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Brownmillerite Subgroup

A group of related mineral species
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About Brownmillerite SubgroupHide

Recently defined as anion-deficient perovskites (Mitchell et al., 2017).


Unique IdentifiersHide

Mindat ID:
50243
Long-form identifier:
mindat:1:1:50243:4
GUID
(UUID V4):
792f64c8-80bc-4b15-a60a-ff8729403c80

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0003433BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003434BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003435BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003436BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003437BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003438BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003439BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003440BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003441BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003442BrownmilleriteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0017771BrownmilleriteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic0.0001293
0017772BrownmilleriteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic1.49293
0017773BrownmilleriteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic3.21293
0017774BrownmilleriteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic4.511293
0017775BrownmilleriteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic6.27293
0017776BrownmilleriteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic7.73293
0009418BrownmilleriteColville A A, Geller S (1971) The crystal structure of brownmillerite, Ca2FeAlO5 Acta Crystallographica B27 2311-23151971synthetic0293
0009431BrownmilleriteColville A, Geller S (1972) Crystal structures of Ca2Fe1.43Al0.57O5 and Ca2Fe1.28Al0.72O5 _cod_database_code 1000040 Acta Crystallographica B28 3196-32001972synthetic0293
0003425SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003426SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003427SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003428SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003429SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003430SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003431SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0003432SrebrodolskiteRedhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-4202004synthetic0293
0006826SrebrodolskiteKahlenberg V, Fischer R X (2000) Crystal growth and cation distribution in doped dicalcium ferrite Ca2(Fe1-xMex)2O5 (Me=Al,Ga) European Journal of Mineralogy 12 129-13520000293
0006827SrebrodolskiteKahlenberg V, Fischer R X (2000) Crystal growth and cation distribution in doped dicalcium ferrite Ca2(Fe1-xMex)2O5 (Me=Al,Ga) European Journal of Mineralogy 12 129-13520000293
0017759SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic0.0001293
0017760SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic2.249293
0017761SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic3.863293
0017762SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic5.564293
0017763SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic6.326293
0017764SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic8.167293
0017765SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic9.73293
0017766SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic0.0001293
0017767SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic2.015293
0017768SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic3.729293
0017769SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic6.267293
0017770SrebrodolskiteVanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-5042008synthetic8.89293
0016066SrebrodolskiteBertaut E, Blum P, Sagnieres A (1959) Structure du Ferrite Bicalcique et de la Brownmillerite _cod_database_code 1008124 Acta Crystallographica 12 149-15919590293
0016894SrebrodolskiteBertaut E, Blum P, Sagnieres A (1959) Structure du ferrite bicalcique et de la brownmillerite _cod_database_code 1009033 Acta Crystallographica 12 149-15919590293
0011930SrebrodolskiteBerggren J (1971) Refinement of the crystal structure of dicalcium ferrite, Ca2Fe2O5 Acta Chemica Scandinavica 25 3616-362419710293
0016653SrebrodolskiteBertaut F, Blum P, Sagnieres A (1957) La structure du ferrite dicalcique et de la Brownmillerite. _cod_database_code 1008777 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences 244 2944-294619570293
0016654SrebrodolskiteBertaut F, Blum P, Sagnieres A (1958) La structure du ferrite dicalcique et de la brownmillerite, aussi bien que 'Errata'. _cod_database_code 1008778 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences 246 658-65819580293
CIF Raw Data - click here to close

Relationship of Brownmillerite Subgroup to other SpeciesHide

Other Members of this group:
Auricupride SubgroupDefined as B-site vacant inverse single perovskites (so is the Cohenite Subgroup).
Cohenite SubgroupDefined as B-site vacant inverse single perovskites (so is the Auricupride Subgroup).
Diaboleite SubgroupDefined as B-site vacant double perovskites.
Hematophanite SubgroupDefined as anion-deficient partly-inverse B-site quadruple perovskites.
Liguowuite SubgroupDefined as A-site vacant single perovskites .
Macedonite SubgroupDefined as oxide single perovskites with second-order Jahn-Teller distortions.
Oskarssonite SubgroupDefined as B-site vacant single perovskites.
Schoenfliesite SubgroupM2+[Sn4+(OH)6]
Skutterudite SubgroupRedefined as A-site vacant quadruple perovskites.
Söhngeite SubgroupM(OH)3
Stottite SubgroupGroup of tetragonal metal hydroxides.
Group Members:
Brownmillerite Ca2(Al,Fe3+)2O5Orth. mm2
Nataliakulikite Ca4Ti2(Fe3+,Fe2+)(Si,Fe3+,Al)O11Orth. mmm (2/m 2/m 2/m) : Pnma
Sharyginite Ca3TiFe2O8Orth. mm2 : Pmc21
Shulamitite Ca3TiFe3+AlO8Orth. mmm (2/m 2/m 2/m) : Pmma
Srebrodolskite Ca2Fe3+2O5Orth. mmm (2/m 2/m 2/m) : Pnma

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Brownmillerite SubgroupHide

References for Brownmillerite SubgroupHide

Localities for Brownmillerite SubgroupHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Styria
    • Südoststeiermark District
      • Klöch
[Brownmillerite]
Canada
 
  • Québec
    • Nord-du-Québec
      • Kativik
[Srebrodolskite]
China
 
  • Xinjiang
    • Hami Prefecture (Kumul Prefecture; Qumul Prefecture)
      • Yizhou District
        • Huangshan-Jing'erquan ore belt
[Brownmillerite]
Czech Republic
 
  • South Moravian Region
    • Brno-Country District
      • Oslavany
[Brownmillerite]
  • Ústí nad Labem Region
    • Teplice District
      • Zabrušany
[Srebrodolskite]
France
 
  • Occitanie
    • Aveyron
      • Rodez
        • Sévérac-d'Aveyron
[Srebrodolskite]
Georgia
 
  • South Ossetia
    • Greater Caucasus Mountain Range
      • Kel’ volcanic area
        • Shadil-Khokh volcano
[Srebrodolskite]
Germany
 
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
[Brownmillerite]
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Mayen
[Brownmillerite]
[Brownmillerite]
[Brownmillerite]
in the collection of Chjristof SchäferIdentified by Christof Schäfer: Visual Identification, XRD, SEM-EDS, Raman Spectroscopy
[Brownmillerite]
      • Vordereifel
        • Ettringen
[Brownmillerite]
[Brownmillerite]
[Brownmillerite]
[Brownmillerite]
    • Vulkaneifel
      • Daun
        • Üdersdorf
[Brownmillerite]
      • Gerolstein
        • Hohenfels-Essingen
[Srebrodolskite]
  • Thuringia
    • Greiz District
      • Kauern
[Srebrodolskite]
[Srebrodolskite]
Hungary
 
  • Pest County
    • Szob District
      • Verőce
[Shulamitite]
Israel
 
  • Southern District (HaDarom District)
    • Arad
[Brownmillerite]
    • Tamar Regional Council
[Brownmillerite]
[Brownmillerite]
[Shulamitite]
[Brownmillerite]
Jordan
 
  • Amman Governorate
    • Transjordan Plateau
      • Daba-Siwaqa complex
[Brownmillerite]
        • Hashem region
          • Lisdan-Siwaga Fault
[Brownmillerite]
            • Siwaga
[Brownmillerite]
[Brownmillerite]
[Brownmillerite]
  • Irbid Governorate
    • Maqarin area
[Brownmillerite]
Middle East
 
[Brownmillerite]
Palestine
 
  • West Bank
    • Bethlehem Governorate
[Brownmillerite]
    • Jericho Governorate
[Brownmillerite]
    • Quds Governorate
[Brownmillerite]
[Brownmillerite]
Poland
 
  • Lesser Poland Voivodeship
    • Olkusz County
      • Gmina Bolesław
[Srebrodolskite]
  • Lower Silesian Voivodeship
    • Kłodzko County
      • Gmina Nowa Ruda
        • Przygórze
          • Bolesław Mine
[Srebrodolskite]
  • Silesian Voivodeship
    • Bytom
      • Bobrek
[Srebrodolskite]
    • Wodzisław County
      • Rydułtowy
        • ROW Ruch Rydułtowy Mine
[Srebrodolskite]
Romania
 
  • Brașov County
[Brownmillerite]
[Brownmillerite]
  • Covasna County
[Srebrodolskite]
Russia
 
[Sharyginite]
[Srebrodolskite]
[Srebrodolskite]
[Srebrodolskite]
[Srebrodolskite]
    • Korkinsky District
[Srebrodolskite]
  • Kabardino-Balkaria
    • Baksan Valley
[Srebrodolskite]
        • Lakargi Mountain
[Srebrodolskite]
[Srebrodolskite]
[Srebrodolskite]
Ukraine
 
[Sharyginite]
[Brownmillerite]
      • Kalinin coal mine
[Srebrodolskite]
USA
 
  • Wyoming
    • Campbell County
      • Reno Junction
[Srebrodolskite]
 
Mineral and/or Locality  
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