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Identity HelpSmithsonite

10th Sep 2013 19:29 UTCA. A. Faller

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I have a specimen from the "Tsumeb" that has tiny (up to 5.75 mm),clear colorless (non-fluorescing) crystals labeled Calcite. Given their similar crystal symmetry, how do I know these aren't Smithsonite? Given my difficulty applying a hardness test on such small crystals (they just cleave), I applied a drop or two of HCL, both to surrounding (uncrystallized), fluorescing Calcite matrix, and directly to a crystal in question.

If Calcite effervesces vigorously in HCL, and Smithsonite less so vigorously, would the crystal face need to be tested, as opposed to a cleavage surface? Should I remove a crystal and drop it in HCL, doing the same with "matrix", and comparing the results? Do you think it matters, given the unattractive nature of the overall specimen??? I also wonder if there is a practical "Zinc" test? Thanks for indulging me...

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10th Sep 2013 20:25 UTCLefteris Rantos Expert

Aside of any practical tests, the xls could also be Dolomite, as well as intermediate members of several series of simple or double rhombohedral carbonates (Zn-rich Calcite, Pb-rich Calcite, Zn-rich Dolomite and even some other more exotic beasts...)


So ID may not be easy, or at least not unambiguous, without EDS.

11th Sep 2013 04:22 UTCA. A. Faller

Thanks for those points. Would I at least be able to rule out Dolomite with the response these crystals show in cold, dilute HCL?

11th Sep 2013 21:09 UTCLefteris Rantos Expert

Both Smithsonite and Dolomite do not react strongly in cold HCl. Only a relatively pure Calcite will

11th Sep 2013 21:11 UTCA. A. Faller

Good enough. I think I have calcite, then. Thanks for your help...
 
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