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Litvinskite

A valid IMA mineral species
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About LitvinskiteHide

07905750017061528195497.jpg
Galia P. Litvinskaya
Formula:
Na2(◻,Na,Mn)ZrSi6O12(OH,O)6
Colour:
Dark cherry-red to reddish-brown
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.61
Crystal System:
Monoclinic
Name:
Named in honor of Galia Petrovna Litvinskaya (Галина Петровна Литвинская) (21 September 1920, Vladimir, Russian Empire - 06 August 1994, Moscow, Russia), geologist-geochemist, crystallographer, and senior lecturer of the Department of Crystallography and Crystallochemistry at the Moscow State University.
Lovozerite Group. Compare kapustinite.

Kapustinite undergoes a partial alteration to litvinskite over about one year. The transformation occurs in only a few hours when in hot water (80–100 °C).


Unique IdentifiersHide

Mindat ID:
11437
Long-form identifier:
mindat:1:1:11437:2
GUID
(UUID V4):
f06581e1-bcd5-4018-ba35-60ccfe470fa8

IMA Classification of LitvinskiteHide

Approved
IMA Formula:
Na3ZrSi6O13(OH)5
Approval year:
1999
First published:
2000

Classification of LitvinskiteHide

9.CJ.15a

9 : SILICATES (Germanates)
C : Cyclosilicates
J : [Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
LtvIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LitvinskiteHide

Vitreous
Transparency:
Transparent
Colour:
Dark cherry-red to reddish-brown
Streak:
White
Hardness:
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Imperfect on {110}.
Fracture:
Conchoidal
Density:
2.61 g/cm3 (Measured)    2.63 g/cm3 (Calculated)

Optical Data of LitvinskiteHide

Type:
Biaxial (-)
RI values:
nα = 1.546(1) nβ = 1.574(1) nγ = 1.575(1)
2V:
Measured: <10°
Max Birefringence:
δ = 0.029
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemistry of LitvinskiteHide

Mindat Formula:
Na2(◻,Na,Mn)ZrSi6O12(OH,O)6
Common Impurities:
Mn

Crystallography of LitvinskiteHide

Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Bm
Cell Parameters:
a = 10.589 Å, b = 10.217 Å, c = 7.355 Å
β = 92.91°
Ratio:
a:b:c = 1.036 : 1 : 0.72
Unit Cell V:
794.6 ų
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012370LitvinskiteYamnova N A, Egorov-Tismenko Y K, Pekov I V, Ekimenkova I A (2001) Crystal structure of litvinskite: A new natural member of the lovozerite group Crystallography Reports 46 190-1932001Alluaiv mountain, Lovozero massif, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.37 Å(44)
5.29 Å(100)
3.329 Å(74)
3.238 Å(100)
2.981 Å(39)
2.553 Å(37)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of LitvinskiteHide

General Appearance of Type Material:
Equant grains to 7 cm and as aggregates to 15 cm. Sometimes replaced by terskite and gaidonnayite.
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Moscow, Russia.
Geological Setting of Type Material:
In a hyperagpaitic pegmatite.
Associated Minerals at Type Locality:

Synonyms of LitvinskiteHide

Other Language Names for LitvinskiteHide

Relationship of Litvinskite to other SpeciesHide

Other Members of this group:
CombeiteNa4.5Ca3.5Si6O17.5(OH)0.5Trig. 3m (3 2/m) : R3m
KapustiniteNa6ZrSi6O16(OH)2Mon. 2/m : B2/m
KazakoviteNa6Mn2+Ti(Si6O18)Trig. 3m (3 2/m) : R3m
LovozeriteNa2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2OTrig. 3 : R3
TisinaliteNa3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2OTrig. 3m (3 2/m)
TownenditeNa8ZrSi6O18Trig. 3m (3 2/m) : R3m
ZirsinaliteNa6(Ca,Mn2+,Fe2+)Zr(Si6O18)Trig. 3m (3 2/m) : R3m

Common AssociatesHide

Associated Minerals Based on Photo Data:
8 photos of Litvinskite associated with TerskiteNa4ZrSi6O16 · 2H2O
7 photos of Litvinskite associated with AegirineNaFe3+Si2O6
4 photos of Litvinskite associated with EudialyteNa15Ca6Fe3Zr3Si(Si25O73)(O,OH,H2O)3(Cl,OH)2
2 photos of Litvinskite associated with GaidonnayiteNa2Zr(Si3O9) · 2H2O
2 photos of Litvinskite associated with CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2O
2 photos of Litvinskite associated with SodaliteNa4(Si3Al3)O12Cl
2 photos of Litvinskite associated with KapustiniteNa6ZrSi6O16(OH)2
1 photo of Litvinskite associated with Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2
1 photo of Litvinskite associated with HackmaniteNa8Al6Si6O24(Cl2,S)

Related Minerals - Strunz-mindat GroupingHide

9.CJ.AvdeeviteNaAl4(Be5Li)(Si6O18)2(H2O)1-2Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.CJ.NakkaalaaqiteK2[Na3Ca]LiCa2Ti2Be4Si12O38Orth. mmm (2/m 2/m 2/m) : Fddd
9.CJ.ZolotareviteNa5Zr[Si6O15(OH)3] · 3H2OTrig. 3m (3 2/m) : R3m
9.CJ.Beryllocordierite-NaNaMg4(Al5Be)(AlSi5O18)2 · 2H2OOrth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.Beryllosachanbińskiite-NaNaMn4(Al5Be)(AlSi5O18)2 · 2H2OOrth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.05BazziteBe3Sc2(Si6O18)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05BerylBe3Al2(Si6O18)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05IndialiteMg2Al3(AlSi5O18)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05 vaVorobyeviteBe3Al2(Si6O18)
9.CJ.05StoppaniiteBe3Fe3+2(Si6O18) · H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05Ferroindialite(Fe2+,Mg)2Al4Si5O18Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.05JohnkoivulaiteCs[Be2B]Mg2Si6O18Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CJ.10Cordierite(Mg,Fe)2Al3(AlSi5O18)Orth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.10Sekaninaite(Fe,Mg)2Al3(AlSi5O18)Orth. mmm (2/m 2/m 2/m) : Cccm
9.CJ.15aCombeiteNa4.5Ca3.5Si6O17.5(OH)0.5Trig. 3m (3 2/m) : R3m
9.CJ.15bImandriteNa12Ca3Fe3+2(Si6O18)2Orth. mmm (2/m 2/m 2/m)
9.CJ.15aKazakoviteNa6Mn2+Ti(Si6O18)Trig. 3m (3 2/m) : R3m
9.CJ.15cKoashviteNa6(Ca,Mn)(Ti,Fe)Si6O18 · H2OOrth. mmm (2/m 2/m 2/m)
9.CJ.15aLovozeriteNa2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2OTrig. 3 : R3
9.CJ.15aTisinaliteNa3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2OTrig. 3m (3 2/m)
9.CJ.15aZirsinaliteNa6(Ca,Mn2+,Fe2+)Zr(Si6O18)Trig. 3m (3 2/m) : R3m
9.CJ.15aKapustiniteNa6ZrSi6O16(OH)2Mon. 2/m : B2/m
9.CJ.15aTownenditeNa8ZrSi6O18Trig. 3m (3 2/m) : R3m
9.CJ.25BaratoviteKCa7(Ti,Zr)2Li3Si12O36F2Mon. 2/m : B2/b
9.CJ.25KatayamaliteKLi3Ca7Ti2(SiO3)12(OH)2Mon. 2/m : B2/b
9.CJ.25AleksandroviteKCa7Sn2Li3Si12O36F2Mon. 2/m : B2/b
9.CJ.30DioptaseCuSiO3 · H2OTrig. 3 : R3
9.CJ.35KostyleviteK2Zr(Si3O9) · H2OMon. 2/m : P21/b
9.CJ.40PetarasiteNa5Zr2(Si6O18)(Cl,OH) · 2H2OMon. 2/m : P21/m
9.CJ.45Gerenite-(Y)(Ca,Na)2(Y,REE)3Si6O18 · 2H2OTric. 1 : P1
9.CJ.50OdintsoviteK2Na4Ca3Ti2Be4Si12O38Orth. mmm (2/m 2/m 2/m) : Fddd
9.CJ.55MathewrogersitePb7FeAl3GeSi12O36(OH,H2O)6Trig.
9.CJ.60PezzottaiteCs(Be2Li)Al2(Si6O18)Trig. 3 : R3

Fluorescence of LitvinskiteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LitvinskiteHide

References for LitvinskiteHide

Localities for LitvinskiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
TARASSOFF (2007)
Russia
 
  • Murmansk Oblast
    • Khibiny Massif
Pekov et al. (2004)
    • Lovozersky District
      • Alluaiv Mountain
        • Umbozero mine
Pekov et al. (2000) +1 other reference
 
Mineral and/or Locality  
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