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Crichton, W. A., Müller, H., Merlini, M., Roth, T., Detlefs, C. (2010) Monazite structure from dehydrated CaSeO4·2H2O. Mineralogical Magazine, 74 (1) 127-139 doi:10.1180/minmag.2010.074.1.127

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Reference TypeJournal (article/letter/editorial)
TitleMonazite structure from dehydrated CaSeO4·2H2O
JournalMineralogical Magazine
AuthorsCrichton, W. A.Author
Müller, H.Author
Merlini, M.Author
Roth, T.Author
Detlefs, C.Author
Year2010 (February)Volume74
Page(s)127-139Issue1
PublisherMineralogical Society
DOIdoi:10.1180/minmag.2010.074.1.127Search in ResearchGate
Mindat Ref. ID244049Long-form Identifiermindat:1:5:244049:5
GUID7996c4b5-60ac-4d1f-888f-0fa5dbdda486
Full ReferenceCrichton, W. A., Müller, H., Merlini, M., Roth, T., Detlefs, C. (2010) Monazite structure from dehydrated CaSeO4·2H2O. Mineralogical Magazine, 74 (1) 127-139 doi:10.1180/minmag.2010.074.1.127
Plain TextCrichton, W. A., Müller, H., Merlini, M., Roth, T., Detlefs, C. (2010) Monazite structure from dehydrated CaSeO4·2H2O. Mineralogical Magazine, 74 (1) 127-139 doi:10.1180/minmag.2010.074.1.127
In(2010, February) Mineralogical Magazine Vol. 74 (1) Mineralogical Society
Abstract/NotesAbstractThe structure of the high-temperature form of CaSeO4, formed by dehydration of the gyspum-type structure dihydrate is presented. The material is equivalent to that described previously as a P212121 form, but is however, a monazite with unit cell a = 6.85661(16) Å, b = 7.04962(15) Å, c = 6.68817(15) Å and β = 104.2675(21)° in space group P121/n1. Also presented is evidence for two intermediate trigonal and pseudo-trigonal phases related to the structurally similar minerals rhabdophane, bassanite, and γ-CaSO4. This result permits closer comparisons between intermediate-temperature structures of the selenate with related sulphates, and orthophosphates with a view to extending structural stability via synthesis of solid-solutions.


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