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Larosite

A valid IMA mineral species
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07380330015206957278368.jpg
Alfred Larose
Formula:
(Cu,Ag)21PbBiS13
Colour:
Pale buff (polished section)
Lustre:
Metallic
Hardness:
3 - 3½
Specific Gravity:
6.19 (Calculated)
Crystal System:
Orthorhombic
Name:
Named after Alfred LaRose (1870-1940), blacksmith and prospector who was one of the principal discoverers in 1903 of the rich silver deposits of the Cobalt area of northern Ontario, which led to a huge exploration and mining boom in the region. Two versions of the name are found in the literature, LaRose and Larose, the latter traditionally used by the family, but the former used in the naming of the mine. LaRose was inducted into the Canadian Mining Hall of Fame in 2003.
Note: Electron microbe analyses of larosite from Norway (Cook et al., 2010) gave Cu20.47Ag3.68Fe0.22Pb1.01Bi1.06S15.00 calculated on the basis of 15 S atoms.


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Unique IdentifiersHide

Mindat ID:
2334
Long-form identifier:
mindat:1:1:2334:0
GUID
(UUID V4):
fd5e88ae-a67b-4d35-af0e-90a0047e08a5

IMA Classification of LarositeHide

Classification of LarositeHide

2.LB.35

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
L : Unclassified Sulfosalts
B : With essential Pb
2.16.9.1

2 : SULFIDES
16 : Miscellaneous
5.7.43

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
7 : Sulpharsenites etc. of Pb and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
LarIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LarositeHide

Metallic
Transparency:
Opaque
Colour:
Pale buff (polished section)
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN100=121 - 130 kg/mm2 - Vickers
Density:
6.19 g/cm3 (Calculated)

Optical Data of LarositeHide

Anisotropism:
Moderate, in gray and greenish buff.
Reflectivity:
WavelengthR1R2
400nm35.4%36.9%
420nm34.9%36.1%
440nm34.4%35.4%
460nm33.8%34.8%
480nm33.2%33.9%
500nm32.7%33.3%
520nm32.2%32.8%
540nm32.0%32.7%
560nm31.9%32.6%
580nm31.9%32.6%
600nm31.8%32.5%
620nm31.9%32.5%
640nm32.0%32.3%
660nm32.2%32.2%
680nm32.3%32.0%
700nm32.5%31.9%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 36.9%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Pale buff
Pleochroism:
Weak

Chemistry of LarositeHide

Mindat Formula:
(Cu,Ag)21PbBiS13

Crystallography of LarositeHide

Crystal System:
Orthorhombic
Cell Parameters:
a = 22.15 Å, b = 24.03 Å, c = 11.67 Å
Ratio:
a:b:c = 0.922 : 1 : 0.486
Unit Cell V:
6,211.53 ų (Calculated from Unit Cell)
Z:
10
Morphology:
small acicular to flamelike crystals, the largest being about 300 µm long.
Comment:
Point Group: n.d.; Space Group: n.d.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.206 Å(50)
2.917 Å(90)
2.846 Å(60)
2.471 Å(60)
2.555 Å(40)
2.162 Å(40)
1.982 Å(100)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of LarositeHide

General Appearance of Type Material:
Acicular to flame-like crystals, up to 25x300 microns, in an assemblage of chalcocite and stromeyerite in the central portion of a layered vein.
Place of Conservation of Type Material:
Canadian Geological Survey, Ottawa, Canada, 12126.
Associated Minerals at Type Locality:
Reference:
Petruk, W. (1972) Larosite, a new copper-lead-bismuth sulphide. Canadian Mineralogist: 11: 886-891.

Synonyms of LarositeHide

Other Language Names for LarositeHide

German:Larosit
Simplified Chinese:硫铋铅铜矿
Spanish:Larosita
Traditional Chinese:硫鉍鉛銅礦

Related Minerals - Strunz-mindat GroupingHide

2.LB.CiriottiiteCu(Cu,Ag)3Pb19(Sb,As)22(As2)S56Mon. 2/m
2.LB.HayyaniteCu5Ag11Pb76Sb71As17(As2+)8S224Mon. 2/m : P21/b
2.LB.05MiharaiteCu4FePbBiS6Orth.
2.LB.30ArdaitePb19Sb13S35Cl7Mon.
2.LB.30LaunayiteCuPb10(Sb,As)12S20Mon.
2.LB.30MadocitePb19(Sb,As)16S43Orth.
2.LB.30PlayfairitePb16(Sb,As)19S44ClMon.
2.LB.30SorbyiteCuPb9(Sb,As)11S26Mon. 2/m : B2/m
2.LB.30SterryiteCu(Ag,Cu)3Pb19(Sb,As)22(As-As)S56Mon. 2/m
2.LB.40PetroviciteCu3HgPbBiSe5Orth.
2.LB.40MazzettiiteAg3HgPbSbTe5Orth.
2.LB.45CreraritePt2-x(Bi,Pb)11(S,Se)11Tric. 1 : P1
2.LB.50QuijarroiteCu6HgPb2Bi4Se12Orth. mm2 : Pmn21
2.LB.55ZnamenskyitePb4In2Bi4S13Orth. mmm (2/m 2/m 2/m) : Pbam

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LarositeHide

References for LarositeHide

Localities for LarositeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Ontario
    • Timiskaming District
      • Cobalt-Gowganda region
159-161. +1 other reference
          • Coleman Township
PETRUK (1972)
China
 
  • Guangdong
    • Meizhou
      • Mei Co.
Binghui Chen et al. (1994)
  • Henan
    • Luoyang
      • Song County
        • Qiyugou ore field
Shihua Li and Jinzhong Qi (2000) +1 other reference
  • Tibet
    • Xigazê Prefecture (Rikaze Prefecture; Shigatse Prefecture)
      • Namling Co. (Nanmulin Co.)
Li et al. (2019)
Norway
 
  • Telemark
    • Tinn
      • Hovin
Cook et al. (2010)
Cook et al. (2010)
USA
 
  • Montana
    • Silver Bow County
      • Butte Mining District (Summit Valley Mining District)
Gammons et al. (2016)
 
Mineral and/or Locality  
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