce)
Reference List:
Localities for Ilmajokite-(Ce)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Bussen et al. (1972) +3 other references |
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Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia