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Holtstam, Dan, Nysten, Per, Gatedal, Kjell (1998) Parageneses and compositional variations of Sb oxyminerals from Långban-type deposits in Värmland, Sweden. Mineralogical Magazine, 62 (3) 395-407 doi:10.1180/002646198547666

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Reference TypeJournal (article/letter/editorial)
TitleParageneses and compositional variations of Sb oxyminerals from Långban-type deposits in Värmland, Sweden
JournalMineralogical MagazineISSN0026-461X
AuthorsHoltstam, DanAuthor
Nysten, PerAuthor
Gatedal, KjellAuthor
Year1998 (June)Volume62
Page(s)395-407Issue3
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_62/62-3-395.pdf+
DOIdoi:10.1180/002646198547666Search in ResearchGate
Mindat Ref. ID285Long-form Identifiermindat:1:5:285:3
GUID3bd7129a-38e2-4313-b81a-86cda829d705
Full ReferenceHoltstam, Dan, Nysten, Per, Gatedal, Kjell (1998) Parageneses and compositional variations of Sb oxyminerals from Långban-type deposits in Värmland, Sweden. Mineralogical Magazine, 62 (3) 395-407 doi:10.1180/002646198547666
Plain TextHoltstam, Dan, Nysten, Per, Gatedal, Kjell (1998) Parageneses and compositional variations of Sb oxyminerals from Långban-type deposits in Värmland, Sweden. Mineralogical Magazine, 62 (3) 395-407 doi:10.1180/002646198547666
Abstract/NotesAbstractThe Långban, Nordmark and Jakobsberg Mn-Fe deposits contain the only known occurrences of filipstadite and manganostibite (ideal formulae (Mn, Mg)2(Sb0.55+Fe0.53+)O4 and Mn72+SbAsO12, respectively). Filipstadite from Nordmark is newly recognized, and occurs in assemblages with svabite-johnbaumite, calcite, tephroite-forsterite, phlogopite-kinoshitalite, tilasite, ±jacobsite, ±plumbia roméite, ±adelite, ±hedyphane. Manganostibite from Långban and Jakobsberg is reported for the first time, and the mineral is generally associated with katoptrite, tephroite, humite-group minerals, calcite, svabite, allactite, manganosite, hausmannite, jacobsite, spinel s.s., etc. Whereas filipstadite is clearly secondary relative to the major part of the matrix components, manganostibite is believed to have formed coevally with the principal ore and skarn minerals at these deposits.The previously known compositional ranges are extended. Based on electron-microprobe analyses, Nordmark filipstadite contains 4.1–7.3 MgO, 0.0–0.5 Al2O3, 30.5–45.3 MnO, 17.0–40.1 Fe2O3, 0.2–0.9 ZnO, 19.9–29.9 Sb2O5 (all in wt.%), corresponding to 58–100 mol.% of a pure filipstadite component. Associated jacobsites show Sb2O5 contents of up to c. 5 wt.%. Manganostibites (all three deposits considered) contain 1.0–2.9 MgO, 2.8–3.8 SiO2, 57.4–60.3 MnO, 0.2–3.5 Mn2O3, 0.3–2.0 Fe2O3, 0.0–2.4 ZnO, 21.5–23.0 Sb2O5, 7.7–10.0 As2O5 (all in wt.%). Si and trivalent cations are incorporated via a (Mn3+,Fe3+) + Si4+=Mn2+ + As5+ exchange mechanism, which improves the local charge balance at tetrahedral structural sites dominated by As.


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