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Mineralogical ClassificationCrystal structure of chlorinated mineral of cancrinite group with bystrite-type framework

7th Sep 2017 10:08 UTCMarco E. Ciriotti Manager

Referenza:

▪ Kaneva, E.V., Sapozhnikov, A.N., Suvorova, L.F. (2017): Crystal Structure of Chlorinated Mineral of Cancrinite Group with Bystrite-Type Framework. Crystallography Reports, 62, 558-565.


Abstract:

The formula of chlorinated bystrite (rare mineral of cancrinite group) has been refined to Na7.22Ca0.92[Al6Si6O24](S5)0.94Cl1.01. The X-ray diffraction data on the contents of chlorine and sulfur in this mineral are confirmed by the results of chemical analysis. The bystrite cage is found to contain a (S5)2– cluster, which is elongated along the c axis and has a chain configuration. Different ways of aggregation of sulfur atoms lead to cis- and trans-configurations of chains. Columns of cancrinite cages contain –Ca–Cl–Ca–Cl– chains, which were observed previously in the structures of minerals of davyne subgroup, afghanite, and tounkite.
 
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