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Henmilite

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Fuka mine, Bitchu-cho (Bicchu-cho), Takahashi City, Okayama Prefecture, Chugoku Region, Honshu Island, Japan
© Christian Rewitzer

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Formula:
Ca
 
2
Cu[B(OH)
 
4
]
 
2
(OH)
 
4
System:TriclinicHardness:1½ - 2
Name:Named for Professor Kitinosuke Henmi and his daughter Dr. Chiyoko Henmi,Department of Earth Science, Okayama University, in recognition of their work on skarn minerals from Fuka.
This page provides mineralogical data about Henmilite.

Classification of Henmilite

IMA status:Approved 1981
Strunz 8th edition ID:5/G.09-20
Nickel-Strunz 10th (pending) edition ID:6.AC.30

6 : BORATES
A : Monoborates
C : B(O,OH)4, without and with additional anions; 1(T), 1(T)+OH, etc
Dana 8th edition ID:26.1.5.1

26 : HYDRATED BORATES CONTAINING HYDROXYL OR HALOGEN
1 : Monoborates
Hey's CIM Ref.:9.3.25

9 : Borates
3 : Borates of Ca and Sr
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Type Occurrence of Henmilite

Type Locality:Fuka mine, Bitchu-cho (Bicchu-cho), Takahashi City, Okayama Prefecture, Chugoku Region, Honshu Island, Japan
Year of Discovery:1986

Physical Properties of Henmilite

Hardness (Mohs):1½ - 2

Crystallography of Henmilite

Crystal System:Triclinic
Cell Parameters:a = 5.76Å, b = 7.97Å, c = 5.64Å
α = 109.61°, β = 91.47°, γ = 83.68°
Ratio:a:b:c = 0.723 : 1 : 0.708
Unit Cell Volume:V 242.40 ų (Calculated from Unit Cell)

Optical Data of Henmilite

Type:Biaxial (-)
RI values: nα = 1.585 nβ = 1.608 nγ = 1.615
2V:Measured: 58° , Calculated: 56°
Maximum Birefringence:δ = 0.030

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:small

Chemical Properties of Henmilite

Formula:
Ca
 
2
Cu[B(OH)
 
4
]
 
2
(OH)
 
4
Essential elements:B, Ca, Cu, H, O
All elements listed in formula:B, Ca, Cu, H, O

Relationship of Henmilite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
6.AC.05Sinhalite
MgAl(BO
 
4
)
6.AC.10Pseudosinhalite
Mg
 
2
Al
 
3
(BO
 
3
)
 
2
(OH)O
 
3
6.AC.15Behierite
(Ta
5+
 
,Nb
5+
 
)(BO
 
4
)
6.AC.15Schiavinatoite
(Nb,Ta)(BO
 
4
)
6.AC.20Frolovite
Ca[B(OH)
 
4
]
 
2
6.AC.25Hexahydroborite
Ca[B(OH)
 
4
]
 
2
 · 6H
 
2
O
6.AC.35Bandylite
Cu[B(OH)
 
4
]Cl
6.AC.40Teepleite
Na
 
2
[B(OH)
 
4
]Cl
6.AC.45Moydite-(Y)
Y[B(OH)
 
4
](CO
 
3
)
6.AC.50Carboborite
Ca
 
2
Mg[B(OH)
 
4
]
 
2
(CO
 
3
)
 
2
 · 4H
 
2
O
6.AC.55Sulfoborite
Mg
 
3
[B(OH)
 
4
]
 
2
(SO
 
4
)(OH,F)
 
2
6.AC.60Lüneburgite
Mg
 
3
[B
 
2
(OH)
 
6
](PO
 
4
)
 
2
 · 6H
 
2
O
6.AC.65Seamanite
Mn
2+
3
[B(OH)
 
4
](PO
 
4
)(OH)
 
2
6.AC.70Cahnite
Ca
 
2
[B(OH)
 
4
](AsO
 
4
)
Related Minerals - Hey's Index Grouping:

- +
9.3.1Calciborite
Ca(B
 
2
O
 
4
)
9.3.2Sibirskite
Ca
 
2
(HB
 
2
O
 
5
)(OH)
9.3.3Fabianite
CaB
 
3
O
 
5
OH
9.3.4Uralborite
Ca
 
2
[B
 
3
O
 
3
(OH)
 
5
 · OB(OH)
 
3
]
9.3.5Vimsite
CaB
 
2
O
 
2
(OH)
 
4
9.3.6Olshanskyite
Ca
 
3
[B(OH)
 
4
]
 
4
(OH)
 
2
9.3.7Frolovite
Ca[B(OH)
 
4
]
 
2
9.3.8Korzhinskite
Ca(B
 
2
O
 
4
) · H
 
2
O
9.3.9Tyretskite
Ca
 
2
B
 
5
O
 
9
OH · H
 
2
O
9.3.10Nifontovite
Ca(B
 
2
O
 
4
) · 2.3H
 
2
O
9.3.12Inyoite
Ca(H
 
4
B
 
3
O
 
7
)(OH) · 4H
 
2
O
9.3.13Gowerite
Ca[B
 
5
O
 
8
(OH)][B(OH)
 
3
] · 3H
 
2
O
9.3.14Colemanite
Ca[B
 
3
O
 
4
(OH)
 
3
] · H
 
2
O
9.3.15Pentahydroborite
CaB
 
2
O(OH)
 
6
 · 2H
 
2
O
9.3.16Hexahydroborite
Ca[B(OH)
 
4
]
 
2
 · 6H
 
2
O
9.3.17Meyerhofferite
Ca
 
2
(H
 
3
B
 
3
O
 
7
)
 
2
 · 4H
 
2
O
9.3.18Priceite
Ca
 
2
B
 
5
O
 
7
(OH)
 
5
 · H
 
2
O
9.3.19Ginorite
Ca
 
2
B
 
14
O
 
23
 · 8H
 
2
O
9.3.20Probertite
NaCaB
 
5
O
 
7
(OH)
 
4
 · 3H
 
2
O
9.3.21Ulexite
NaCa[B
 
5
O
 
6
(OH)
 
6
] · 5H
 
2
O
9.3.22Hydroboracite
CaMg[B
 
3
O
 
4
(OH)
 
3
]
 
2
 · 3H
 
2
O
9.3.23Inderborite
CaMg(H
 
3
B
 
3
O
 
7
)
 
2
 · 8H
 
2
O
9.3.24Wardsmithite
Ca
 
5
Mg[B
 
4
O
 
7
]
 
6
 · 30H
 
2
O
9.3.26Strontioborite
SrB
 
8
O
 
11
(OH)
 
4
9.3.27Veatchite
Sr
 
2
B
 
11
O
 
16
(OH)
 
5
 · H
 
2
O
9.3.28Veatchite-A
Sr
 
2
B
 
11
O
 
16
(OH)
 
5
 · H
 
2
O
9.3.29 P-Veatchite
9.3.30 Balavinskite
Sr
 
2
B
 
6
O
 
11
 · 4H
 
2
O
9.3.31Tunellite
SrB
 
6
O
 
9
(OH)
 
2
 · 3H
 
2
O
9.3.32Strontioginorite
(Sr,Ca)
 
2
B
 
14
O
 
23
 · 8H
 
2
O

Other Names for Henmilite

Synonyms:
IMA1981-050
Other Languages:
German:Henmilit
Russian:Хенмилит
Spanish:Henmilita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Henmilite

Reference List:

- +
Nakai, I., Okada, H., Masutomi, K., Koyama, E. and Nagashima, K. (1986) Henmilite, Ca2Cu(OH)4[B(OH)4]2, a new mineral from Fuka, Okayama Prefecture, Japan. American Mineralogist, 71, 1234-1239.

Grew, E.S., and Anovitz, L.M. (1996) BORON: Mineralogy, Petrology and Geochemistry, second edition, as revised (2002).

Internet Links for Henmilite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Henmilite details from Handbook of Mineralogy (PDF)
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    • Localities for Henmilite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Japan
     
    • Honshu Island
      • Chugoku Region
        • Okayama Prefecture
          • Takahashi City
            • Bitchu-cho (Bicchu-cho)
    		American Mineralogist (1986): 71: 1234-1239; Mineralogical Record (1996): 27: 303.
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