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Broken Guerrero, Mexico amethyst artificially repaired by Hydrothermal Solution Quartz

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Copyright © Jamison K. Brizendine
 
 
 
 
 
 
minID: JDY-151

Broken Guerrero, Mexico amethyst artificially repaired by Hydrothermal Solution Quartz

Copyright © Jamison K. Brizendine  - This image is copyrighted. Unauthorized reproduction prohibited.
Dimensions: 5 cm x 5 cm x 3.75 cm

This is a cabinet specimen of amethyst from Guerrero, Mexico and then altered by a hydrothermal silicon dioxide solution. This was the original state of the specimen: http://www.mindat.org/photo-614942.html . The “rehealing” was done by Vlad Klipov of Cleveland, Ohio.

Before the specimen was subjected to the autoclave, there were roughly seven crystals that probably were terminated. Most likely those crystals broke after the pocket was subjected to some tectonic force. One of the terminations later had secondary quartz crystal growth (lower front right). The quartz during the secondary quartz crystallization was clear as there was no iron to produce the amethyst color. Various smaller quartz crystals also grew during this secondary pulse of crystallization. One of the pre-requisites of trying to “regrow” quartz was that the specimen had to have as little matrix as possible as the matrix would have dissolved, and then those dissolved particles would have damaged the steel autoclave. This particular specimen had barely any matrix and therefore made a very good candidate to attempt the experiment. Another specimen was rejected for this process because it had too much matrix.

After five months of being in an alkaline aqueous solution at high temperatures and pressures (roughly 650 F [345 C] and 10,000 psi), all broken terminations were “regrown and re-healed”. These new growths were all clear points, because the silica solution in the autoclave was pure. Note that the purple color has quite diminished, but there is still a portion of the original color that remained. Any small crystals originally on the matrix were dissolved in the autoclave. You can see the contact between new and old crystal growths quite easily.

The biggest fear during the experiment was the dissolution of the entire amethyst cluster. The amethyst cluster was held together by a thin matrix of sandstone and smaller secondary quartz crystals. These crystals acted as a natural cement. In the autoclave the smaller crystals would have eventually dissolved over time (and did) and if the natural “cement” had dissolved, then the entire integrity of the cluster would have been broken. The cluster would have been a bunch of loose fragments in the autoclave had this occurred. Luckily, this did not occur and cluster remained intact. Note that this specimen has an “extra” front crystal, this was so it wouldn’t wobble in the autoclave.

This specimen was displayed at the 2015 Tucson Gem & Mineral Show with several other specimens that were grown by the hydrothermal silicon dioxide solution process. For more pictures of the display and this specimen, see this thread by Matt Zukowski (http://www.mineral-forum.com/message-board/viewtopic.php?t=4197) and this thread by Elise Skalwold (http://www.mineral-forum.com/message-board/viewtopic.php?t=4243). Both threads are on the Friends of Minerals forum.

This photo shows the specimen before and after for a quick comparison.

Before the specimen was altered the dimensions were approximately 5 x 5 x 3.7 cm
After the specimen was altered the dimensions are now approximately 9.1 x 8.8 x 6.6 cm

Jamison K. Brizendine specimen and photo

References cited:

Skalwold, E., 2015, Quartz, natural and synthetic: Mineral-forum.com, http://www.mineral-forum.com/message-board/viewtopic.php?t=4243

Zukowski, M., 2015, Tucson show 2015: Mineral-forum.com, http://www.mineral-forum.com/message-board/viewtopic.php?t=4197


This Photo was Mindat.org Photo of the Day - 8th Jan 2016

This photo has been shown 1379 times
Photo added:31st Dec 2015
Dimensions:2084x1048px (2.18 megapixels)

Data Identifiers

Mindat Photo ID:724266 📋 (quote this with any query about this photo)
Long-form Identifier:mindat:1:4:724266:0 📋
GUID:ca628fa1-bfb3-4cf1-8d6a-ab7f27b4c9c7 📋
Specimen MinIDJDY-151 (note: this is not unique to this photo, it is unique to the specimen)

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