Brownmillerite Subgroup
A group of related mineral species
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About Brownmillerite Subgroup
Member of:
Recently defined as anion-deficient perovskites (Mitchell et al., 2017).
Unique Identifiers
Mindat ID:
50243
Long-form identifier:
mindat:1:1:50243:4
GUID
(UUID V4):
(UUID V4):
792f64c8-80bc-4b15-a60a-ff8729403c80
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0003433 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003434 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003435 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003436 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003437 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003438 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003439 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003440 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003441 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003442 | Brownmillerite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0017771 | Brownmillerite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 0.0001 | 293 | |
0017772 | Brownmillerite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 1.49 | 293 | |
0017773 | Brownmillerite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 3.21 | 293 | |
0017774 | Brownmillerite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 4.511 | 293 | |
0017775 | Brownmillerite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 6.27 | 293 | |
0017776 | Brownmillerite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 7.73 | 293 | |
0009418 | Brownmillerite | Colville A A, Geller S (1971) The crystal structure of brownmillerite, Ca2FeAlO5 Acta Crystallographica B27 2311-2315 | 1971 | synthetic | 0 | 293 | |
0009431 | Brownmillerite | Colville A, Geller S (1972) Crystal structures of Ca2Fe1.43Al0.57O5 and Ca2Fe1.28Al0.72O5 _cod_database_code 1000040 Acta Crystallographica B28 3196-3200 | 1972 | synthetic | 0 | 293 | |
0003425 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003426 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003427 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003428 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003429 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003430 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003431 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0003432 | Srebrodolskite | Redhammer G J, Tippelt G, Roth G, Amthauer G (2004) Structural variations in the brownmillerite series Ca2(Fe2-xAlx)O5: Single-crystal X-ray diffraction at 25 deg C and high temperature X-ray powder diffraction (25 C <= T <= 1000 C) American Mineralogist 89 405-420 | 2004 | synthetic | 0 | 293 | |
0006826 | Srebrodolskite | Kahlenberg V, Fischer R X (2000) Crystal growth and cation distribution in doped dicalcium ferrite Ca2(Fe1-xMex)2O5 (Me=Al,Ga) European Journal of Mineralogy 12 129-135 | 2000 | 0 | 293 | ||
0006827 | Srebrodolskite | Kahlenberg V, Fischer R X (2000) Crystal growth and cation distribution in doped dicalcium ferrite Ca2(Fe1-xMex)2O5 (Me=Al,Ga) European Journal of Mineralogy 12 129-135 | 2000 | 0 | 293 | ||
0017759 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 0.0001 | 293 | |
0017760 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 2.249 | 293 | |
0017761 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 3.863 | 293 | |
0017762 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 5.564 | 293 | |
0017763 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 6.326 | 293 | |
0017764 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 8.167 | 293 | |
0017765 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 9.73 | 293 | |
0017766 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 0.0001 | 293 | |
0017767 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 2.015 | 293 | |
0017768 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 3.729 | 293 | |
0017769 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 6.267 | 293 | |
0017770 | Srebrodolskite | Vanpeteghem C B, Angel R J, Zhao J, Ross N L, Redhammer G J, Seifert F (2008) The effect of oxygen vacancies and aluminium substitution on the high-pressure properties of brownmillerite-structured Ca2Fe2-xAlxO5 Physics and Chemistry of Minerals 35 493-504 | 2008 | synthetic | 8.89 | 293 | |
0016066 | Srebrodolskite | Bertaut E, Blum P, Sagnieres A (1959) Structure du Ferrite Bicalcique et de la Brownmillerite _cod_database_code 1008124 Acta Crystallographica 12 149-159 | 1959 | 0 | 293 | ||
0016894 | Srebrodolskite | Bertaut E, Blum P, Sagnieres A (1959) Structure du ferrite bicalcique et de la brownmillerite _cod_database_code 1009033 Acta Crystallographica 12 149-159 | 1959 | 0 | 293 | ||
0011930 | Srebrodolskite | Berggren J (1971) Refinement of the crystal structure of dicalcium ferrite, Ca2Fe2O5 Acta Chemica Scandinavica 25 3616-3624 | 1971 | 0 | 293 | ||
0016653 | Srebrodolskite | Bertaut F, Blum P, Sagnieres A (1957) La structure du ferrite dicalcique et de la Brownmillerite. _cod_database_code 1008777 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences 244 2944-2946 | 1957 | 0 | 293 | ||
0016654 | Srebrodolskite | Bertaut F, Blum P, Sagnieres A (1958) La structure du ferrite dicalcique et de la brownmillerite, aussi bien que 'Errata'. _cod_database_code 1008778 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences 246 658-658 | 1958 | 0 | 293 |
CIF Raw Data - click here to close
Relationship of Brownmillerite Subgroup to other Species
Member of:
Other Members of this group:
Auricupride Subgroup | Defined as B-site vacant inverse single perovskites (so is the Cohenite Subgroup). | |
Cohenite Subgroup | Defined as B-site vacant inverse single perovskites (so is the Auricupride Subgroup). | |
Diaboleite Subgroup | Defined as B-site vacant double perovskites. | |
Hematophanite Subgroup | Defined as anion-deficient partly-inverse B-site quadruple perovskites. | |
Liguowuite Subgroup | Defined as A-site vacant single perovskites . | |
Macedonite Subgroup | Defined as oxide single perovskites with second-order Jahn-Teller distortions. | |
Oskarssonite Subgroup | Defined as B-site vacant single perovskites. | |
Schoenfliesite Subgroup | M2+[Sn4+(OH)6] | |
Skutterudite Subgroup | Redefined as A-site vacant quadruple perovskites. | |
Söhngeite Subgroup | M(OH)3 | |
Stottite Subgroup | Group of tetragonal metal hydroxides. |
Group Members:
Brownmillerite | Ca2(Al,Fe3+)2O5 | Orth. mm2 |
Nataliakulikite | Ca4Ti2(Fe3+,Fe2+)(Si,Fe3+,Al)O11 | Orth. mmm (2/m 2/m 2/m) : Pnma |
Sharyginite | Ca3TiFe2O8 | Orth. mm2 : Pmc21 |
Shulamitite | Ca3TiFe3+AlO8 | Orth. mmm (2/m 2/m 2/m) : Pmma |
Srebrodolskite | Ca2Fe3+2O5 | Orth. mmm (2/m 2/m 2/m) : Pnma |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Brownmillerite Subgroup
mindat.org URL:
https://www.mindat.org/min-50243.html
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References for Brownmillerite Subgroup
Localities for Brownmillerite Subgroup
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Feuerberg, Hohenfels-Essingen, Gerolstein, Vulkaneifel, Rhineland-Palatinate, Germany