| Reference Type | Journal (article/letter/editorial) |
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| Title | The crystal structure of Ba2F2(S6+O3S2–), a natural thiosulphate weathering product of old smelting slags at the Surrender Mill, Yorkshire, UK |
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| Journal | Mineralogical Magazine |
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| Authors | Kampf, A. R. | Author |
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| Year | 2009 (April) | Volume | 73 |
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| Issue | 2 |
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| Publisher | Mineralogical Society |
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| URL | |
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| DOI | doi:10.1180/minmag.2009.073.2.251Search in ResearchGate |
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| Classification | Not set | LoC | Not set |
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| Mindat Ref. ID | 16990471 | Long-form Identifier | mindat:1:5:16990471:7 |
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| GUID | 0 |
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| Full Reference | Kampf, A. R. (2009) The crystal structure of Ba2F2(S6+O3S2–), a natural thiosulphate weathering product of old smelting slags at the Surrender Mill, Yorkshire, UK. Mineralogical Magazine, 73 (2) 251-255 doi:10.1180/minmag.2009.073.2.251 |
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| Plain Text | Kampf, A. R. (2009) The crystal structure of Ba2F2(S6+O3S2–), a natural thiosulphate weathering product of old smelting slags at the Surrender Mill, Yorkshire, UK. Mineralogical Magazine, 73 (2) 251-255 doi:10.1180/minmag.2009.073.2.251 |
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| In | (2009, April) Mineralogical Magazine Vol. 73 (2) Mineralogical Society |
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| Abstract/Notes | The crystal structure of Ba2F2(S6+O3S2–), a natural thiosulphate weathering product of old smelting slags at the Surrender Mill, Yorkshire, England, UK, has been solved to R1 = 0.88% for 399 unique [Fo > 4α F] reflections and 0.91% for all 407 reflections. The compound is monoclinic, C2/m, a 15.3172(5), b 4.5898(1), c 4.6320(2) Å, β 101.449(1)º, V 319.17(2) Å3. The structure of Ba2F2(S6+O3S2–) consists of BaF2Ba layer fragments of the fluorite-type structure of frankdicksonite (BaF2) parallel to (100) alternating with layers of thiosulphate groups. The layer sequence in one unit cell is (S6+O3S2–)-BaF2Ba-(S6+O3S2–)-BaF2Ba. The structure resembles that of grandreefite, Pb2F2SO4. |
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