Log InRegister
Quick Links : The Mindat ManualThe Rock H. Currier Digital LibraryMindat Newsletter [Free Download]
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreContact UsAdvertise on Mindat
Donate to MindatCorporate SponsorshipSponsor a PageSponsored PagesMindat AdvertisersAdvertise on Mindat
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe ElementsThe Rock H. Currier Digital LibraryGeologic Time
Minerals by PropertiesMinerals by ChemistryMineral Visual ExplorerAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDLocalities Near MeSearch ArticlesSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
Mining CompaniesStatisticsUsersMineral MuseumsClubs & OrganizationsMineral Shows & EventsThe Mindat DirectoryDevice SettingsThe Mineral QuizTime Machine
Photo SearchPhoto GalleriesSearch by ColorPhoto Colour ExplorerNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Puthiyadath, Anagha; Murphy, Patrick; Mafi, Delara; Patel, Purti; Jackson, Timothy A. (2025) Formation of a MnIII–O–CeIV species from a MnIII-hydroxo complex and ceric ammonium nitrate. Dalton Transactions, 54 (37). doi:10.1039/d5dt01728a

Advanced
   -   Only viewable:
Reference TypeJournal (article/letter/editorial)
TitleFormation of a MnIII–O–CeIV species from a MnIII-hydroxo complex and ceric ammonium nitrate
JournalDalton Transactions
AuthorsPuthiyadath, AnaghaAuthor
Murphy, PatrickAuthor
Mafi, DelaraAuthor
Patel, PurtiAuthor
Jackson, Timothy A.Author
Year2025Volume54
Issue37
PublisherRoyal Society of Chemistry (RSC)
DOIdoi:10.1039/d5dt01728aSearch in ResearchGate
Generate Citation Formats
Mindat Ref. ID19009892Long-form Identifiermindat:1:5:19009892:8
GUID0
Full ReferencePuthiyadath, Anagha; Murphy, Patrick; Mafi, Delara; Patel, Purti; Jackson, Timothy A. (2025) Formation of a MnIII–O–CeIV species from a MnIII-hydroxo complex and ceric ammonium nitrate. Dalton Transactions, 54 (37). doi:10.1039/d5dt01728a
Plain TextPuthiyadath, Anagha; Murphy, Patrick; Mafi, Delara; Patel, Purti; Jackson, Timothy A. (2025) Formation of a MnIII–O–CeIV species from a MnIII-hydroxo complex and ceric ammonium nitrate. Dalton Transactions, 54 (37). doi:10.1039/d5dt01728a
In(2025) Dalton Transactions Vol. 54 (37). Royal Society of Chemistry (RSC)

References Listed

These are the references the publisher has listed as being connected to the article. Please check the article itself for the full list of references which may differ. Not all references are currently linkable within the Digital Library.

Nair, Vijay, Deepthi, Ani (2007) Cerium(IV) Ammonium NitrateA Versatile Single-Electron Oxidant. Chemical Reviews, 107 (5) 1862-1891 doi:10.1021/cr068408n
Fillol, Julio Lloret, Codolà, Zoel, Garcia-Bosch, Isaac, Gómez, Laura, Pla, Juan José, Costas, Miquel (2011) Efficient water oxidation catalysts based on readily available iron coordination complexes. Nature Chemistry, 3 (10) 807-813 doi:10.1038/nchem.1140
Codolà, Zoel, Garcia-Bosch, Isaac, Acuña-Parés, Ferran, Prat, Irene, Luis, Josep M., Costas, Miquel, Lloret-Fillol, Julio (2013) Electronic Effects on Single-Site Iron Catalysts for Water Oxidation. Chemistry - A European Journal, 19 (25). 8042-8047 doi:10.1002/chem.201301112
Hong, Dachao, Mandal, Sukanta, Yamada, Yusuke, Lee, Yong-Min, Nam, Wonwoo, Llobet, Antoni, Fukuzumi, Shunichi (2013) Water Oxidation Catalysis with Nonheme Iron Complexes under Acidic and Basic Conditions: Homogeneous or Heterogeneous?. Inorganic Chemistry, 52 (16) 9522-9531 doi:10.1021/ic401180r
Fukuzumi, Shunichi, Lee, Yong-Min, Nam, Wonwoo (2019) Kinetics and mechanisms of catalytic water oxidation. Dalton Transactions, 48 (3). 779-798 doi:10.1039/c8dt04341h
Moonshiram, D., Alperovich, I., Concepcion, J. J., Meyer, T. J., Pushkar, Y. (2013) Experimental demonstration of radicaloid character in a RuV=O intermediate in catalytic water oxidation. Proceedings of the National Academy of Sciences, 110 (10) 3765-3770 doi:10.1073/pnas.1222102110
Ellis, W. Chadwick, McDaniel, Neal D., Bernhard, Stefan, Collins, Terrence J. (2010) Fast Water Oxidation Using Iron. Journal Of The American Chemical Society, 132 (32) 10990-10991 doi:10.1021/ja104766z
Grotjahn, Douglas B., Brown, Derek B., Martin, Jessica K., Marelius, David C., Abadjian, Marie-Caline, Tran, Hai N., Kalyuzhny, Gregory, Vecchio, Kenneth S., Specht, Zephen G., Cortes-Llamas, Sara A., Miranda-Soto, Valentin, van Niekerk, Christoffel, Moore, Curtis E., Rheingold, Arnold L. (2011) Evolution of Iridium-Based Molecular Catalysts during Water Oxidation with Ceric Ammonium Nitrate. Journal Of The American Chemical Society, 133 (47) 19024-19027 doi:10.1021/ja203095k
Noyes, Arthur A., Garner, Clifford S. (1936) Strong Oxidizing Agents in Nitric Acid Solution. I. Oxidation Potential of Cerous—Ceric Salts. Journal Of The American Chemical Society, 58 (7) 1265-1268 doi:10.1021/ja01298a051
Not Yet Imported: Coordination Chemistry Reviews - journal-article : 10.1016/j.ccr.2013.08.034

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Ezhov, Roman, Ravari, Alireza Karbakhsh, Pushkar, Yulia (2020) Characterization of the Fe V =O Complex in the Pathway of Water Oxidation. Angewandte Chemie International Edition, 59 (32) 13502-13505 doi:10.1002/anie.202003278
Draksharapu, Apparao, Xu, Shuangning, Que, Lawrence (2020) Ce IV ‐ and HClO 4 ‐Promoted Assembly of an Fe 2 IV (μ‐O) 2 Diamond Core from its Monomeric Fe IV =O Precursor at Room Temperature. Angewandte Chemie International Edition, 59 (50) 22484-22488 doi:10.1002/anie.202010027
Codolà, Zoel, Gómez, Laura, Kleespies, Scott T., Que Jr, Lawrence, Costas, Miquel, Lloret-Fillol, Julio (2015) Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation. Nature Communications, 6. doi:10.1038/ncomms6865
Wu, Xiujuan, Yang, Xiaonan, Lee, Yong-Min, Nam, Wonwoo, Sun, Licheng (2015) A nonheme manganese(iv)–oxo species generated in photocatalytic reaction using water as an oxygen source. Chemical Communications, 51 (19). 4013-4016 doi:10.1039/c4cc10411k
Barman, Prasenjit, Vardhaman, Anil Kumar, Martin, Bodo, Wörner, Svenja J., Sastri, Chivukula V., Comba, Peter (2015) Influence of Ligand Architecture on Oxidation Reactions by High-Valent Nonheme Manganese Oxo Complexes Using Water as a Source of Oxygen. Angewandte Chemie International Edition, 54 (7). 2095-2099 doi:10.1002/anie.201409476
Lee, Yuri, Puthiyadath, Anagha, Jones, Shannon D., Denler, Melissa C., Murphy, Patrick, Mafi, Delara, Jackson, Timothy A. (2024) Ceric Ammonium Nitrate Oxidation of a MnII Complex Generates a Bis(μ-oxo)dimanganese(IV,IV) Product via a MnIV–Oxo Intermediate. Inorganic Chemistry, 63 (46). doi:10.1021/acs.inorgchem.4c03205
Gupta, Sikha, Arora, Pragya, Kumar, Rakesh, Awasthi, Ayushi, Chandra, Bittu, Eerlapally, Raju, Xiong, Jin, Guo, Yisong, Que, Lawrence, Draksharapu, Apparao (2024) Formation of a Reactive [Mn(III)−O−Ce(IV)] Species and its Facile Equilibrium with Related Mn(IV)(OX) (X = Sc or H) Complexes. Angewandte Chemie International Edition, 63 (3) doi:10.1002/anie.202316378
Karmalkar, Deepika G., Sankaralingam, Muniyandi, Seo, Mi Sook, Ezhov, Roman, Lee, Yong‐Min, Pushkar, Yulia N., Kim, Won‐Suk, Fukuzumi, Shunichi, Nam, Wonwoo (2019) A High‐Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity. Angewandte Chemie International Edition, 58 (45). 16124-16129 doi:10.1002/anie.201910032
Gupta, Sikha, Arora, Pragya, Aghaei, Zahra, Singh, Baghendra, Jackson, Timothy A., Draksharapu, Apparao (2025) Formation and Reactivity of a MnIV(O)(μ-O)CeIV Species: A Closest Mimic of Photosystem II. Journal of the American Chemical Society, 147 (1). doi:10.1021/jacs.4c12523
Opalade, Adedamola A., Hessefort, Logan, Day, Victor W., Jackson, Timothy A. (2021) Controlling the Reactivity of a Metal-Hydroxo Adduct with a Hydrogen Bond. Journal of the American Chemical Society, 143 (37) 15159-15175 doi:10.1021/jacs.1c06199
Eroy-Reveles, Aura A., Leung, Yvonne, Beavers, Christine M., Olmstead, Marilyn M., Mascharak, Pradip K. (2008) Near-Infrared Light Activated Release of Nitric Oxide from Designed Photoactive Manganese Nitrosyls:  Strategy, Design, and Potential as NO Donors. Journal Of The American Chemical Society, 130 (13) 4447-4458 doi:10.1021/ja710265j
Not Yet Imported: WIREs Computational Molecular Science - journal-article : 10.1002/wcms.81

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Not Yet Imported: - journal-article : 10.1002/wcms.1327

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Not Yet Imported: WIREs Computational Molecular Science - journal-article : 10.1002/wcms.1606

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Neese, Frank (2023) The SHARK integral generation and digestion system. Journal of Computational Chemistry, 44 (3) 381-396 doi:10.1002/jcc.26942
Tao, Jianmin, Perdew, John P., Staroverov, Viktor N., Scuseria, Gustavo E. (2003) Climbing the Density Functional Ladder: Nonempirical Meta–Generalized Gradient Approximation Designed for Molecules and Solids. Physical Review Letters, 91 (14). doi:10.1103/physrevlett.91.146401
Weigend, Florian, Ahlrichs, Reinhart (2005) Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy. Physical Chemistry Chemical Physics, 7 (18). 3297pp. doi:10.1039/b508541a
Not Yet Imported: Journal of Chemical Theory and Computation - journal-article : 10.1021/ct900090f

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Grimme, Stefan, Antony, Jens, Ehrlich, Stephan, Krieg, Helge (2010) A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. The Journal of Chemical Physics, 132 (15). 154104pp. doi:10.1063/1.3382344
Grimme, Stefan, Ehrlich, Stephan, Goerigk, Lars (2011) Effect of the damping function in dispersion corrected density functional theory. Journal of Computational Chemistry, 32 (7). 1456-1465 doi:10.1002/jcc.21759
Neese, Frank (2003) An improvement of the resolution of the identity approximation for the formation of the Coulomb matrix. Journal of Computational Chemistry, 24 (14). 1740-1747 doi:10.1002/jcc.10318
Not Yet Imported: - journal-article : 10.1021/acs.jctc.6b01041

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Beineke, Thomas A., Delgaudio, J. (1968) Crystal structure of ceric ammonium nitrate. Inorganic Chemistry, 7 (4) 715-721 doi:10.1021/ic50062a020
Wijeratne, Gayan B., Corzine, Briana, Day, Victor W., Jackson, Timothy A. (2014) Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn(III)–OH Complex Derived from Dioxygen. Inorganic Chemistry, 53 (14) 7622-7634 doi:10.1021/ic500943k
Rice, Derek B., Jones, Shannon D., Douglas, Justin T., Jackson, Timothy A. (2018) NMR Studies of a MnIII-hydroxo Adduct Reveal an Equilibrium between MnIII-hydroxo and μ-Oxodimanganese(III,III) Species. Inorganic Chemistry, 57 (13) 7825-7837 doi:10.1021/acs.inorgchem.8b00917
Rice, Derek B., Munasinghe, Aruna, Grotemeyer, Elizabeth N., Burr, Andrew D., Day, Victor W., Jackson, Timothy A. (2019) Structure and Reactivity of (μ-Oxo)dimanganese(III,III) and Mononuclear Hydroxomanganese(III) Adducts Supported by Derivatives of an Amide-Containing Pentadentate Ligand. Inorganic Chemistry, 58 (1) 622-636 doi:10.1021/acs.inorgchem.8b02794
Leto, Domenick F., Jackson, Timothy A. (2014) Mn K-Edge X-ray Absorption Studies of Oxo- and Hydroxo-manganese(IV) Complexes: Experimental and Theoretical Insights into Pre-Edge Properties. Inorganic Chemistry, 53 (12) 6179-6194 doi:10.1021/ic5006902
Gupta, Sikha, Arora, Pragya, Kumar, Rakesh, Awasthi, Ayushi, Chandra, Bittu, Eerlapally, Raju, Xiong, Jin, Guo, Yisong, Que, Lawrence, Draksharapu, Apparao (2024) Formation of a Reactive [Mn(III)−O−Ce(IV)] Species and its Facile Equilibrium with Related Mn(IV)(OX) (X = Sc or H) Complexes. Angewandte Chemie International Edition, 63 (3) doi:10.1002/anie.202316378
Not Yet Imported: - journal-article : 10.1039/B712872J

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Draksharapu, Apparao, Rasheed, Waqas, Klein, Johannes E. M. N., Que, Lawrence (2017) Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III). Angewandte Chemie International Edition, 56 (31). 9091-9095 doi:10.1002/anie.201704322
Sankaralingam, Muniyandi, Lee, Yong-Min, Karmalkar, Deepika G., Nam, Wonwoo, Fukuzumi, Shunichi (2018) A Mononuclear Non-heme Manganese(III)–Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions. Journal Of The American Chemical Society, 140 (40) 12695-12699 doi:10.1021/jacs.8b07772
Sawant, Sarvesh C., Wu, Xiujuan, Cho, Jaeheung, Cho, Kyung-Bin, Kim, Sun Hee, Seo, Mi Sook, Lee, Yong-Min, Kubo, Minoru, Ogura, Takashi, Shaik, Sason, Nam, Wonwoo (2010) Water as an Oxygen Source: Synthesis, Characterization, and Reactivity Studies of a Mononuclear Nonheme Manganese(IV) Oxo Complex. Angewandte Chemie International Edition, 49 (44). 8190-8194 doi:10.1002/anie.201000819
Rice, Derek B., Wijeratne, Gayan B., Burr, Andrew D., Parham, Joshua D., Day, Victor W., Jackson, Timothy A. (2016) Steric and Electronic Influence on Proton-Coupled Electron-Transfer Reactivity of a Mononuclear Mn(III)-Hydroxo Complex. Inorganic Chemistry, 55 (16) 8110-8120 doi:10.1021/acs.inorgchem.6b01217
Not Yet Imported: Journal of Molecular Catalysis A: Chemical - journal-article : 10.1016/j.molcata.2006.01.042

If you would like this item imported into the Digital Library, please contact us quoting Journal ID
Zang, Yan, Kim, Jinheung, Dong, Yanhong, Wilkinson, Elizabeth C., Appelman, Evan H., Que, Lawrence (1997) Models for Nonheme Iron Intermediates:  Structural Basis for Tuning the Spin States of Fe(TPA) Complexes. Journal Of The American Chemical Society, 119 (18) 4197-4205 doi:10.1021/ja9638521
Chiou, Yu-Min, Que, Lawrence (1995) Models for .alpha.-Keto Acid-Dependent Non-heme Iron Enzymes: Structures and Reactivity of [FeII(L)(O2CCOPh)](ClO4) Complexes. Journal Of The American Chemical Society, 117 (14) 3999-4013 doi:10.1021/ja00119a015
Kim, Jinheung, Zang, Yan, Costas, Miquel, Harrison, Roger G., Wilkinson, Elizabeth C., Que Jr, Lawrence (2001) A nonheme iron(II) complex that models the redox cycle of lipoxygenase. JBIC Journal of Biological Inorganic Chemistry, 6 (3) 275-284 doi:10.1007/s007750000198

See Also

These are possibly similar items as determined by title/reference text matching only.

Lee, Yuri, Puthiyadath, Anagha, Jones, Shannon D., Denler, Melissa C., Murphy, Patrick, Mafi, Delara, Jackson, Timothy A. (2024) Ceric Ammonium Nitrate Oxidation of a MnII Complex Generates a Bis(μ-oxo)dimanganese(IV,IV) Product via a MnIV–Oxo Intermediate. Inorganic Chemistry, 63 (46). doi:10.1021/acs.inorgchem.4c03205
Grotemeyer, Elizabeth N., Parham, Joshua D., Jackson, Timothy A. (2023) Reaction landscape of a mononuclear MnIII–hydroxo complex with hydrogen peroxide. Dalton Transactions, 52 (40) 14350-14370 doi:10.1039/d3dt02672h
Wijeratne, Gayan B., Day, Victor W., Jackson, Timothy A. (2015) O–H bond oxidation by a monomeric MnIII–OMe complex. Dalton Transactions, 44 (7). 3295-3306 doi:10.1039/c4dt03546a
Rice, Derek B., Jones, Shannon D., Douglas, Justin T., Jackson, Timothy A. (2018) NMR Studies of a MnIII-hydroxo Adduct Reveal an Equilibrium between MnIII-hydroxo and μ-Oxodimanganese(III,III) Species. Inorganic Chemistry, 57 (13) 7825-7837 doi:10.1021/acs.inorgchem.8b00917
Puthiyadath, Anagha; Jackson, Timothy A. (2025) Comparing the Thermodynamic Properties and Reactivity of Fe III - and Mn III –Hydroxo Complexes. Inorganic Chemistry, 64 (51). doi:10.1021/acs.inorgchem.5c04654
Brunclik, Samuel A., Opalade, Adedamola A., Jackson, Timothy A. (2023) Electronic structure contributions to O–O bond cleavage reactions for MnIII-alkylperoxo complexes. Dalton Transactions, 52 (39) 13878-13894 doi:10.1039/d3dt01672b
Mudoi, Prashurya Pritam; Ahmed, Niku; Choudhury, Anup; Li, Yanling; Lescouëzec, Rodrigue; Kintzel, Benjamin; Akintola, Oluseun; Plass, Winfried; Rajendiran, Marimuthu; Gogoi, Nayanmoni (2025) Investigation of protonation induced metal-to-metal electron transfer in a cyano-bridged MnIII–FeIII dinuclear complex. Dalton Transactions, 54 (37). doi:10.1039/d5dt01885d
Denler, Melissa C., Wijeratne, Gayan B., Rice, Derek B., Colmer, Hannah E., Day, Victor W., Jackson, Timothy A. (2018) MnIII-Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity. Dalton Transactions, 47 (38). 13442-13458 doi:10.1039/c8dt02300j
Singh, Priya, Lomax, Markell J. A., Opalade, Adedamola A., Nguyen, Brandon B., Srnec, Martin, Jackson, Timothy A. (2024) Basicity of MnIII-Hydroxo Complexes Controls the Thermodynamics of Proton-Coupled Electron Transfer Reactions. Inorganic Chemistry, 63 (46). doi:10.1021/acs.inorgchem.4c03254
Grotemeyer, Elizabeth N., Aghaei, Zahra, Jackson, Timothy A. (2024) Spectroscopic Properties and Reactivity of a MnIII‐Hydroperoxo Complex that is Stable at Room Temperature. Chemistry – A European Journal, 30 (70). doi:10.1002/chem.202403051
Gupta, Sikha, Arora, Pragya, Aghaei, Zahra, Singh, Baghendra, Jackson, Timothy A., Draksharapu, Apparao (2025) Formation and Reactivity of a MnIV(O)(μ-O)CeIV Species: A Closest Mimic of Photosystem II. Journal of the American Chemical Society, 147 (1). doi:10.1021/jacs.4c12523
 
and/or  
Mindat.org® is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization. Mindat® and mindat.org® are registered trademarks of the Hudson Institute of Mineralogy.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2026, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph and Ida Chau.
To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: June 7, 2026 01:31:25
Go to top of page