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Terlinguaite : [Hg3]4+Hg2+Cl2O2, Goethite : α-Fe3+O(OH), Quartz : SiO2, Cinnabar : HgS, Corderoite : Hg2+3S2Cl2, Shakhovite ? : [Hg2]2+Hg2+2[Sb3+O3](OH)3

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Summary of all keyboard shortcuts

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Copyright © Michael F. Cox
 
 
 
 
minID: 91X-UW4

Terlinguaite : [Hg3]4+Hg2+Cl2O2, Goethite : α-Fe3+O(OH), Quartz : SiO2, Cinnabar : HgS, Corderoite : Hg2+3S2Cl2, Shakhovite ? : [Hg2]2+Hg2+2[Sb3+O3](OH)3

Copyright © Michael F. Cox  - Creative Commons Non-Commercial Share Alike Licence - Some Rights Reserved
Field of View: 4 mm

Terlinguaite and iridescent goethite on quartz in a matrix of silicified tuffaceous sediment. Minor red colloidal cinnabar with an admixture of corderoite (up to 25% or so) occurs scattered in the matrix, a thin band is visible at the lower left. The goethite displays a typical iridescence and it, as well as the brown iron staining, might be from the decomposition of pyrite during mineralization of the mercury mine deposit.

This sample is a small pocket approximately 2-cm in size recovered from an exposure of veined stibnite and cinnabar in silicified tuffaceous rock. The matrix is rich in massive stibnite. The cinnabar , goethite, and quartz are typical. The quartz crystals are distinct and are often enveloped by black silica tubes and presumed goethite, based on luster, iridescence, and past PXRD identification at this location. Where the quartz appears to be black, brown, or red, it is because of inclusions and the substrate. Goethite and silica tubes are most abundant where terlinguaite also occurs. Corderoite is presumed based on the fact it occurs in an intimate mixture with cinnabar at this deposit, and also because matrix not shown contains microscopic corderoite crystals.

The terlinguaite and shakhovite were confirmed by Gail Dunning, well known expert on mercury minerals and locations. Gail was assisted by Anthony Kampf, who performed the PXRD. AT the left center side of the photo is a flat-lying striated crystal that is not tapered. This might be shakhovite, a mineral also found in this small pocket.

Goethite is sometimes included in the quartz, but mostly coats the quartz. The yellow-green terlinguaite mostly covers the goethite and silica tubes, but the later sometimes coat the terlinguaite or are included in the terlinguaite. This, and the assemblage of secondary oxide minerals formed by the redox of other minerals, for example goethite after pyrite, suggest oxidation during deposition. McCormack (1986) believed meteoric water mixing probably supplied limited oxygen during the hydrothermal activity, but also believed that most of the oxidation products at the deposit are supergene and formed much later from ordinary weathering processes. The goethite in this specimen, being included in quartz that is, in turn, under terlinguaite, points to oxidation during the mineral precipitation.

This pocket was found in vuggy banded stibnite and quartz veining, with post-deposition but coeval dissolution and then in-filling of pores, voids, and fractures with massive cinnabar and corderoite, and then subsequent alteration to secondary mercury minerals, including those shown here and others not shown, such as calomel, montroydite, and a half-dozen unnamed mercury minerals that are in process for characterization and naming. The silicified tuffaceous sandstone matrix is comprised of grains of locally-reworked (fluvial and lacustrine) peralkaline rhyolite ash dating to about 16.39 ± 0.02 Ma (n = 3) (Henry et al., 2017), the main eruption of the McDermitt caldera. Antimony, mercury, and other trace elements in hydrothermal fluids invaded the volcanic rocks and sediments very soon after the first ring fractures formed around the developing caldera collapse. From the research of a significant body of professionals and academics, the caldera geology and mineral deposits are well defined.

Henry et al. of Stanford University published a fabulous map and description of the McDermitt caldera and rocks. It can be downloaded online. As of June, 2017, the URL for the map is: https://pubs.nbmg.unr.edu/Prel-geol-McDermitt-caldera-p/of2016-01.htm

Collected: 2016 by Michael F. Cox

This photo has been shown 89 times
Photo added:11th Jun 2020
Dimensions:5184x3456px (17.92 megapixels)
Camera:CANON EOS 600D / Rebel T3i / Kiss X5

Data Identifiers

Mindat Photo ID:1058211 📋 (quote this with any query about this photo)
Long-form Identifier:mindat:1:4:1058211:1 📋
GUID:ff687714-9d64-4f44-b417-ed0ade9b46e7 📋
Specimen MinID91X-UW4 (note: this is not unique to this photo, it is unique to the specimen)

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