| Reference Type | Journal (article/letter/editorial) |
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| Title | Canutite, NaMn3[AsO4][AsO3(OH)]2, a new protonated alluaudite-group mineral from the Torrecillas mine, Iquique Province, Chile |
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| Journal | Mineralogical Magazine |
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| Authors | Kampf, Anthony R. | Author |
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| Mills, Stuart J. | Author |
| Hatert, F. | Author |
| Nash, Barbara P. | Author |
| Dini, M. | Author |
| Molina Donoso, A. A. | Author |
| Year | 2014 (August) | Volume | 78 |
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| Issue | 4 |
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| Publisher | Mineralogical Society |
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| Download URL | https://rruff.info/rruff_1.0/uploads/MM78_787.pdf+ |
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| DOI | doi:10.1180/minmag.2014.078.4.02Search in ResearchGate |
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| Generate Citation Formats |
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| Classification | Not set | LoC | Not set |
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| Mindat Ref. ID | 244537 | Long-form Identifier | mindat:1:5:244537:7 |
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| GUID | 0 |
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| Full Reference | Kampf, Anthony R., Mills, Stuart J., Hatert, F., Nash, Barbara P., Dini, M., Molina Donoso, A. A. (2014) Canutite, NaMn3[AsO4][AsO3(OH)]2, a new protonated alluaudite-group mineral from the Torrecillas mine, Iquique Province, Chile. Mineralogical Magazine, 78 (4) 787-795 doi:10.1180/minmag.2014.078.4.02 |
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| Plain Text | Kampf, Anthony R., Mills, Stuart J., Hatert, F., Nash, Barbara P., Dini, M., Molina Donoso, A. A. (2014) Canutite, NaMn3[AsO4][AsO3(OH)]2, a new protonated alluaudite-group mineral from the Torrecillas mine, Iquique Province, Chile. Mineralogical Magazine, 78 (4) 787-795 doi:10.1180/minmag.2014.078.4.02 |
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| Abstract/Notes | The new mineral canutite (IMA2013-070), NaMn3[AsO4][AsO3(OH)]2, was found at two different locations at the Torrecillas mine, Salar Grande, Iquique Province, Chile, where it occurs as a secondary alteration phase in association with anhydrite, halite, lavendulan, magnesiokoritnigite, pyrite, quartz and scorodite. Canutite is reddish brown in colour. It forms as prisms elongated on [20] and exhibiting the forms {010}, {100}, {10}, {201} and {102}, or as tablets flattened on {102} and exhibiting the forms {102} and {110}. Crystals are transparent with a vitreous lustre. The mineral has a pale tan streak, Mohs hardness of 2½, brittle tenacity, splintery fracture and two perfect cleavages, on {010} and {101}. The calculated density is 4.112 g cm−3. Optically, canutite is biaxial (+) with α = 1.712(3), β = 1.725(3) and γ = 1.756(3) (measured in white light). The measured 2V is 65.6(4)°, the dispersion is r < v (slight), the optical orientation is Z = b; X ^ a = 18° in obtuse β and pleochroism is imperceptible. The mineral is slowly soluble in cold, dilute HCl. The empirical formula (for tabular crystals from near the mineshaft), determined from electron - microprobe analyses, is (Na1.05Mn2.64Mg0.34Cu0.14Co0.03)∑4.20As3O12H1.62. Canutite is monoclinic, C2/c, a = 12.3282(4), b = 12.6039(5), c = 6.8814(5) Å, β = 113.480(8)°, V = 980.72(10) Å3 and Z = 4. The eight strongest X-ray powder diffraction lines are [dobs Å(I)(hkl)]: 6.33(34)(020), 4.12(26)(21), 3.608(29)(310,31), 3.296(57)(12), 3.150(28)(002,131), 2.819(42)(400,041,330), 2.740(100)(240,02,112) and 1.5364(31)(multiple). The structure, refined to R1 = 2.33% for 1089 Fo > 4σF reflections, shows canutite to be isostructural with protonated members of the alluaudite group. |
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