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Techniques for CollectorsBest Way to Clean Aragonite/Calcite

21st Aug 2018 16:02 UTCScott Rider

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I found a good vein of aragonite and calcite over the weekend on a club field trip. We went to the Crystal Hill district, and I found dozens upon dozens of clusters of both of these minerals. Some even are part calcite, part aragonite in the same crystal!! Anyway, since the specimens were found close to the surface, many have the manganese dirt coating some of the aragonite. The calcite seems more robust and cleaning the dirt off those is easy. However, the aragonite is a different story. Those do not clean readily.


What would be the best way to go about cleaning the dirt off? I was thinking oxalic acid probably would work. I was told that would not affect calcite, so I assume it wouldn't harm the aragonite either? Anyone have any better ideas? Or is oxalic the way to go?


Side note: I can't really experiment yet, I am in the middle of selling my house (closes today!) and moving into my new home on Sept 22nd. But I figured I'd ask now and be ready when I move... Below are some of the finds:



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21st Aug 2018 16:31 UTCBob Harman

SCOTT,

Congratulations and good luck with your move. And nice find!


I have cleaned many Indiana aragonite specimens. First of all start with one of your lower end examples as a way of experimenting.


I thought oxalic acid (sold as wood bleach) was most useful in removing iron staining. If so, I don't see much staining so, I think, its use is ?????. But maybe I am wrong, if anyone has other ideas please post them.

I would clean your specimen by soaking an hour or so in water, then VERY BRIEFLY (4-5 seconds!) swoosh the specimen thru dilute vinegar. Follow with a good rinse. This way, you might be surprised how clean aragonite can get without any acid damage at all. If you have a hi pressure cleaning gun VERY GENTLY use the spray after soaking instead of or after the vinegar soak. CHEERS.......BOB

21st Aug 2018 17:07 UTCScott Rider

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Thanks Bob for the suggestions, I'm very excited that I've finally sold the house and moving on to the next chapter of my life!! Going prospecting/mining has kept me sane during this process, as selling and buying homes is not fun...


As for the specimens, I shall attempt to soak a few of the smaller specimens in warm water/soap, and then trying the vinegar solution as well. I have used vinegar in the past, but for much longer than you suggest. I think that is a good idea to do a short exposure, then rinse, and then probably repeat if there is some dirt. The majority of the dirt cleans off just by rinsing in water with no soap. But what is left isn't as easy to remove.


I have pieces up to about a foot long, so I'll have to experiment with the lighter and lower end ones first. I prefer not using acids unless its absolutely necessary as I would like to retain the luster. However, I have had luck removing clay and organic dirt from specimens with oxalic acid from my pegmatite finds. That is why I was thinking that may work, but I fear it'll kill the luster of the crystals so I'll let my friend try that solution out first. I don't think the dirt is organic in origin though, but the dirt is heavy with manganese oxides (and probably iron oxides as well). But, I am unfamiliar with how oxalic acid works with manganese oxides.


I was also thinking about an ultrasonic cleaner (not just for these but for future finds as well). Any suggestions on a good one that doesn't break the bank!


Here are two of the larger specimens. The larger one is in excellent condition, however, its nearly impossible to tell as its coated with that dirt, but it also seems to have some botryoidal material over some of the terminations that doesn't resemble the dirt that is all over the rest of the specimen. Perhaps that is some manganese oxide mineral (like pyrolusite):



Close up of the better one:
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21st Aug 2018 17:35 UTCSusan Robinson

Do not use oxalic acid on any calcite or aragonite specimens. It forms calcium oxalate which re-deposits itself on the specimens as a white coating, which is difficult, if not impossible, to remove.

21st Aug 2018 18:48 UTCThomas Lühr Expert

Scott


Follow Susan's advice. Oxalic acid will ruin your calcite for sure.

Calcite/Aragonite is chemically very sensible, especially to any kind of acids.

Before using hard chemicals soak it for a few days in a solution of washing powder and then give it a treatment with a high pressure water gun (at the next petrol station / car wash). A plastic box will prevent that the specimens are blown away.

I have alse heared that other collectors had success with a treatment in the dish washer ... while their wifes were absent ;))


Iron Out respectively Waller's solution is semisafe in use to remove rust or weaken clay. A short treatment for a few hours will not do much harm to the calcite, but a long treatment (overnight or longer) will dertroy the luster.


Good luck

Thomas

21st Aug 2018 19:06 UTCScott Rider

Susan and Thomas, thank you for saving me some time and frustration!! I'd only experiment on a couple crappy specimens I saved just for this purpose! So, now I can try other things on those instead! I think I'll stay away from using acids just in general on these specimens. And I've been thinking about a ultrasonic cleaner for some time now, and I think once I'm in my new house I'll buy one of those. Any suggestions for a good one for around $100-200?


For now, I'm storing these guys up until I move next month!! In the meantime, I should build a shed there LOL!!!
 
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