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Natrozippeite

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Big Photo

Happy Jack Mine (Blue Dike Mine), Copper Point, White Canyon, White Canyon District, San Juan Co., Utah, USA
© Knut Eldjarn

Show Natrozippeite Photos (31)



Formula:
Na
 
5
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
5
(OH)
 
3
 · 12H
 
2
O
System:MonoclinicColour:Yellow to greenish ...
Hardness:5 - 5½
Member of:Zippeite Group
Name:Named in 1976 for its composition, with dominant sodium, and its relationship to Zippeite.
This page provides mineralogical data about Natrozippeite.

Classification of Natrozippeite

IMA status:Approved 1971
Strunz 8th edition ID:6/D.20-30
Nickel-Strunz 10th (pending) edition ID:7.EC.05

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
E : Uranyl sulfates
C : With medium-sized and large cations
Dana 7th edition ID:31.10.4.2
Dana 8th edition ID:31.10.4.2

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous
Hey's CIM Ref.:25.8.10

25 : Sulphates
8 : Sulphates of Sb, V, Cr and U
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Type Occurrence of Natrozippeite

Type Locality:Happy Jack Mine (Blue Dike Mine), Copper Point, White Canyon, White Canyon District, San Juan Co., Utah, USA
General Appearance of Type Material:velvety crusts of minute yellow masses and rare crystals
Year of Discovery:1971
Geological Setting of type material:Post-mine encrustation and/or supergene in origin.

Occurrences of Natrozippeite

Geological Setting:A secondary mineral of uranium mineral deposits, frequently if not most commonly as post-mine growths.

Physical Properties of Natrozippeite

Lustre:Dull, Earthy
Diaphaneity (Transparency):Translucent
Colour:Yellow to greenish yellow or yellowish green
Streak:yellow
Hardness (Mohs):5 - 5½
Cleavage:Perfect
Parallel to flattening of grains.
Fracture:Micaceous
Density (calculated):4.517 g/cm3

Crystallography of Natrozippeite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:P21/m {P1 1 21/m} {P21/m} {P1 21/m 1}
Space Group Setting:P21/m
Cell Parameters:a = 17.6425(11) Å, b = 14.6272(9) Å, c = 17.6922(11) Å
β = 104.461(1)°
Ratio:a:b:c = 1.206 : 1 : 1.21
Unit Cell Volume:V 4,421.01 ų (Calculated from Unit Cell)
Morphology:Found as earthy to velvety patches or crusts of earthy yellow mineral, rarely as micro-crystals.
Twinning:Reported as common, but no morphology given.
Comment:Pronounced pseudo-cells may be 5 x b
X-Ray Powder Diffraction:
d-spacingIntensity
7.34(100)
3.75(10)
3.66(50)
3.49(40)
3.15(40)
2.86(20)
2.12(10)
1.75(10)
Comments:Data collected on synthetic material

Optical Data of Natrozippeite

Type:Biaxial (-)
RI values: nα = 1.630 nβ = 1.690 nγ = 1.738
2V:Measured: 80° , Calculated: 80°
Birefringence:0.100-0.109
Maximum Birefringence:δ = 0.108

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:relatively strong
Pleochroism:Strong
Comments:Colorless to yellow

Chemical Properties of Natrozippeite

Formula:
Na
 
5
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
5
(OH)
 
3
 · 12H
 
2
O
Essential elements:H, Na, O, S, U
All elements listed in formula:H, Na, O, S, U

Relationship of Natrozippeite to other Species

Member of:Zippeite Group
Other Members of Group:

- +
Cobaltzippeite
Co(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
Magnesiozippeite
Mg(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
Nickelzippeite
Ni(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O (?)
Pseudojohannite
Cu
 
6.5
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
8
(OH)
 
5
 · 25H
 
2
O
Sejkoraite-(Y)
Y
 
2
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
6
(OH)
 
2
 · 26H
 
2
O
Zinczippeite
Zn(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
Zippeite
K
 
3
(UO
 
2
)
 
4
(SO
 
4
)
 
2
O
 
3
(OH) · 3H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
7.EC.05Cobaltzippeite
Co(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
7.EC.05Magnesiozippeite
Mg(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
7.EC.05Nickelzippeite
Ni(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O (?)
7.EC.05Zinczippeite
Zn(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
7.EC.05Zippeite
K
 
3
(UO
 
2
)
 
4
(SO
 
4
)
 
2
O
 
3
(OH) · 3H
 
2
O
7.EC.10Rabejacite
Ca(UO
 
2
)
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 6H
 
2
O
7.EC.15Marécottite
Mg
 
3
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
6
(OH)
 
2
 · 28H
 
2
O
7.EC.15Sejkoraite-(Y)
Y
 
2
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
6
(OH)
 
2
 · 26H
 
2
O
7.EC.20Pseudojohannite
Cu
 
6.5
(UO
 
2
)
 
8
(SO
 
4
)
 
4
O
 
8
(OH)
 
5
 · 25H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.8.1Klebelsbergite
(SbO)
 
4
(SO
 
4
)(OH)
 
2
25.8.2Coquandite
(SbO)
 
6
(SO
 
4
)O
 
2
 · H
 
2
O
25.8.3Peretaite
Ca(SbO)
 
4
(SO
 
4
)
 
2
(OH)
 
2
 · 2H
 
2
O
25.8.4Cannonite
Bi
 
2
(SO
 
4
)O(OH)
 
2
25.8.5Minasragrite
(V
4+
 
O)(SO
 
4
) · 5H
 
2
O
25.8.6Stanleyite
(V
4+
 
O)(SO
 
4
) · 6H
 
2
O
25.8.7Redingtonite
(Fe
2+
 
,Mg,Ni)(Cr,Al)
 
2
(SO
 
4
)
 
4
·22H
 
2
O
25.8.8Metauranopilite
(UO
 
2
)
 
6
(SO
 
4
)(OH)
 
10
 · 5H
 
2
O
25.8.9Uranopilite
(UO
 
2
)
 
6
(SO
 
4
)O
 
2
(OH)
 
6
 · 14H
 
2
O
25.8.11Zippeite
K
 
3
(UO
 
2
)
 
4
(SO
 
4
)
 
2
O
 
3
(OH) · 3H
 
2
O
25.8.12Johannite
Cu(UO
 
2
)
 
2
(SO
 
4
)
 
2
(OH)
 
2
 · 8H
 
2
O
25.8.13Magnesiozippeite
Mg(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O
25.8.14Zinczippeite
Zn(UO
 
2
)
 
2
(SO
 
4
)O
 
2
 · 3.5H
 
2
O

Other Names for Natrozippeite

Synonyms:
IMA1971-004Na ZippeiteSodium-Zippeite
Other Languages:
German:Na Zippeit
Russian:Натрийциппеит

Other Information

Fluorescence in UV light:Bright yellow in both SW and LW
Thermal Behaviour:Small amount of water (= 0.5 %) may be lost at 101 degrees C.
Health Warning:Naturally radioactive.

References for Natrozippeite

Reference List:

- +
Frondel Clifford, Ito, Jun, Honea. Russell M., and Weeks, Alice M., (1976), Mineralogy of the Zippeite Group, Canadian Mineralogist: 14: 429-436.

Gaines, Richard V., H. Catherine, W. Skinner, Eugene E. Foord, Brian Mason, Abraham Rosenzweig, Vandall King, (1997), Dana's New Mineralogy : The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana: 661.

Journal of the Czech Geological Society, Prague (1997): 42(4): 48.

Burns, P.C., Deely, K.M., and Hayden, L.A. (2003): The crystals chemistry of the Zippeite group. Canadian Mineralogist 41(3), 687-706.

Burns, P.C. (2005): U 6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. Canadian Mineralogist 43, 1839-1894.

Internet Links for Natrozippeite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Sodium-Zippeite details from Handbook of Mineralogy (PDF)
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    • Localities for Natrozippeite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • Mendoza
      • Malargüe Department
        • Pampa Amarilla District
    		Brodtkorb, M.K. de, Mineralogia y consideraciones geneticas del yacimiento Huemul. Provincia de Mendoza. Revista de la Asociacion Geologica Argentina 21 (3): 165-179. 1966
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
        • Příbram
          • Háje
    		Plášil, J. et al.: Supergenní mineralizace z haldy šachty č. 16 Příbram - Háje. Bulletin mineralogicko-petrografického oddělení Národního muzea v Praze, 2008, vol. 16, 1, 43-55.
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Jáchymov (St Joachimsthal) District
            • Jáchymov (St Joachimsthal)
    		Lapis 2002(7/8), 59
      • Plzeň Region
        • Nepomuk (Pomuk)
          • Kasejovice
    		Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES. MS Thesis, Notre Dame University.
      • Ústí Region
        • Krušné Hory Mts (Erzgebirge)
          • Dubí
    		Pauliš P., Kopecký S., Černý P. 2007: Uranové minerály České Republiky a jejich naleziště. 1. část. (Kutna Hora, issue 1)]
          • Krupka (Graupen)
    		Števko M., Bačík P., Ozdín D., Zeman M., Jonáš J., 2010: Výskyt schrockingeritu na fluoritovom ložisku Vrchoslav v Krušných horách (Česká republika). Bull. mineral.-petrolog. Odd. Nár. Muz.(Praha), 18, 2, 99-105.
    • Moravia (Mähren; Maehren)
      • Vysočina Region
        • Nové Město na Moravě
    		Pauliš P., Kopecký S., Černý P. 2007: Uranové minerály České Republiky a jejich naleziště. 1. část. (Kutna Hora, issue 1)
    Mineralienwelt 1993(1), 13
    Petr Pauliš, Stanislav Kopecký, Pavel Černý: Uranové minerály České republiky a jejich lokality 2007
    Petr Pauliš
    Petr Pauliš, Stanislav Kopecký, Pavel Černý: Uranové minerály České republiky a jejich lokality. (2007)
    France
     
    • Pays de Loire
      • Loire-Atlantique
        • Gétigné
    		J. Plášil, J. Hauser, V. Petříček, N. Meisser, S. J. Mills, R. Škoda, K. Fejfarová, J. Čejka, J. Sejkora, J. Hloušek, J.-M. Johannet, V. Machovič, and L. Lapčák (2012): Crystal structure and formula revision of deliensite, Fe[(UO2)2(SO4)2(OH)2](H2O)7. Mineralogical Magazine 76, 2837-2860.
    Germany
     
    • Saxony-Anhalt
    		Wittern: "Mineralfundorte in Deutschland", 2001
    • Saxony
      • Erzgebirge
        • Schwarzenberg District
          • Pöhla
    		Wittern: "Mineralfundorte in Deutschland", 2001
    Russia
     
    • Eastern-Siberian Region
      • Transbaikalia (Zabaykalye)
        • Chitinskaya Oblast'
          • Krasnokamensk
            • Strel'tsovskoe Mo-U ore field
    		P.M. Kartashov data
    Slovakia
     
    • Banská Bystrica Region
      • Banská Štiavnica Co.
    		Števko M., Sejkora J., Plášil J. (2012): Supergénna uránová mineralizácia na ložisku Banská Štiavnica (Slovenská republika). Bull. mineral.-petrolog. Odd. Nár. Muz. (Praha), 20, 1, 110-120 (in Slovak with English abstract).
    Spain
     
    • Catalonia
      • Lleida (Lérida)
        • El Pallars Jussà
          • La Torre de Cabdella
            • La Plana de Mont-ros
              • Castell-estaó
    		Joan Abella i Creus and Joan Viñals i Olià (2012) NUEVOS MINERALES DE LA “MINA EUREKA”: METAMUNIRITA, SCHRÖCKINGERITA, BOLTWOODITA Y GORDAITA, CASTELL-ESTAÓ, LA TORRE DE CABDELLA, LLEIDA, ESPAÑA. - http://mineralsabella.blogspot.com.es/2012/06/nuevos-minerales-de-la-mina-eureka.html
    UK
     
    • England
      • Cornwall
        • St Just District
          • St Just
            • Pendeen
    		[Golley & Williams, 1995, 57 - "Cornish Mineral Reference Manual"]
    USA
     
    • Arizona
      • Gila Co.
        • Sierra Ancha Mts
          • Sierra Ancha District
            • Asbestos Point (Asbestos Peak) area
              • Bull Canyon
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 375.
      • Yavapai Co.
        • Eureka District
          • Bagdad
            • Bozarth Mesa
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 313, 375; Frondel, C., et al (1976), Mineralogy of the zippeite group, Can.Min.: 14: 429-436;
    • Colorado
      • Gilpin Co.
    		Minerals of Colorado (1997) E.B. Eckels
      • Montrose Co.
    		Minerals of Colorado (1997) E.B. Eckels
    • Nevada
      • Lander Co.
        • Reese River District
    		Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University; Jensen, M. and J. Herrmann (2012) Uranium mineralization at the Apex Mine, Lander County, Nevada. Rocks and Minerals 87:270-276
    • New Mexico
      • McKinley Co.
    		Northrop, Minerals of New Mexico, 3rd Rev. Ed., 1996; Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University
          • Ambrosia Lake area
    		Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University
    • Utah
      • Emery Co.
        • San Rafael District (San Rafael Swell)
          • Delta
    		Rocks & Min.:57:249.; Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University
    Can Min 14:429-436
      • Grand Co.
        • Moab
    		Kim Gorall
        • Thompsons District (S. E. Thomsons)
          • Parco Mine Group
    		UGMS Bull 117 Minerals and Mineral Localities of Utah; Am Min 49:1511-1526; Am Min (1964) 49:1511-1526; Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University
    Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University
      • San Juan Co.
        • Cane Springs
    		Can Min 14:429-436
        • Green River District
    		Can Min 14:429-436
        • White Canyon District
          • Red Canyon
    		Collected by and in the collections of Brent Thorne, Joe Marty, and Mark Rushton.
          • White Canyon
            • Copper Point
    		Can Min 14:429-436; Bridget E. McCollam (2002) ZIPPEITES: CHEMICAL CHARACTERIZATION AND POWDER X-RAY DIFFRACTION STUDIES OF SYNTHETIC AND NATURAL SAMPLES MS Thesis, Notre Dame University
            • Deer Flat
    		Can Min 14:429-436
    Rick Dalrymple Collection
      • Wayne Co.
        • Fremont District
          • Fruita
    		Can Min 14:429-436
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