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GeneralSmoky Quartz, artifically darkened

24th Jan 2021 12:02 UTCGeorg Graf OP
Hi All,
there are articial darkened Smoky Quartzes from "Arkansas". How and how long does this process of colour change last?
Best to All, Georg
24th Jan 2021 23:02 UTCIan Nicastro
It's accomplished by exposure to a source of gamma radiation, usually a rod of cobalt 60, and such sources are commonly used to sterilize equipment and supplies used in the fields of research, medicine, pharmaceuticals, cosmetics and even food. Cobalt 60 source gamma exposure doesn't leave items with any residual radiation. There are various companies in the US that offer sterilization services and so mine owners or mineral dealers could utilize these companies as well. The time of exposure would vary on the size of the cobalt 60 source and how active it is... but for this application it would probably be on the order of hours. I used to work at a facility with a cobalt 60 source and there was a chart showing how long of an exposure you would need to hit a certain desired dose of radiation, and the chart changed every week or month as the cobalt 60 source slowly decayed over time. I think that the smoky color change that occurs in irradiated quartz crystals is not fully reversible. I anticipate that leaving the irradiated crystals in the sun for a prolonged period of time would bleach the color somewhat but never fully. Plenty of other minerals are gamma irradiated by mineral dealers fairly often to improve color, such as spodumene var. kunzite, topaz, fluorite, and tourmaline. Â

25th Jan 2021 14:54 UTCBret Howard 🌟
The smoky color is stable. I have several irradiated Arkansas quartzes that were treated at least 25 years ago. They are essentially black. They have shown no loss of color but they are not exposed to sunlight. They are actually rather nice crystals. Always wondered why someone would want to irradiate them in the first place. I use them for educational purposes to illustrate effects of various mineral/gemstone treatments. Heat treatment should remove the smoky color by eliminating the color centers caused by the irradiation process.
Bret
25th Jan 2021 18:18 UTCAmir C. Akhavan Expert
>> Always wondered why someone would want to irradiate them in the first place.Â
The irradiated ones I got from Arkansas would probably not sell as well in their natural state: they got too many inclusions and internal fractures and were certainly rather milky, not clear.
BTW, color will fade in UV light, too, and will fade completely.
Color is said to be less stable than in natural smoky quartz but I don't know any systematic studies about this. Makes sense, though, because they would probably be at least a bit smoky if it the trace element composition allowed it (too much hydrogen is not good for color center formation).

25th Jan 2021 19:48 UTCBret Howard 🌟
Yes, I agree, the average person would probably find the smoky ones more desirable. Some of the ones I have would definitely be at least partially milky if they hadn't been irradiated but some appear to have been reasonably transparent originally and not low quality. I was thinking that back when these were treated, nice Arkansas quartz specimens were reasonably cheap and plentiful so maybe whoever had them treated said "why not".Â

25th Jan 2021 16:26 UTCGeorg Graf OP
Hi Ian Nicastro,
hi Bret Howard,
much thanks for your informations.
Stay safe! Georg
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Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2026, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph and Ida Chau.
To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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