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Murad, Enver, Schwertmann, Udo (1984) The influence of crystallinity on the Mössbauer spectrum of lepidocrocite. Mineralogical Magazine, 48 (349) 507-511 doi:10.1180/minmag.1984.048.349.04

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Reference TypeJournal (article/letter/editorial)
TitleThe influence of crystallinity on the Mössbauer spectrum of lepidocrocite
JournalMineralogical MagazineISSN0026-461X
AuthorsMurad, EnverAuthor
Schwertmann, UdoAuthor
Year1984 (December)Volume48
Issue349
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_48/48-349-507.pdf+
DOIdoi:10.1180/minmag.1984.048.349.04Search in ResearchGate
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Mindat Ref. ID3664Long-form Identifiermindat:1:5:3664:5
GUID0
Full ReferenceMurad, Enver, Schwertmann, Udo (1984) The influence of crystallinity on the Mössbauer spectrum of lepidocrocite. Mineralogical Magazine, 48 (349) 507-511 doi:10.1180/minmag.1984.048.349.04
Plain TextMurad, Enver, Schwertmann, Udo (1984) The influence of crystallinity on the Mössbauer spectrum of lepidocrocite. Mineralogical Magazine, 48 (349) 507-511 doi:10.1180/minmag.1984.048.349.04
In(1984, December) Mineralogical Magazine Vol. 48 (349) Mineralogical Society
Abstract/NotesAbstractParticle morphology can result in very pronounced effects of crystallinity on the Mössbauer spectra of lepidocrocite. Such effects can noticeably increase the quadrupole splitting of poorly crystallized paramagnetic lepidocrocites, making it necessary to fit two doublets of different quadrupole splittings to Mössbauer spectra of such samples, and may lower the onset of magnetic ordering from the bulk Néel temperature of 77 ±1 K to about 50 K.At 4.2 K, distributions of magnetic hyperfine fields with a limiting upper field of 460 kOe are observed. The contributions of lower fields to such distributions increase with decreasing crystallinity, producing asymmetrically broadened resonant lines.

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Lepidocrocite


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