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EducationShipping radioactive minerals
29th Mar 2017 20:37 UTCReiner Mielke Expert
29th Mar 2017 20:54 UTCWayne Corwin
How little is too much now? ? ?
29th Mar 2017 21:49 UTCMatt Neuzil Expert
29th Mar 2017 22:19 UTCRudy Bolona Expert
29th Mar 2017 23:48 UTCMatt Neuzil Expert
30th Mar 2017 00:22 UTCReiner Mielke Expert
30th Mar 2017 01:38 UTCDoug Daniels
30th Mar 2017 03:13 UTCRudy Bolona Expert
30th Mar 2017 03:33 UTCAlfredo Petrov Manager
30th Mar 2017 05:08 UTCDoug Daniels
30th Mar 2017 05:30 UTCDana Slaughter 🌟 Expert
30th Mar 2017 10:04 UTCReiner Mielke Expert
Hello Doug,
Yes that is the irony of it all and in effect means you cannot ship anything that is radioactive across a border where radiation detectors are used. However I suppose you could ship it to a lab in your own country because it is safe to do that. However shipping the same thing across a border makes it unsafe. It is all just irrational fear and it makes everyone feel safer to have these restrictions. Politically it also good because most voters are fearful of anything radioactive unless it is safely in the hands of power companies where nothing ever goes wrong. Of course it is perfectly safe for people to have guns since they are not dangerous like deadly radioactive minerals. LOL
30th Mar 2017 11:02 UTCJohan Kjellman Expert
Reiner Mielke Wrote:
-------------------------------------------------------
> the critical factor is no longer the level of
> radiation at the surface of the parcel but the
> isotopic makeup of the mineral.
Does this mean that they let minerals with the right isotopic makeup continue to the adressee?
I vaguely recall a story from Alfredo that he was waved through a Canada/US check-up with the car full of radioactive Bancroft (?) material, since it didn't register as a threath from an isotopic point of view.
cheers
30th Mar 2017 11:27 UTCPaul De Bondt Manager
The price of fear.
30th Mar 2017 12:29 UTCJolyon Ralph Founder
I guess things are just going to end up being "lost" more frequently.
30th Mar 2017 13:49 UTCPeter Trebilcock Expert
One of the packages was intercepted at Swindon distribution centre, the other in London, which is quite a long return trip from Cornwall to collect a small package.
Withholding your senders name on the parcel will not work and you will still be caught or have the package destroyed especially if bought through an auction site.
The senders names are witheld to save embarrassment.
30th Mar 2017 13:58 UTCHarold Moritz 🌟 Expert
For artificial isotopic mixes you have to go through the detailed analysis and complex formula alluded to by Reiner, which is not necessary for natural stuff. Really only labs, hospitals, the gubmint or folks working in nuclear power would be involved in using that stuff.
I cant say what the rules are for other countries, but they likely have a similar document.
30th Mar 2017 14:36 UTCReiner Mielke Expert
In Feb.2015 I investigated this in detail. The USPS website says that for U and Th bearing minerals anything more than 1000 Bq is considered radioactive. For uraninite that means more than 0.007gms and thorianite more than 0.26 grams. Lets assume you have some uraninite in a 10cm diameter box, so as such the distance to the centre ( assuming a point source) would be 5cm. Using this calculator http://www.radprocalculator.com/Gamma.aspx and assuming a 1000Bq source should give you a reading at the surface of the box of 0.005 mR/hr. In otherwords if you have a reading greater than 0.005 mR/hr the box would be considered radioactive and could not be mailed. That is fine except that an empty box measures 0.015 mR/hr! which is background here. So in effect I have no way of measuring if a parcel would be rejected or not since I cannot distinguish U and Th from K or C. My conclusion was that one cannot mail anything by air that is radioactive period, unless you can accurately determine that the mass of the U and Th in the sample generates less than a total of 1000 Bq. ( good luck with that one LOL)
Surface mail is another matter and much easier to figure out, you just need the proper labelling and packing, and the surface of the parcel cannot exceed 0.5 mR/Hr. The only catch is you have to send it by first class registered mail which is more expensive than normal.
30th Mar 2017 14:41 UTCReiner Mielke Expert
> radiation at the surface of the parcel but the
> isotopic makeup of the mineral.
As far as I know that currently only applies to parcels sent by UPS and Purolator. I was told this by their radiation consultant after they seized my parcel destined for Germany at the Canadian border.
30th Mar 2017 14:47 UTCAndrew Debnam 🌟
30th Mar 2017 14:50 UTCReiner Mielke Expert
30th Mar 2017 14:57 UTCAndrew Debnam 🌟
30th Mar 2017 15:08 UTCHarold Moritz 🌟 Expert
Getting the exterior of a parcel with a hand sample or smaller of U ore in the middle to below the USPS domestic 0.5 mR/Hr threshold is not that difficult, just get a big enough outer box (distance is better than shielding). There are no USPS restrictions on the size or mass of a natural sample and you dont have to characterize the isotopes. What mainly matters for natural samples is the reading outside the outer box.
Private shippers have their own rules and I suspect because of all the various international border rules and paperwork they have to deal with they just no longer want to take on the costs of dealing with transporting rad material. It is likely very time consuming and a very, very small portion of their revenue.
30th Mar 2017 16:35 UTCPavel Kartashov Manager
"The problem was discussed on mindat many times but only qualitatively, on fingers. It seems to me, that experimental quantitative data would be interesting for evrybody.
This is naturexperiment:
specimen - 4x2.5x1.7 cm 52 g natural pseudomorphose of gummite after uraninite xl from Karelia
natural radioactivity on the table 25 µR/h
A - experiments on air - specimen is covered by newspaper and polyethilen (2-3 layer of both):
tightly to detector 2283 µR/h (butt 2.5x1.7=4.2 cm2) - 4253 µR/h (side 4x2.5=10 cm2)
3 cm from detector 1225 µR/h butt - 1814 µR/h side
30 cm from detector 60 µR/h butt - 83 µR/h side
B - specimen deposited in the lead tube container with 16 mm walls - 536 µR/h butt - 858 µR/h side (tightly to detector)
the same but container in outer foam plastic cover with 16 mm walls - 277 µR/h butt - 494 µR/h side.
Weight of the lead container itself is 2700 g, with foam plastic cover - 2750 g. Size of the ready-mounted container is : l -16 cm, d- 9.5 cm.
Compare sizes and weights of the specimen and the container with radioactivity data..
Who will send 2800 g instead of 52 g? If it will stoped on any custom because of massive piece of lead for begining..."
30th Mar 2017 17:56 UTCReiner Mielke Expert
Thank you for the detailed analysis. I like your specimen and your table cover with the pretty flowers. The table cover is just like the one my late grandmother used to have. Sure brings back good memories.
30th Mar 2017 18:19 UTCRudy Bolona Expert
30th Mar 2017 19:30 UTCPavel Kartashov Manager
30th Mar 2017 21:26 UTCFred E. Davis
30th Mar 2017 21:56 UTCPavel Kartashov Manager
31st Mar 2017 07:10 UTCJoel Dyer
It seems that so much concentration, effort and resources are spent on meaningless matters, and the big, important questions for humanity remain unsolved. Not sure to cry or laugh at all the nonsense in regulations, politics etc....tragicomedy??
Cheers,
Joel
31st Mar 2017 08:49 UTCPaul De Bondt Manager
We created rules to rule rules. ( gnarfing smiley )
31st Mar 2017 19:03 UTCŁukasz Kruszewski Expert
31st Mar 2017 23:24 UTCReiner Mielke Expert
31st Mar 2017 23:39 UTCAlfredo Petrov Manager
1st Apr 2017 01:40 UTCMatt Neuzil Expert
1st Apr 2017 05:37 UTCFrank de Wit Manager
-------------------------------------------------------
> Just to put this discussion in perspective, there was a dispute back in the 1930s about whether one could legally mail limburger cheese in the U.S,,
> with one postmaster considering it "hazardous" and another merely "offensive".
Limburger cheese (Rommedoe) is offensive.
But French Époisses is hazarous...
When you open a package of Époisses, small birds drop dead from the roof!
1st Apr 2017 12:29 UTCReiner Mielke Expert
Frank, how is it in the Netherland?
1st Apr 2017 14:19 UTCAlysson Rowan Expert
Any radioactive material?
That's anything containing potassium (including bananas), vanadium (including your spanners), REEs (including the cold cathode tubes in your laptop - and thet have mercury, too!), tritium & promethium (anything luminised), lumps of Cornish granite (U, Th and all of the daughter products) and so on. Oh, and anything living or recently dead contains Carbon-14.
Don't let's get into the contamination that began with the first atomic test, either.
Seriously, though - the only stuff that we (as collectors) should ever want to send that is detectably radioactive are uranium and thorium minerals.
The isotopic makeup is easy to list - but you have to assume up to 10% thorium in a uranium mineral and up to 10% uranium in a thorium mineral, and you can list the isotopic make up from the book.
I suppose that I'm going to have to produce a table of isotopic make-up for all known radioactive minerals as another supplement to Here be Dragons. Feh!
Here be Dragons : The Care and Feeding of Radioactive Mineral Species
The new edition (Feb 2017) is right here:- Alysson Rowan's Published Papers and Stuff
Oh, and for all legal purposes, anything containing less than 35kBq radioisotopes is considered non-radioactive here in the UK. (That's about 28kg bananas, if I remember right).
1st Apr 2017 17:51 UTCŁukasz Kruszewski Expert
1st Apr 2017 19:57 UTCAlysson Rowan Expert
2nd Apr 2017 01:55 UTCReiner Mielke Expert
2nd Apr 2017 03:22 UTCDoug Daniels
2nd Apr 2017 11:42 UTCReiner Mielke Expert
I suppose it is the decay products that they are worried about. K decays to Ar and Ca. Uranium and Thorium to Pb,Th,Ra,Rn,Po etc. It couldn't be the radioactivity itself since the same level of radioactivity from K is just as dangerous as U and Th. Besides if K radioactivity where treated the same it would be too unpopular since people are naturally radioactive due to K.
2nd Apr 2017 12:09 UTCAlysson Rowan Expert
Anything that falls outside of the acceptable total dose (too radioactive to ship) or acceptable nuclides (that 35kg of bananas or a shipment of luminous watches) will be quarantined. They are actually looking for fissionable materials (Pu239 and Uranium), but are unable to tell the difference (because they don't understand that there is a difference) between weapons grade concentrate and a lump of uraninite. They are also looking for radiographic sources (which they shouldn't be shipping in any case).
To be fair - they have put together a set of rules that any of their least bright employees can follow without having to refer to a big book of what can be shipped (and which requires an understanding of health physics and use of expensive instruments to interpret and apply).
Of course, radiation leaks from a perfectly well sealed package in a way that toxic chemicals don't - and so folks get really, really worried by it - for the simple reason that they don't understand it.
2nd Apr 2017 12:37 UTCReiner Mielke Expert
2nd Apr 2017 12:57 UTCJohan Kjellman Expert
2nd Apr 2017 13:01 UTCReiner Mielke Expert
2nd Apr 2017 13:11 UTCReiner Mielke Expert
Interesting philosophical question. I think maybe it would be better is to say it takes indifferent and selfish people to make up a world run by fear- and profit enabled by ignorant people.
2nd Apr 2017 14:28 UTCPavel Kartashov Manager
They should to measure not simply gamma-rays total dose, but specific energies of gamma-ray connected with individual isotopes.
2nd Apr 2017 14:49 UTCReiner Mielke Expert
Do terrorists actually ship radioactives through the mail? I have never heard of such a case and I am sure we would if that happened. Such news would be welcomed by politicians since it would increase fear and people in fear are easier to control. It would be a win win for the politicans and manufactures if this was reported so I think this has never happened.
"They should to measure not simply gamma-rays total dose, but specific energies of gamma-ray connected with individual isotopes."
Some check points do this including UPS and Purolator. Many do not because it requires more expensive equipment and more knowledge. The problem apparently is that such measurements are not quantitative and so according to the UPS consultant they cannot assess whether or not the material can be shipped, thus the requirement to have quantitative isotopic analysis provided by the shipper.
2nd Apr 2017 16:03 UTCHarold Moritz 🌟 Expert
Correct me if I am off, but isnt the best way to detect high grade material by looking for neutron flux? This flux is immaterial for natural samples, but it is what makes the high grade stuff actually useful. And it is very penetrative so it's easy to read through cars, trucks, containers and ship hulls as they pass by, no? (I'm falling back on my admittedly dated rad worker training from my nuke plant decommissioning days).
"If it wasn't for the stuff we were trying to ship around there would be nothing for them to detect..." I know you are having fun with this Reiner, but there are probably a lot more medical radioisotope shipments than minerals. These have very short half-lives and must be constantly replenished and shipped right away to hospitals all over the continent. I believe they are made in a Canadian reactor (the US had one too, but it became a victim of budget cuts I believe), so somehow that stuff makes it across the border. There are also the sources in portable x-ray fluorescence detectors, which are commonly rented and thus shipped all over.
2nd Apr 2017 16:41 UTCReiner Mielke Expert
Natural radioactive decay does not produce neutrons only alpha, beta and gamma rays.
Medical and other isotopes as such have been going across the border long before they started installing radiation detectors everywhere. So that cannot be the reason why they have. My point is that this is a waist of time and money as no one has ever died frorm radioactive mineral specimens and no one has ever shipped radioactive material through the mail for use in terrorist activity that anyone knows of. The risks of this happening are miniscule and the presumed danger associated with the shipping of radioactives are unproven and unsubstantiated. I know of no other thing that has received so much attention where no clear danger exists. Boggles the mind. They would be far better off investing that money in finding a defense against asteroids which are a proven danger.
2nd Apr 2017 17:02 UTCMatt Neuzil Expert
2nd Apr 2017 17:07 UTCReiner Mielke Expert
2nd Apr 2017 17:11 UTCHarold Moritz 🌟 Expert
Perhaps, as I just posted on the toxic minerals discussion, because nearly all adverse exposure is occupational, the main reason for all this is an increase in the protection of the employees who are potentially handling these packages daily, and because of "right to know" laws in occupational settings (hence the creation of things like MSDS sheets for chemicals in the workplace, etc.), and placarding on vehicles, air transport packaging rules, etc., etc. Then you have litigation if an employee claims illness due to exposure that the employer may have caused. While very difficult to prove either way (for one particular person), the cost of the litigation and potential settlements is enough to warrant safeguards, which due to advice from attorneys, is typically extremely conservative. When it comes to the legal arena, much like the political or security ones, there is no such thing as "no clear danger". Somehow the perceived risk (perhaps on top of increased security mandates) has offset the potential for profit in these matters. And it is much easier (and less risky) to train employees to simply say "no" than to give them the complex rad worker training to make informed decisions or mitigate unrealistic fears. In the end they are private companies that can choose to not ship whatever they want for whatever reason, it's their business...
2nd Apr 2017 17:16 UTCAlysson Rowan Expert
You require quite a significant lump to produce a detectably elevated neutron flux - a couple of sheets of enriched uranium foil will produce detectable beta-gamma, but neutrons will be too few to find easily from outside a vehicle. A paperback-sized slab of enriched uranium will probably be detectable with a good BF3 detector - if you are close enough. The problem with N0 detection is a combination of inverse-square law and neutron scattering.
These companies are looking for a quick, inexpensive detection method - and neutron detectors don't come cheap - plus, they won't detect anything else.
I think I'd like to know if someone were shipping a few Curies of polonium using my parcel service - and that is an extremely handy material for those terrorists. More than 14kg of enriched uranium, in fact (unless they are planning on building a sundog - a quick and dirty reactor designed to irradiate rather than detonate).
Reiner,
What's wrong with an umberella as a defence against asteroids? *silly grin*
Matt,
More likely the metal, if they can get it.
2nd Apr 2017 17:23 UTCAlysson Rowan Expert
Getting a shipping company licenced to carry radioactive materials is expensive. For some materials, licencing is more expensive than for others.
Securicor, here in the UK, was the only courier licenced to ship radioactive sources by road. I used them once. Only once. The source was on a 24hrs shipment, never arrived and was returned to us 3 months later in a severely damaged condition. They billed us £1500 for the service. (I wish to heck that I'd just driven the source to Aberdeen myself).
I don't know if we have ANY licenced carriers, now.
2nd Apr 2017 17:24 UTCReiner Mielke Expert
2nd Apr 2017 17:49 UTCHarold Moritz 🌟 Expert
2nd Apr 2017 17:56 UTCAlysson Rowan Expert
If you take an enriched uranium foil onto an operating reactor site, it will start to produce a few more neutrons, purely because of the ambient thermal neutron flux around that reactor - and this was once the basis of a criticality detector system.
16th Apr 2017 00:44 UTCBrian Eisemann
16th Apr 2017 09:58 UTCAlysson Rowan Expert
It shouldn't be an issue but you'd best avoid United Airlines - they don't even need an excuse to drag you off the plane. ;)
Seriously: If you can point to a properly contained mineral specimen that is in a spaced packaging (with the bill of sale and such like), then security have no cause top complain.
On the other hand, you could do the other thing and hire a car - stopping off at all of those other mineral sites on the umpteen-thousand mile drive home.
16th Apr 2017 12:42 UTCAlan Barnes (2)
To respond to Brian's question, although I haven't done it myself, I have heard of several groups of people travelling back from St Marie (albeit a few years ago now) being stopped by Customs at Dover and questioned about the radioactivity emanating from their vehicle. After answering the questions to Custom's satisfaction the groups were allowed on their way (with specimens). Unless the rules have changed now, in the UK you are legally allowed to own 5Kg of unprocessed uranium minerals..........but who's gonna know?
Alan
16th Apr 2017 13:28 UTCAlysson Rowan Expert
If each specimen is less than 35kBq, (micros and many thumbnails), then they are not individually (legally) radioactive.
As soon, however, as you trim, cut, polish or otherwise modify the chunk of rock they are on, then technically (assuming they are over the 35kBq de minimus), they are no longer natural material and are processed radioactive materials, and are immediately in a completely different category.
Strangely and uncharacteristically for UK law, there are clauses that suggest that reasonable and practicable application be made of the regulations, so long as the rule of taking all precautions that are reasonably practicable is followed.
The rules and regulations concerning shipping of specimens is up to the carrier - and the Post Office have always held that shipping radioactive material by post is a no-no. British Rail had their own rules for parcels and packages (and it was a damned good service at one time) that amounted to It shall be clearly marked as radioactive and not to be near photographic materials. I don't think the parcel service exists on today's rail network, though.
16th Apr 2017 14:15 UTCFred E. Davis
> no longer natural material and are processed radioactive materials [...]
You lost me there. If you chip off a fragment of a boulder to obtain a specimen, then that's ok - it's not yet "processed." But if you trim that chip, it suddenly becomes "processed"? What does altering the non-radioactive matrix (quartz, feldspar etc.) have to do with "processing" the radioactive mineral? I thought separating and concentrating isotopes would qualify as "processed radioactive materials," but when the matrix is NOT radioactive how does trimming the matrix change the category?
16th Apr 2017 17:08 UTCAlysson Rowan Expert
No one will fault you for trimming the matrix, or even picking off a fragment of the specimen for analysis, but the law (as it is in most of Europe) is written with ore separation in mind - and no consideration was ever made as to the numbers of hobby collectors who would like to keep hot rocks. Of course, this clause will be used against you should you spread uraninite dust through a previously uncontaminated neighborhood.
16th Apr 2017 17:14 UTCAlysson Rowan Expert
HSE Information Sheet: Ionising Radiation Protection Series No 8
It references the current legislation here in the UK. It is also aimed at businesses who use ionising radiation or radioactive sources (which is all that you will ever find on most governments' websites).
16th Apr 2017 17:33 UTCAlysson Rowan Expert
Some relevant excerpts from DEFRA's own guidance notes:
Meaning of radioactive material
2.05
Materials which contain naturally occurring radionuclides and which are not used in a
work activity, and which are not used for their radioactive, fertile, or fissile properties,
are not captured by the legislation and are therefore not radioactive material.
NORM industrial activities
2.15
Outside the legislation there are many activities involving radioactivity. An example is
the collection, preparation and display of geological specimens. However, for the
purposes of this legislation, any such activities, unless listed in Table 2.1a or 2.1b (see
page 19), do not involve radioactive material or radioactive waste as defined in this
legislation. This is because in the UK, following Euratom guidance, we believe that the
radiological consequences (in terms of radiation dose) of such activities are trivial. Only
those ‘industrial activities’ which could conceivably lead to the need for controls are
covered by the legislation.
Of course, the legislation is not really that simple - but for the purposes of current legislation, small amounts of radioactive rock in collections are effectively exempt (unless you are a dealer in radioactive rocks, when the law becomes more complex). This does not mean that you shouldn't take care when handling the stuff.
16th Apr 2017 18:06 UTCFred E. Davis
16th Apr 2017 20:42 UTCMatt Neuzil Expert
Regarding these laws, it's getting silly. I guess if I want a Grenville radioactive collection, I will have to keep it I canada
16th Apr 2017 21:24 UTCBrian Eisemann
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Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2024, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: May 9, 2024 01:21:42