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Ashwal, L. D., Armstrong, R. A., Roberts, R. J., Schmitz, M. D., Corfu, F., Hetherington, C. J., Burke, K., Gerber, M. (2007) Geochronology of zircon megacrysts from nepheline-bearing gneisses as constraints on tectonic setting: implications for resetting of the U-Pb and Lu-Hf isotopic systems. Contributions to Mineralogy and Petrology, 153 (4). 389-403 doi:10.1007/s00410-006-0153-9

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Reference TypeJournal (article/letter/editorial)
TitleGeochronology of zircon megacrysts from nepheline-bearing gneisses as constraints on tectonic setting: implications for resetting of the U-Pb and Lu-Hf isotopic systems
JournalContributions to Mineralogy and Petrology
AuthorsAshwal, L. D.Author
Armstrong, R. A.Author
Roberts, R. J.Author
Schmitz, M. D.Author
Corfu, F.Author
Hetherington, C. J.Author
Burke, K.Author
Gerber, M.Author
Year2007 (March 1)Volume153
Page(s)389-403Issue4
PublisherSpringer Science and Business Media LLC
DOIdoi:10.1007/s00410-006-0153-9Search in ResearchGate
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Mindat Ref. ID78696Long-form Identifiermindat:1:5:78696:4
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Full ReferenceAshwal, L. D., Armstrong, R. A., Roberts, R. J., Schmitz, M. D., Corfu, F., Hetherington, C. J., Burke, K., Gerber, M. (2007) Geochronology of zircon megacrysts from nepheline-bearing gneisses as constraints on tectonic setting: implications for resetting of the U-Pb and Lu-Hf isotopic systems. Contributions to Mineralogy and Petrology, 153 (4). 389-403 doi:10.1007/s00410-006-0153-9
Plain TextAshwal, L. D., Armstrong, R. A., Roberts, R. J., Schmitz, M. D., Corfu, F., Hetherington, C. J., Burke, K., Gerber, M. (2007) Geochronology of zircon megacrysts from nepheline-bearing gneisses as constraints on tectonic setting: implications for resetting of the U-Pb and Lu-Hf isotopic systems. Contributions to Mineralogy and Petrology, 153 (4). 389-403 doi:10.1007/s00410-006-0153-9
In(2007, March) Contributions to Mineralogy and Petrology Vol. 153 (4) Springer Science and Business Media LLC
Abstract/NotesNepheline-bearing gneisses from the 75 km2 Tambani body in the Mozambique Belt of southern Malawi, are miaskitic biotite-nepheline monzodiorites, reflecting an absence of K-feldspar, alkali amphiboles or pyroxenes, and contain euhedral zircon megacrysts up to 5 cm across. The zircons contain U = 1–1,860 ppm, Th = 0–2,170 ppm and Y = 400–1,100 ppm, and very low concentrations of all other measured trace elements except Hf (HfO2 = 0.53–0.92 wt. %). Cathodoluminescence images reveal oscillatory sector growth zoning and no evidence for xenocrystic cores, indicating that the zircons represent primary magmatic crystallization products that have survived amphibolite grade metamorphism. U-Pb isotopic analyses (by TIMS) yield an upper intercept age of 730 ± 4 Ma (MSWD = 1.7), which we interpret as the time of magmatic crystallization of the zircons. This is coincident with 11 SHRIMP spot analyses, which yield a mean age of 729 ± 7 Ma (MSWD = 0.37).

Metamorphism, at 522 ± 17 Ma as suggested by monazite, caused partial Pb-loss during local recrystallization of zircon. Lu-Hf isotopic data for three whole-rocksamples of nepheline-bearing gneiss are collinear with those for zircon megacrysts, and correspond to an age of 584 ± 17 Ma (MSWD = 0.37. We interpret the LuHf array to represent a mixing line defined by the Hf isotopic signature of primary zircon and that of the rock-forming minerals reset during metamorphic (re-)crystallization; hence the 584 Ma age is likely geologically meaningless. Given the well-defined association of nepheline syenites (and phonolitic volcanic equivalents) with continental rifting, we suggest that the Tambani body represents a magmatic product formed at 730 Ma during the break-up of the Rodinia supercontinent. The 522 Ma age is akin to other PanAfrican metamorphic ages that record collisional suturing events during the final assembly of Gondwana. Zircon-bearing nepheline gneisses thus preserve a record of intra-continental rifting and of continental collision in southern Malawi.

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Salambidwe Intrusion, Chikwawa, Southern Region, Malawi


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