Koenenite
A valid IMA mineral species - grandfathered
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About Koenenite
Formula:
Na4Mg9Al4Cl12(OH)22
Colour:
Colourless; tinted pale yellow to deep red due to included hematite. Reddish brown to colourless in transmitted light.
Lustre:
Pearly
Hardness:
1½
Specific Gravity:
1.82 - 2.08
Crystal System:
Trigonal
Name:
After Adolf von Koenen (21 March 1837, Potsdam – 5 May 1915, Göttingen), of Göttingen, geologist/paleontologist, who first identified the mineral.
This page provides mineralogical data about Koenenite.
Unique Identifiers
Mindat ID:
2306
Long-form identifier:
mindat:1:1:2306:7
GUID
(UUID V4):
(UUID V4):
c0e9c588-c919-446f-9f4f-d1656532a2c4
IMA Classification of Koenenite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1902
Type description reference:
Classification of Koenenite
3.BD.25
3 : HALIDES
B : Simple halides, with H2O
D : Simple halides with H2O and additional OH
3 : HALIDES
B : Simple halides, with H2O
D : Simple halides with H2O and additional OH
10.6.2.1
10 : OXYHALIDES AND HYDROXYHALIDES
6 : AmBn(O,OH)pXq
10 : OXYHALIDES AND HYDROXYHALIDES
6 : AmBn(O,OH)pXq
8.6.10
8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
6 : Halides of Al
8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
6 : Halides of Al
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Koe | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Koenenite
Pearly
Transparency:
Transparent, Translucent
Comment:
on cleavage surfaces
Colour:
Colourless; tinted pale yellow to deep red due to included hematite. Reddish brown to colourless in transmitted light.
Hardness:
1½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
On {0001}.
On {0001}.
Density:
1.82 - 2.08 g/cm3 (Measured) 1.82 g/cm3 (Calculated)
Optical Data of Koenenite
Type:
Uniaxial (+)
RI values:
nω = 1.520 nε = 1.550
2V:
Measured: 10°
Max Birefringence:
δ = 0.030
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Pleochroism:
Visible
Comments:
Dichroic: O = red-brown; E = colourless
Chemistry of Koenenite
Mindat Formula:
Na4Mg9Al4Cl12(OH)22
Crystallography of Koenenite
Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 4.072(2) Å, c = 32.64(2) Å
Ratio:
a:c = 1 : 8.016
Unit Cell V:
468.70 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Small crystals as crusts; very acute scalenohedra and rhombohedra; rosettes of intergrown tablets. Crystals indistinct.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0010653 | Koenenite | Allmann R, Lohse H N, Hellner E (1968) Die kristallstruktur des koenenits, eine doppelschichtstruktur mit zwei inkommensurablen teilgittern Zeitschrift fur Kristallographie 126 7-22 | 1968 | 0 | 293 | ||
0010654 | Koenenite | Allmann R, Lohse H N, Hellner E (1968) Die kristallstruktur des koenenits, eine doppelschichtstruktur mit zwei inkommensurablen teilgittern Zeitschrift fur Kristallographie 126 7-22 | 1968 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
11.7 Å | (very strong) |
10.7 Å | (very strong) |
1.924 Å | (very strong) |
1.522 Å | (very strong) |
5.45 Å | (strong) |
3.68 Å | (strong) |
3.34 Å | (strong) |
Comments:
Siegfried-Giesen mine, Germany.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
25 : Evaporites (prebiotic) |
Geological Setting:
marine evaporates
Type Occurrence of Koenenite
Reference:
Rinne, F. (1902) Koenenit. Centralblatt für Mineralogie, Geologie und Paläontologie: 1902: 493-499.
Synonyms of Koenenite
Other Language Names for Koenenite
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
3.BD.05 | Cadwaladerite | Al5(H2O)3(OH)12 · n(Cl,H2O) |
3.BD.15 | Korshunovskite | Mg2Cl(OH)3 · 4H2O |
3.BD.20 | Nepskoeite | Mg4Cl(OH)7 · 6H2O |
Other Information
Notes:
Decomposed by hot water or NH4Cl solution.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Koenenite
mindat.org URL:
https://www.mindat.org/min-2306.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Koenenite
Reference List:
Localities for Koenenite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Canada | |
| Kiihn (1968) +1 other reference |
China | |
| Dongsheng Hu (1995) |
| Jinding Liu and Qun Liu (1984) +1 other reference |
Germany | |
| Weiß (1990) |
| RRUFF ID: R060989 |
| Bode "Mineralien und Fundstellen BRD" ... +1 other reference |
| Emser Hefte 1990 (1) |
| Denise Bicknell collection |
| Dana 7:II:87. |
| Wittern (2001) |
| Palache et al. (1951) +1 other reference |
| Mertineit +1 other reference |
Wittern (2001) |
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Bergmannssegen potash mine, Lehrte, Hanover Region, Lower Saxony, Germany