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Hovis, G., Tribaudino, M. (2025) The thermal expansion of monticellite and olivine. European Journal of Mineralogy, 37 (2). 181-190 doi:10.5194/ejm-37-181-2025

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Reference TypeJournal (article/letter/editorial)
TitleThe thermal expansion of monticellite and olivine
JournalEuropean Journal of Mineralogy
AuthorsHovis, G.Author
Tribaudino, M.Author
Year2025Volume<   37   >
Page(s)181-190Issue<   2   >
URL
DOIdoi:10.5194/ejm-37-181-2025Search in ResearchGate
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Mindat Ref. ID18166138Long-form Identifiermindat:1:5:18166138:4
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Full ReferenceHovis, G., Tribaudino, M. (2025) The thermal expansion of monticellite and olivine. European Journal of Mineralogy, 37 (2). 181-190 doi:10.5194/ejm-37-181-2025
Plain TextHovis, G., Tribaudino, M. (2025) The thermal expansion of monticellite and olivine. European Journal of Mineralogy, 37 (2). 181-190 doi:10.5194/ejm-37-181-2025
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Abstract/NotesThe thermal expansion of two natural monticellite (CaMgSiO4) samples was measured by X-ray powder diffraction between 298 and 1250 K. Axial expansion in monticellite is anisotropic with α(c) > α(b) ≥α(a), with the volume expansion nearly equivalent to that of synthetic forsterite as measured in the same laboratory, although forsterite axes expand as α(b) > α(c) > α(a). Kroll physical and Fei empirical models have been used to describe the volume and axial thermal expansion of both minerals. High-temperature structural data for these minerals show that the Ca-occupied M2 polyhedron in monticellite expands less than the Mg-occupied site in forsterite, resulting in comparatively lower expansion along the b crystallographic axis. But greater expansion of the M1 polyhedron in monticellite accounts for greater expansion along its c axis and, in turn, the nearly equivalent volume expansion relative to that of forsterite.

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MineralCitation Details
Forsterite
Monticellite


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